Durable antimicrobial cotton fabric fabricated by carboxymethyl chitosan and quaternary ammonium salts
In this article, carboxymethyl chitosan (CMC) and (3-carboxypropyl) trimethylammonium chloride (CPTC) were used as raw materials to prepare an antibacterial cotton fabric with excellent laundering durability. CMC was first anchored to the surface of cotton fiber via esterification between the carbox...
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| Veröffentlicht in: | Cellulose (London) 2021-06, Vol.28 (9), p.5867-5879 |
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| creator | Wang, Lujie Wen, Xiaodong Zhang, Xujun Yuan, Shuntao Xu, Qingbo Fu, Feiya Diao, Hongyan Liu, Xiangdong |
| description | In this article, carboxymethyl chitosan (CMC) and (3-carboxypropyl) trimethylammonium chloride (CPTC) were used as raw materials to prepare an antibacterial cotton fabric with excellent laundering durability. CMC was first anchored to the surface of cotton fiber via esterification between the carboxyl groups of CMC and the hydroxyl groups of the cellulose molecules on the cotton fiber surface, and then the CPTC was linked to the CMC chains via amidation to the amino groups of the grafted CMC chains. The antibacterial tests showed that the bacteriostatic reduction rate (BR) of the finished cotton fabric against
S. aureus
and
E. coli
was above 99.9%, and the BR value of modified cotton fabric remained above 99.9% even after 120 laundering cycles. The results of cytotoxicity, vapor transmissibility, and tensile strength of the fabric samples, as well as the evaluation of water absorption and flexibility show that the modified cotton fabrics are safe and comfortable. |
| doi_str_mv | 10.1007/s10570-021-03875-x |
| format | Article |
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S. aureus
and
E. coli
was above 99.9%, and the BR value of modified cotton fabric remained above 99.9% even after 120 laundering cycles. The results of cytotoxicity, vapor transmissibility, and tensile strength of the fabric samples, as well as the evaluation of water absorption and flexibility show that the modified cotton fabrics are safe and comfortable.</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-021-03875-x</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Antiinfectives and antibacterials ; Bioorganic Chemistry ; Ceramics ; Chains ; Chemistry ; Chemistry and Materials Science ; Chitosan ; Composites ; Cotton fabrics ; Cotton fibers ; Durability ; E coli ; Esterification ; Glass ; Hydroxyl groups ; Natural Materials ; Organic Chemistry ; Original Research ; Physical Chemistry ; Polymer Sciences ; Quaternary ammonium salts ; Raw materials ; Sustainable Development ; Tensile strength ; Toxicity ; Washing ; Water absorption</subject><ispartof>Cellulose (London), 2021-06, Vol.28 (9), p.5867-5879</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-2490ea447483976738ebe8787267c74b89620150865456bb90755688db14953f3</citedby><cites>FETCH-LOGICAL-c356t-2490ea447483976738ebe8787267c74b89620150865456bb90755688db14953f3</cites><orcidid>0000-0003-4863-3715</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-021-03875-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-021-03875-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Wang, Lujie</creatorcontrib><creatorcontrib>Wen, Xiaodong</creatorcontrib><creatorcontrib>Zhang, Xujun</creatorcontrib><creatorcontrib>Yuan, Shuntao</creatorcontrib><creatorcontrib>Xu, Qingbo</creatorcontrib><creatorcontrib>Fu, Feiya</creatorcontrib><creatorcontrib>Diao, Hongyan</creatorcontrib><creatorcontrib>Liu, Xiangdong</creatorcontrib><title>Durable antimicrobial cotton fabric fabricated by carboxymethyl chitosan and quaternary ammonium salts</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>In this article, carboxymethyl chitosan (CMC) and (3-carboxypropyl) trimethylammonium chloride (CPTC) were used as raw materials to prepare an antibacterial cotton fabric with excellent laundering durability. CMC was first anchored to the surface of cotton fiber via esterification between the carboxyl groups of CMC and the hydroxyl groups of the cellulose molecules on the cotton fiber surface, and then the CPTC was linked to the CMC chains via amidation to the amino groups of the grafted CMC chains. The antibacterial tests showed that the bacteriostatic reduction rate (BR) of the finished cotton fabric against
S. aureus
and
E. coli
was above 99.9%, and the BR value of modified cotton fabric remained above 99.9% even after 120 laundering cycles. The results of cytotoxicity, vapor transmissibility, and tensile strength of the fabric samples, as well as the evaluation of water absorption and flexibility show that the modified cotton fabrics are safe and comfortable.</description><subject>Antiinfectives and antibacterials</subject><subject>Bioorganic Chemistry</subject><subject>Ceramics</subject><subject>Chains</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chitosan</subject><subject>Composites</subject><subject>Cotton fabrics</subject><subject>Cotton fibers</subject><subject>Durability</subject><subject>E coli</subject><subject>Esterification</subject><subject>Glass</subject><subject>Hydroxyl groups</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Quaternary ammonium salts</subject><subject>Raw materials</subject><subject>Sustainable Development</subject><subject>Tensile strength</subject><subject>Toxicity</subject><subject>Washing</subject><subject>Water absorption</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kEtLAzEUhYMoWKt_wFXA9ehNMnktpT6h4EbBXUimGTtlHm2SgfbfG52CO1dncb9zOPcgdE3glgDIu0iASyiAkgKYkrzYn6AZ4ZIWStHPUzQDLXQ-M32OLmLcAICWlMxQ_TAG61qPbZ-arqnC4Brb4mpIaehxbV1oqqPY5FfYHXBlgxv2h86n9SGT6yYN0fY5YIV3Y4ZCb8MB264b-mbscLRtipforLZt9FdHnaOPp8f3xUuxfHt-Xdwvi4pxkQpaavC2LGWpmJZCMuWdV1JJKmQlS6e0oEA4KMFLLpzTIDkXSq0cKTVnNZujmyl3G4bd6GMym2HMhdpoKGdMayaUyBSdqPxujMHXZhuaLrc2BMzPnmba0-Q9ze-eZp9NbDLFDPdfPvxF_-P6BrN2eUY</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Wang, Lujie</creator><creator>Wen, Xiaodong</creator><creator>Zhang, Xujun</creator><creator>Yuan, Shuntao</creator><creator>Xu, Qingbo</creator><creator>Fu, Feiya</creator><creator>Diao, Hongyan</creator><creator>Liu, Xiangdong</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0003-4863-3715</orcidid></search><sort><creationdate>20210601</creationdate><title>Durable antimicrobial cotton fabric fabricated by carboxymethyl chitosan and quaternary ammonium salts</title><author>Wang, Lujie ; Wen, Xiaodong ; Zhang, Xujun ; Yuan, Shuntao ; Xu, Qingbo ; Fu, Feiya ; Diao, Hongyan ; Liu, Xiangdong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-2490ea447483976738ebe8787267c74b89620150865456bb90755688db14953f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Antiinfectives and antibacterials</topic><topic>Bioorganic Chemistry</topic><topic>Ceramics</topic><topic>Chains</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chitosan</topic><topic>Composites</topic><topic>Cotton fabrics</topic><topic>Cotton fibers</topic><topic>Durability</topic><topic>E coli</topic><topic>Esterification</topic><topic>Glass</topic><topic>Hydroxyl groups</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Quaternary ammonium salts</topic><topic>Raw materials</topic><topic>Sustainable Development</topic><topic>Tensile strength</topic><topic>Toxicity</topic><topic>Washing</topic><topic>Water absorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Lujie</creatorcontrib><creatorcontrib>Wen, Xiaodong</creatorcontrib><creatorcontrib>Zhang, Xujun</creatorcontrib><creatorcontrib>Yuan, Shuntao</creatorcontrib><creatorcontrib>Xu, Qingbo</creatorcontrib><creatorcontrib>Fu, Feiya</creatorcontrib><creatorcontrib>Diao, Hongyan</creatorcontrib><creatorcontrib>Liu, Xiangdong</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Proquest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Lujie</au><au>Wen, Xiaodong</au><au>Zhang, Xujun</au><au>Yuan, Shuntao</au><au>Xu, Qingbo</au><au>Fu, Feiya</au><au>Diao, Hongyan</au><au>Liu, Xiangdong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Durable antimicrobial cotton fabric fabricated by carboxymethyl chitosan and quaternary ammonium salts</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2021-06-01</date><risdate>2021</risdate><volume>28</volume><issue>9</issue><spage>5867</spage><epage>5879</epage><pages>5867-5879</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>In this article, carboxymethyl chitosan (CMC) and (3-carboxypropyl) trimethylammonium chloride (CPTC) were used as raw materials to prepare an antibacterial cotton fabric with excellent laundering durability. CMC was first anchored to the surface of cotton fiber via esterification between the carboxyl groups of CMC and the hydroxyl groups of the cellulose molecules on the cotton fiber surface, and then the CPTC was linked to the CMC chains via amidation to the amino groups of the grafted CMC chains. The antibacterial tests showed that the bacteriostatic reduction rate (BR) of the finished cotton fabric against
S. aureus
and
E. coli
was above 99.9%, and the BR value of modified cotton fabric remained above 99.9% even after 120 laundering cycles. The results of cytotoxicity, vapor transmissibility, and tensile strength of the fabric samples, as well as the evaluation of water absorption and flexibility show that the modified cotton fabrics are safe and comfortable.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-021-03875-x</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-4863-3715</orcidid></addata></record> |
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| subjects | Antiinfectives and antibacterials Bioorganic Chemistry Ceramics Chains Chemistry Chemistry and Materials Science Chitosan Composites Cotton fabrics Cotton fibers Durability E coli Esterification Glass Hydroxyl groups Natural Materials Organic Chemistry Original Research Physical Chemistry Polymer Sciences Quaternary ammonium salts Raw materials Sustainable Development Tensile strength Toxicity Washing Water absorption |
| title | Durable antimicrobial cotton fabric fabricated by carboxymethyl chitosan and quaternary ammonium salts |
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