Recent development of magnetic nanomaterial-supported M(Salen) composites as recyclable heterogeneous catalysts
Metal complexes of Salen-type ligands [M(Salen)] were widely used as catalysts with high activity for coupling reactions, addition reactions and epoxidation reactions. However, homogeneous catalysts based on M(Salen) complexes are difficult to separate and recover. Therefore, it is of great signific...
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| Veröffentlicht in: | Chemical papers 2021-07, Vol.75 (7), p.2965-2980 |
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| creator | Min, Jie Xia, Zhenhao Zhang, Tiecheng Su, Hongying Zhi, Yunfei Shan, Shaoyun |
| description | Metal complexes of Salen-type ligands [M(Salen)] were widely used as catalysts with high activity for coupling reactions, addition reactions and epoxidation reactions. However, homogeneous catalysts based on M(Salen) complexes are difficult to separate and recover. Therefore, it is of great significance to find suitable supports to support M(Salen) complexes and obtain composites as separable and recyclable heterogeneous catalysts. Magnetic nanomaterials, which is widely researched as an inorganic nanosupports, are advantageous for the preparation of supported M(Salen) catalysts due to their characteristics of magnetic separation, good chemical stability and easy functionalization. In this review, research works on many types of the magnetic nanomaterial-supported M(Salen) catalysts, especially their preparations and applications as heterogeneous catalysts are discussed in detail. In addition, the advantages and disadvantages of different magnetic nanomaterials-supported M(Salen) composites are described, and some recommendations and references are provided for structure design of magnetic nanomaterial-supported M(Salen) catalyst with improved magnetic separation and catalytic efficiency. At last, limitations of magnetic nanomaterial-supported M(Salen), including structural instability, tedious multistep reactions and difficulty in industrial production, are discussed and their applications as heterogeneous catalysts are prospected. |
| doi_str_mv | 10.1007/s11696-021-01549-3 |
| format | Article |
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However, homogeneous catalysts based on M(Salen) complexes are difficult to separate and recover. Therefore, it is of great significance to find suitable supports to support M(Salen) complexes and obtain composites as separable and recyclable heterogeneous catalysts. Magnetic nanomaterials, which is widely researched as an inorganic nanosupports, are advantageous for the preparation of supported M(Salen) catalysts due to their characteristics of magnetic separation, good chemical stability and easy functionalization. In this review, research works on many types of the magnetic nanomaterial-supported M(Salen) catalysts, especially their preparations and applications as heterogeneous catalysts are discussed in detail. In addition, the advantages and disadvantages of different magnetic nanomaterials-supported M(Salen) composites are described, and some recommendations and references are provided for structure design of magnetic nanomaterial-supported M(Salen) catalyst with improved magnetic separation and catalytic efficiency. At last, limitations of magnetic nanomaterial-supported M(Salen), including structural instability, tedious multistep reactions and difficulty in industrial production, are discussed and their applications as heterogeneous catalysts are prospected.</description><identifier>ISSN: 2585-7290</identifier><identifier>ISSN: 0366-6352</identifier><identifier>EISSN: 1336-9075</identifier><identifier>DOI: 10.1007/s11696-021-01549-3</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Biochemistry ; Biotechnology ; Catalysts ; Chemical reactions ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Composite materials ; Coordination compounds ; Epoxidation ; Industrial Chemistry/Chemical Engineering ; Magnetic separation ; Materials Science ; Medicinal Chemistry ; Nanomaterials ; Review ; Structural stability</subject><ispartof>Chemical papers, 2021-07, Vol.75 (7), p.2965-2980</ispartof><rights>Institute of Chemistry, Slovak Academy of Sciences 2021</rights><rights>Institute of Chemistry, Slovak Academy of Sciences 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-42a939f9ef4ef1bdc4ced508d21d12801ffab6021f02efbb4c25aa0f2069edea3</citedby><cites>FETCH-LOGICAL-c356t-42a939f9ef4ef1bdc4ced508d21d12801ffab6021f02efbb4c25aa0f2069edea3</cites><orcidid>0000-0003-2950-3309</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11696-021-01549-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11696-021-01549-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Min, Jie</creatorcontrib><creatorcontrib>Xia, Zhenhao</creatorcontrib><creatorcontrib>Zhang, Tiecheng</creatorcontrib><creatorcontrib>Su, Hongying</creatorcontrib><creatorcontrib>Zhi, Yunfei</creatorcontrib><creatorcontrib>Shan, Shaoyun</creatorcontrib><title>Recent development of magnetic nanomaterial-supported M(Salen) composites as recyclable heterogeneous catalysts</title><title>Chemical papers</title><addtitle>Chem. Pap</addtitle><description>Metal complexes of Salen-type ligands [M(Salen)] were widely used as catalysts with high activity for coupling reactions, addition reactions and epoxidation reactions. However, homogeneous catalysts based on M(Salen) complexes are difficult to separate and recover. Therefore, it is of great significance to find suitable supports to support M(Salen) complexes and obtain composites as separable and recyclable heterogeneous catalysts. Magnetic nanomaterials, which is widely researched as an inorganic nanosupports, are advantageous for the preparation of supported M(Salen) catalysts due to their characteristics of magnetic separation, good chemical stability and easy functionalization. In this review, research works on many types of the magnetic nanomaterial-supported M(Salen) catalysts, especially their preparations and applications as heterogeneous catalysts are discussed in detail. In addition, the advantages and disadvantages of different magnetic nanomaterials-supported M(Salen) composites are described, and some recommendations and references are provided for structure design of magnetic nanomaterial-supported M(Salen) catalyst with improved magnetic separation and catalytic efficiency. At last, limitations of magnetic nanomaterial-supported M(Salen), including structural instability, tedious multistep reactions and difficulty in industrial production, are discussed and their applications as heterogeneous catalysts are prospected.</description><subject>Biochemistry</subject><subject>Biotechnology</subject><subject>Catalysts</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Composite materials</subject><subject>Coordination compounds</subject><subject>Epoxidation</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Magnetic separation</subject><subject>Materials Science</subject><subject>Medicinal Chemistry</subject><subject>Nanomaterials</subject><subject>Review</subject><subject>Structural stability</subject><issn>2585-7290</issn><issn>0366-6352</issn><issn>1336-9075</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAUhYMoOIzzB1wF3OgimlcfWcrgC0YEH-uQpjdjpW1qkgrz7-1YwZ2rexbnO4d7EDpl9JJRWlxFxnKVE8oZoSyTiogDtGBC5ETRIjtEC56VGSm4osdoFWNTUSkLwcu8WCD_DBb6hGv4gtYP3V57hzuz7SE1Fvem951JEBrTkjgOgw8Javx4_mJa6C-w9d3gY5MgYhNxALuzralawO8wQX4LPfgxYmuSaXcxxRN05EwbYfV7l-jt9uZ1fU82T3cP6-sNsSLLE5HcKKGcAifBsaq20kKd0bLmrGa8pMw5U-XTx45ycFUlLc-MoY7TXEENRizR2Zw7BP85Qkz6w4-hnyo1zwTjSpRSTS4-u2zwMQZweghNZ8JOM6r32-p5Wz016Z9ttZggMUNxMvdbCH_R_1DfpoR_tw</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Min, Jie</creator><creator>Xia, Zhenhao</creator><creator>Zhang, Tiecheng</creator><creator>Su, Hongying</creator><creator>Zhi, Yunfei</creator><creator>Shan, Shaoyun</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-2950-3309</orcidid></search><sort><creationdate>20210701</creationdate><title>Recent development of magnetic nanomaterial-supported M(Salen) composites as recyclable heterogeneous catalysts</title><author>Min, Jie ; Xia, Zhenhao ; Zhang, Tiecheng ; Su, Hongying ; Zhi, Yunfei ; Shan, Shaoyun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-42a939f9ef4ef1bdc4ced508d21d12801ffab6021f02efbb4c25aa0f2069edea3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Biochemistry</topic><topic>Biotechnology</topic><topic>Catalysts</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Composite materials</topic><topic>Coordination compounds</topic><topic>Epoxidation</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Magnetic separation</topic><topic>Materials Science</topic><topic>Medicinal Chemistry</topic><topic>Nanomaterials</topic><topic>Review</topic><topic>Structural stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Min, Jie</creatorcontrib><creatorcontrib>Xia, Zhenhao</creatorcontrib><creatorcontrib>Zhang, Tiecheng</creatorcontrib><creatorcontrib>Su, Hongying</creatorcontrib><creatorcontrib>Zhi, Yunfei</creatorcontrib><creatorcontrib>Shan, Shaoyun</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical papers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Min, Jie</au><au>Xia, Zhenhao</au><au>Zhang, Tiecheng</au><au>Su, Hongying</au><au>Zhi, Yunfei</au><au>Shan, Shaoyun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent development of magnetic nanomaterial-supported M(Salen) composites as recyclable heterogeneous catalysts</atitle><jtitle>Chemical papers</jtitle><stitle>Chem. 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| subjects | Biochemistry Biotechnology Catalysts Chemical reactions Chemistry Chemistry and Materials Science Chemistry/Food Science Composite materials Coordination compounds Epoxidation Industrial Chemistry/Chemical Engineering Magnetic separation Materials Science Medicinal Chemistry Nanomaterials Review Structural stability |
| title | Recent development of magnetic nanomaterial-supported M(Salen) composites as recyclable heterogeneous catalysts |
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