Novel synthesis and electrochemical investigations of ZnO/C composites for lithium-ion batteries
For the first time, ZnO/C composites were synthesized using zinc glycerolate as a precursor through one-step calcination under a nitrogen atmosphere. The effect of the heat treatment conditions on the structure, composition, morphology as well as on the electrochemical properties regarding applicati...
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| Veröffentlicht in: | Journal of materials science 2021-08, Vol.56 (23), p.13227-13242 |
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| creator | Thauer, E. Zakharova, G. S. Andreikov, E. I. Adam, V. Wegener, S. A. Nölke, J. -H. Singer, L. Ottmann, A. Asyuda, A. Zharnikov, M. Kiselkov, D. M. Zhu, Q. Puzyrev, I. S. Podval’naya, N. V. Klingeler, R. |
| description | For the first time, ZnO/C composites were synthesized using zinc glycerolate as a precursor through one-step calcination under a nitrogen atmosphere. The effect of the heat treatment conditions on the structure, composition, morphology as well as on the electrochemical properties regarding application in lithium-ion batteries are investigated. The products obtained by calcination of the precursor in nitrogen at 400—800 °C consist of zinc oxide nanoparticles and amorphous carbon that is
in-situ
generated from organic components of the glycerolate precursor. When used as anode material for lithium-ion batteries, the as-prepared ZnO/C composite synthesized at a calcination temperature of 700 °C delivers initial discharge and charge capacities of 1061 and 671 mAh g
−1
at a current rate of 100 mA g
−1
and hence 1.5 times more than bare ZnO, which reaches only 749/439 mAh g
−1
. The native carbon improves the conductivity, allowing efficient electronic conductivity and Li-ion diffusion. By means of
ex-situ
XRD studies a two-step storage mechanism is proven. |
| doi_str_mv | 10.1007/s10853-021-06125-4 |
| format | Article |
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in-situ
generated from organic components of the glycerolate precursor. When used as anode material for lithium-ion batteries, the as-prepared ZnO/C composite synthesized at a calcination temperature of 700 °C delivers initial discharge and charge capacities of 1061 and 671 mAh g
−1
at a current rate of 100 mA g
−1
and hence 1.5 times more than bare ZnO, which reaches only 749/439 mAh g
−1
. The native carbon improves the conductivity, allowing efficient electronic conductivity and Li-ion diffusion. By means of
ex-situ
XRD studies a two-step storage mechanism is proven.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-021-06125-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Anodes ; Batteries ; Carbon ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Composite materials ; Crystallography and Scattering Methods ; Electric properties ; Electrochemical analysis ; Electrode materials ; Energy Materials ; Heat treatment ; Ion diffusion ; Lithium ; Lithium-ion batteries ; Materials Science ; Morphology ; Nanoparticles ; Polymer Sciences ; Precursors ; Rechargeable batteries ; Roasting ; Solid Mechanics ; Zinc oxide ; Zinc oxides</subject><ispartof>Journal of materials science, 2021-08, Vol.56 (23), p.13227-13242</ispartof><rights>The Author(s) 2021</rights><rights>COPYRIGHT 2021 Springer</rights><rights>The Author(s) 2021. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c503t-149b45139049fc8da852d5eb31b16a6a64205b074cfcef16fe142cc48989793e3</citedby><cites>FETCH-LOGICAL-c503t-149b45139049fc8da852d5eb31b16a6a64205b074cfcef16fe142cc48989793e3</cites><orcidid>0000-0001-6584-6056</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-021-06125-4$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-021-06125-4$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Thauer, E.</creatorcontrib><creatorcontrib>Zakharova, G. S.</creatorcontrib><creatorcontrib>Andreikov, E. I.</creatorcontrib><creatorcontrib>Adam, V.</creatorcontrib><creatorcontrib>Wegener, S. A.</creatorcontrib><creatorcontrib>Nölke, J. -H.</creatorcontrib><creatorcontrib>Singer, L.</creatorcontrib><creatorcontrib>Ottmann, A.</creatorcontrib><creatorcontrib>Asyuda, A.</creatorcontrib><creatorcontrib>Zharnikov, M.</creatorcontrib><creatorcontrib>Kiselkov, D. M.</creatorcontrib><creatorcontrib>Zhu, Q.</creatorcontrib><creatorcontrib>Puzyrev, I. S.</creatorcontrib><creatorcontrib>Podval’naya, N. V.</creatorcontrib><creatorcontrib>Klingeler, R.</creatorcontrib><title>Novel synthesis and electrochemical investigations of ZnO/C composites for lithium-ion batteries</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>For the first time, ZnO/C composites were synthesized using zinc glycerolate as a precursor through one-step calcination under a nitrogen atmosphere. The effect of the heat treatment conditions on the structure, composition, morphology as well as on the electrochemical properties regarding application in lithium-ion batteries are investigated. The products obtained by calcination of the precursor in nitrogen at 400—800 °C consist of zinc oxide nanoparticles and amorphous carbon that is
in-situ
generated from organic components of the glycerolate precursor. When used as anode material for lithium-ion batteries, the as-prepared ZnO/C composite synthesized at a calcination temperature of 700 °C delivers initial discharge and charge capacities of 1061 and 671 mAh g
−1
at a current rate of 100 mA g
−1
and hence 1.5 times more than bare ZnO, which reaches only 749/439 mAh g
−1
. The native carbon improves the conductivity, allowing efficient electronic conductivity and Li-ion diffusion. By means of
ex-situ
XRD studies a two-step storage mechanism is proven.</description><subject>Anodes</subject><subject>Batteries</subject><subject>Carbon</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Composite materials</subject><subject>Crystallography and Scattering Methods</subject><subject>Electric properties</subject><subject>Electrochemical analysis</subject><subject>Electrode materials</subject><subject>Energy Materials</subject><subject>Heat treatment</subject><subject>Ion diffusion</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Materials Science</subject><subject>Morphology</subject><subject>Nanoparticles</subject><subject>Polymer Sciences</subject><subject>Precursors</subject><subject>Rechargeable batteries</subject><subject>Roasting</subject><subject>Solid Mechanics</subject><subject>Zinc oxide</subject><subject>Zinc oxides</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kctrVDEUh4MoOFb_AVcBVy7S5nkfyzL4KBQLPjZuYm7mZCbl3mTMyRT735s6QhkQOYsD4ftOTvIj5LXg54Lz_gIFH4xiXArGOyEN00_ISpheMT1w9ZSsOJeSSd2J5-QF4i3n3PRSrMiPT_kOZor3qe4AI1KXNhRm8LVkv4MlejfTmO4Aa9y6GnNCmgP9nm4u1tTnZZ8xVkAacqFzrLt4WFiD6ORqhRIBX5Jnwc0Ir_72M_Lt_buv64_s-ubD1frymnnDVWVCj5M2Qo1cj8EPGzcYuTEwKTGJzrXSkpuJ99oHD0F0AYSW3uthHMZ-VKDOyJvj3H3JPw9tXXubDyW1K600qsHCjOaR2roZbEwh1-L8EtHby64zg-FjLxp1_g-q1ebhQ3KCENv5ifD2RGhMhV916w6I9urL51NWHllfMmKBYPclLq7cW8HtQ5j2GKZtYdo_YVrdJHWUsMFpC-Xxdf-xfgO7XqAb</recordid><startdate>20210801</startdate><enddate>20210801</enddate><creator>Thauer, E.</creator><creator>Zakharova, G. 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S.</au><au>Andreikov, E. I.</au><au>Adam, V.</au><au>Wegener, S. A.</au><au>Nölke, J. -H.</au><au>Singer, L.</au><au>Ottmann, A.</au><au>Asyuda, A.</au><au>Zharnikov, M.</au><au>Kiselkov, D. M.</au><au>Zhu, Q.</au><au>Puzyrev, I. S.</au><au>Podval’naya, N. V.</au><au>Klingeler, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel synthesis and electrochemical investigations of ZnO/C composites for lithium-ion batteries</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2021-08-01</date><risdate>2021</risdate><volume>56</volume><issue>23</issue><spage>13227</spage><epage>13242</epage><pages>13227-13242</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>For the first time, ZnO/C composites were synthesized using zinc glycerolate as a precursor through one-step calcination under a nitrogen atmosphere. The effect of the heat treatment conditions on the structure, composition, morphology as well as on the electrochemical properties regarding application in lithium-ion batteries are investigated. The products obtained by calcination of the precursor in nitrogen at 400—800 °C consist of zinc oxide nanoparticles and amorphous carbon that is
in-situ
generated from organic components of the glycerolate precursor. When used as anode material for lithium-ion batteries, the as-prepared ZnO/C composite synthesized at a calcination temperature of 700 °C delivers initial discharge and charge capacities of 1061 and 671 mAh g
−1
at a current rate of 100 mA g
−1
and hence 1.5 times more than bare ZnO, which reaches only 749/439 mAh g
−1
. The native carbon improves the conductivity, allowing efficient electronic conductivity and Li-ion diffusion. By means of
ex-situ
XRD studies a two-step storage mechanism is proven.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-021-06125-4</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0001-6584-6056</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Anodes Batteries Carbon Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Composite materials Crystallography and Scattering Methods Electric properties Electrochemical analysis Electrode materials Energy Materials Heat treatment Ion diffusion Lithium Lithium-ion batteries Materials Science Morphology Nanoparticles Polymer Sciences Precursors Rechargeable batteries Roasting Solid Mechanics Zinc oxide Zinc oxides |
| title | Novel synthesis and electrochemical investigations of ZnO/C composites for lithium-ion batteries |
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