Studies on near infrared emission of Yb3+ ions in a SeO2 based glass system
SeO2 based glasses of the composition 39 PbO–(60-x) B2O3– xSeO2:1.0 Yb2O3 (with 10 ≤ x ≤ 50) was synthesized. Analysis of the results of structural studies of the samples revealed that the glass network consists of [SeO4]2− and [SeO3]2− units; the studies further indicated an increasing fraction of...
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creator | Naresh, Pathuri Ravi Kumar, Valluri Sesha Reddy, A. Siva Kostrzewa, M. Venkatramaiah, N. Krishna Mohan, N. Ravi Kumar, V. Veeraiah, N. |
description | SeO2 based glasses of the composition 39 PbO–(60-x) B2O3– xSeO2:1.0 Yb2O3 (with 10 ≤ x ≤ 50) was synthesized. Analysis of the results of structural studies of the samples revealed that the glass network consists of [SeO4]2− and [SeO3]2− units; the studies further indicated an increasing fraction of [SeO3]2− units and decreasing concentration of [SeO4]2− groups with increase of SeO2 content. Optical Absorption (OA) and photoluminescence (PL) spectra have exhibited bands due to 2F7/2 → 2F5/2 and 2F5/2 → 2F7/2 transitions, respectively. Evaluated absorption and emission cross-sections and lifetime of the excited state of Yb3+ ions exhibited an increase with increase of SeO2 content. Results of PL studies indicated nearly fourfold increase of PL output with increase of SeO2 content up to 50%. Such increase is attributed to the increased concentration of isolated [SeO3]2- pyramidal groups. Overall, the rise of SeO2 content in Yb3+ doped PbO–B2O3–SeO2 glass system facilitated the increase of PL emission of Yb3+ ions largely. |
doi_str_mv | 10.1016/j.physb.2021.412827 |
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Siva ; Kostrzewa, M. ; Venkatramaiah, N. ; Krishna Mohan, N. ; Ravi Kumar, V. ; Veeraiah, N.</creator><creatorcontrib>Naresh, Pathuri ; Ravi Kumar, Valluri ; Sesha Reddy, A. Siva ; Kostrzewa, M. ; Venkatramaiah, N. ; Krishna Mohan, N. ; Ravi Kumar, V. ; Veeraiah, N.</creatorcontrib><description>SeO2 based glasses of the composition 39 PbO–(60-x) B2O3– xSeO2:1.0 Yb2O3 (with 10 ≤ x ≤ 50) was synthesized. Analysis of the results of structural studies of the samples revealed that the glass network consists of [SeO4]2− and [SeO3]2− units; the studies further indicated an increasing fraction of [SeO3]2− units and decreasing concentration of [SeO4]2− groups with increase of SeO2 content. Optical Absorption (OA) and photoluminescence (PL) spectra have exhibited bands due to 2F7/2 → 2F5/2 and 2F5/2 → 2F7/2 transitions, respectively. Evaluated absorption and emission cross-sections and lifetime of the excited state of Yb3+ ions exhibited an increase with increase of SeO2 content. Results of PL studies indicated nearly fourfold increase of PL output with increase of SeO2 content up to 50%. Such increase is attributed to the increased concentration of isolated [SeO3]2- pyramidal groups. Overall, the rise of SeO2 content in Yb3+ doped PbO–B2O3–SeO2 glass system facilitated the increase of PL emission of Yb3+ ions largely.</description><identifier>ISSN: 0921-4526</identifier><identifier>EISSN: 1873-2135</identifier><identifier>DOI: 10.1016/j.physb.2021.412827</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>1.0 μm emission ; Absorption ; Boron oxides ; Chemical synthesis ; Emission analysis ; Emission and absorption cross-sections ; Glass ; Ions ; Luminescence ; Near infrared radiation ; Photoluminescence ; Selenium dioxide ; SeO2 based glass system ; Studies ; Yb3+ ions</subject><ispartof>Physica. 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Siva</creatorcontrib><creatorcontrib>Kostrzewa, M.</creatorcontrib><creatorcontrib>Venkatramaiah, N.</creatorcontrib><creatorcontrib>Krishna Mohan, N.</creatorcontrib><creatorcontrib>Ravi Kumar, V.</creatorcontrib><creatorcontrib>Veeraiah, N.</creatorcontrib><title>Studies on near infrared emission of Yb3+ ions in a SeO2 based glass system</title><title>Physica. B, Condensed matter</title><description>SeO2 based glasses of the composition 39 PbO–(60-x) B2O3– xSeO2:1.0 Yb2O3 (with 10 ≤ x ≤ 50) was synthesized. Analysis of the results of structural studies of the samples revealed that the glass network consists of [SeO4]2− and [SeO3]2− units; the studies further indicated an increasing fraction of [SeO3]2− units and decreasing concentration of [SeO4]2− groups with increase of SeO2 content. Optical Absorption (OA) and photoluminescence (PL) spectra have exhibited bands due to 2F7/2 → 2F5/2 and 2F5/2 → 2F7/2 transitions, respectively. Evaluated absorption and emission cross-sections and lifetime of the excited state of Yb3+ ions exhibited an increase with increase of SeO2 content. Results of PL studies indicated nearly fourfold increase of PL output with increase of SeO2 content up to 50%. Such increase is attributed to the increased concentration of isolated [SeO3]2- pyramidal groups. Overall, the rise of SeO2 content in Yb3+ doped PbO–B2O3–SeO2 glass system facilitated the increase of PL emission of Yb3+ ions largely.</description><subject>1.0 μm emission</subject><subject>Absorption</subject><subject>Boron oxides</subject><subject>Chemical synthesis</subject><subject>Emission analysis</subject><subject>Emission and absorption cross-sections</subject><subject>Glass</subject><subject>Ions</subject><subject>Luminescence</subject><subject>Near infrared radiation</subject><subject>Photoluminescence</subject><subject>Selenium dioxide</subject><subject>SeO2 based glass system</subject><subject>Studies</subject><subject>Yb3+ ions</subject><issn>0921-4526</issn><issn>1873-2135</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kE1PwzAMhiMEEmPwC7hE4oha8tWkPXBAE19i0g6DA6coTV1ItbUj7pD278kYZ3yxZb-vLT-EXHKWc8b1TZdvPndY54IJnisuSmGOyISXRmaCy-KYTFgleKYKoU_JGWLHUnDDJ-RlOW6bAEiHnvbgIg19G12EhsI6IIbUHlr6XstrmmpMY-roEhaC1g6T6mPlECnucIT1OTlp3Qrh4i9PydvD_evsKZsvHp9nd_PMC83HDHxVNbXTEurS61Io75kzrTFaOOO806JmyviKadcyqJqiZlIZVZrWc9fKQk7J1WHvJg5fW8DRdsM29umkFYVUWpXSyKSSB5WPA2KE1m5iWLu4s5zZPTXb2V9qdk_NHqgl1-3BBemB7wDRog_Qe2hCBD_aZgj_-n8Ac211Zw</recordid><startdate>20210401</startdate><enddate>20210401</enddate><creator>Naresh, Pathuri</creator><creator>Ravi Kumar, Valluri</creator><creator>Sesha Reddy, A. 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Siva</creatorcontrib><creatorcontrib>Kostrzewa, M.</creatorcontrib><creatorcontrib>Venkatramaiah, N.</creatorcontrib><creatorcontrib>Krishna Mohan, N.</creatorcontrib><creatorcontrib>Ravi Kumar, V.</creatorcontrib><creatorcontrib>Veeraiah, N.</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Physica. B, Condensed matter</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Naresh, Pathuri</au><au>Ravi Kumar, Valluri</au><au>Sesha Reddy, A. Siva</au><au>Kostrzewa, M.</au><au>Venkatramaiah, N.</au><au>Krishna Mohan, N.</au><au>Ravi Kumar, V.</au><au>Veeraiah, N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Studies on near infrared emission of Yb3+ ions in a SeO2 based glass system</atitle><jtitle>Physica. B, Condensed matter</jtitle><date>2021-04-01</date><risdate>2021</risdate><volume>606</volume><spage>412827</spage><pages>412827-</pages><artnum>412827</artnum><issn>0921-4526</issn><eissn>1873-2135</eissn><abstract>SeO2 based glasses of the composition 39 PbO–(60-x) B2O3– xSeO2:1.0 Yb2O3 (with 10 ≤ x ≤ 50) was synthesized. Analysis of the results of structural studies of the samples revealed that the glass network consists of [SeO4]2− and [SeO3]2− units; the studies further indicated an increasing fraction of [SeO3]2− units and decreasing concentration of [SeO4]2− groups with increase of SeO2 content. Optical Absorption (OA) and photoluminescence (PL) spectra have exhibited bands due to 2F7/2 → 2F5/2 and 2F5/2 → 2F7/2 transitions, respectively. Evaluated absorption and emission cross-sections and lifetime of the excited state of Yb3+ ions exhibited an increase with increase of SeO2 content. Results of PL studies indicated nearly fourfold increase of PL output with increase of SeO2 content up to 50%. Such increase is attributed to the increased concentration of isolated [SeO3]2- pyramidal groups. Overall, the rise of SeO2 content in Yb3+ doped PbO–B2O3–SeO2 glass system facilitated the increase of PL emission of Yb3+ ions largely.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.physb.2021.412827</doi><orcidid>https://orcid.org/0000-0001-8743-1230</orcidid><orcidid>https://orcid.org/0000-0003-0235-2707</orcidid></addata></record> |
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subjects | 1.0 μm emission Absorption Boron oxides Chemical synthesis Emission analysis Emission and absorption cross-sections Glass Ions Luminescence Near infrared radiation Photoluminescence Selenium dioxide SeO2 based glass system Studies Yb3+ ions |
title | Studies on near infrared emission of Yb3+ ions in a SeO2 based glass system |
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