Hydrogen Behavior in Top Gate Amorphous In-Ga-Zn-O Device Fabrication Process During Gate Insulator Deposition and Gate Insulator Etching

The hydrogen behavior in the amorphous In-Ga-Zn-O (a-IGZO) thin-film layer according to the device process with top gate structure was quantitatively investigated. The hydrogen quantities in the a-IGZO thin-film layer with gate insulator (w/GI) and after GI dry-etching were increased by 3.40\times...

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Veröffentlicht in:IEEE transactions on electron devices 2021-06, Vol.68 (6), p.2723-2728
Hauptverfasser: Song, Aeran, Hong, Hyun Min, Son, Kyoung Seok, Lim, Jun Hyung, Chung, Kwun-Bum
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Hong, Hyun Min
Son, Kyoung Seok
Lim, Jun Hyung
Chung, Kwun-Bum
description The hydrogen behavior in the amorphous In-Ga-Zn-O (a-IGZO) thin-film layer according to the device process with top gate structure was quantitatively investigated. The hydrogen quantities in the a-IGZO thin-film layer with gate insulator (w/GI) and after GI dry-etching were increased by 3.40\times 10^{20} and 2.50\times 10^{\vphantom {D^{a}}20} /cm 3 , respectively, in comparison with without GI (w/o GI). In addition, the calculated carrier concentration of the a-IGZO thin-film layer by band alignment increased by 1.60\times 10^{18} and 7.38\times 10^{17}/cm^{3} , respectively, compared with w/o GI. Due to the plasma effect, the hydrogen quantity and the calculated carrier concentration in the a-IGZO thin-film layer after GI dry-etching slightly decreased from w/GI by 0.90 \times 10^{20} and 8.62 \times 10^{17} /cm 3 , respectively. The increased hydrogen quantity in the a-IGZO thin-film layer can contribute to increase in carrier concentration by providing free electrons through the hydrogen reaction with oxygen ions or transition of hydrogen state. Here, we attempted to correlate the hydrogen effect to the increase of the carrier concentration through various physical analysis.
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The hydrogen quantities in the a-IGZO thin-film layer with gate insulator (w/GI) and after GI dry-etching were increased by <inline-formula> <tex-math notation="LaTeX">3.40\times 10^{20} </tex-math></inline-formula> and <inline-formula> <tex-math notation="LaTeX">2.50\times 10^{\vphantom {D^{a}}20} </tex-math></inline-formula>/cm 3 , respectively, in comparison with without GI (w/o GI). In addition, the calculated carrier concentration of the a-IGZO thin-film layer by band alignment increased by <inline-formula> <tex-math notation="LaTeX">1.60\times 10^{18} </tex-math></inline-formula> and <inline-formula> <tex-math notation="LaTeX">7.38\times 10^{17}/cm^{3} </tex-math></inline-formula>, respectively, compared with w/o GI. Due to the plasma effect, the hydrogen quantity and the calculated carrier concentration in the a-IGZO thin-film layer after GI dry-etching slightly decreased from w/GI by <inline-formula> <tex-math notation="LaTeX">0.90 \times 10^{20} </tex-math></inline-formula> and <inline-formula> <tex-math notation="LaTeX">8.62 \times 10^{17} </tex-math></inline-formula>/cm 3 , respectively. The increased hydrogen quantity in the a-IGZO thin-film layer can contribute to increase in carrier concentration by providing free electrons through the hydrogen reaction with oxygen ions or transition of hydrogen state. Here, we attempted to correlate the hydrogen effect to the increase of the carrier concentration through various physical analysis.]]></description><identifier>ISSN: 0018-9383</identifier><identifier>EISSN: 1557-9646</identifier><identifier>DOI: 10.1109/TED.2021.3074120</identifier><identifier>CODEN: IETDAI</identifier><language>eng</language><publisher>New York: IEEE</publisher><subject>Amorphous In–Ga–Zn–O (a-IGZO) ; band alignment ; Bonding ; Carrier density ; elastic recoil detection (ERD) ; Etching ; Free electrons ; gate insulator (GI) ; Hydrogen ; hydrogen behavior ; Indium gallium zinc oxide ; Insulators ; Ions ; Logic gates ; Mathematical analysis ; Oxygen ions ; Silicon compounds ; Thin film transistors</subject><ispartof>IEEE transactions on electron devices, 2021-06, Vol.68 (6), p.2723-2728</ispartof><rights>Copyright The Institute of Electrical and Electronics Engineers, Inc. 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The hydrogen quantities in the a-IGZO thin-film layer with gate insulator (w/GI) and after GI dry-etching were increased by <inline-formula> <tex-math notation="LaTeX">3.40\times 10^{20} </tex-math></inline-formula> and <inline-formula> <tex-math notation="LaTeX">2.50\times 10^{\vphantom {D^{a}}20} </tex-math></inline-formula>/cm 3 , respectively, in comparison with without GI (w/o GI). In addition, the calculated carrier concentration of the a-IGZO thin-film layer by band alignment increased by <inline-formula> <tex-math notation="LaTeX">1.60\times 10^{18} </tex-math></inline-formula> and <inline-formula> <tex-math notation="LaTeX">7.38\times 10^{17}/cm^{3} </tex-math></inline-formula>, respectively, compared with w/o GI. Due to the plasma effect, the hydrogen quantity and the calculated carrier concentration in the a-IGZO thin-film layer after GI dry-etching slightly decreased from w/GI by <inline-formula> <tex-math notation="LaTeX">0.90 \times 10^{20} </tex-math></inline-formula> and <inline-formula> <tex-math notation="LaTeX">8.62 \times 10^{17} </tex-math></inline-formula>/cm 3 , respectively. The increased hydrogen quantity in the a-IGZO thin-film layer can contribute to increase in carrier concentration by providing free electrons through the hydrogen reaction with oxygen ions or transition of hydrogen state. Here, we attempted to correlate the hydrogen effect to the increase of the carrier concentration through various physical analysis.]]></description><subject>Amorphous In–Ga–Zn–O (a-IGZO)</subject><subject>band alignment</subject><subject>Bonding</subject><subject>Carrier density</subject><subject>elastic recoil detection (ERD)</subject><subject>Etching</subject><subject>Free electrons</subject><subject>gate insulator (GI)</subject><subject>Hydrogen</subject><subject>hydrogen behavior</subject><subject>Indium gallium zinc oxide</subject><subject>Insulators</subject><subject>Ions</subject><subject>Logic gates</subject><subject>Mathematical analysis</subject><subject>Oxygen ions</subject><subject>Silicon compounds</subject><subject>Thin film transistors</subject><issn>0018-9383</issn><issn>1557-9646</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>RIE</sourceid><recordid>eNpdkMFqGzEQhkVoIG6Se6AXQc_rzkharXVMY8cxBNKDc8llkbWztkwibaVdgx8hb91NHXroaRjm-_-Bj7EbhCkimB_rxXwqQOBUQqVQwBmbYFlWhdFKf2ETAJwVRs7kBfua835ctVJiwt4fjk2KWwr8J-3swcfEfeDr2PGl7YnfvsXU7eKQ-SoUS1u8hOKJz-ngHfF7u0ne2d7HwH-l6ChnPh-SD9tTdhXy8Gr7sXFOXcz-L2hD8_910bvdGLpi5619zXT9OS_Z8_1iffdQPD4tV3e3j4UTBvtCVcpYLF3TalkKvdGkNxYlVsYJsNAYglY6UNQCVUq1zmmsUJjGaZhJM5OX7Pupt0vx90C5r_dxSGF8WYtSAqJSGkcKTpRLMedEbd0l_2bTsUaoP4TXo_D6Q3j9KXyMfDtFPBH9w41CU4GRfwBgLHwE</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Song, Aeran</creator><creator>Hong, Hyun Min</creator><creator>Son, Kyoung Seok</creator><creator>Lim, Jun Hyung</creator><creator>Chung, Kwun-Bum</creator><general>IEEE</general><general>The Institute of Electrical and Electronics Engineers, Inc. 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The hydrogen quantities in the a-IGZO thin-film layer with gate insulator (w/GI) and after GI dry-etching were increased by <inline-formula> <tex-math notation="LaTeX">3.40\times 10^{20} </tex-math></inline-formula> and <inline-formula> <tex-math notation="LaTeX">2.50\times 10^{\vphantom {D^{a}}20} </tex-math></inline-formula>/cm 3 , respectively, in comparison with without GI (w/o GI). In addition, the calculated carrier concentration of the a-IGZO thin-film layer by band alignment increased by <inline-formula> <tex-math notation="LaTeX">1.60\times 10^{18} </tex-math></inline-formula> and <inline-formula> <tex-math notation="LaTeX">7.38\times 10^{17}/cm^{3} </tex-math></inline-formula>, respectively, compared with w/o GI. Due to the plasma effect, the hydrogen quantity and the calculated carrier concentration in the a-IGZO thin-film layer after GI dry-etching slightly decreased from w/GI by <inline-formula> <tex-math notation="LaTeX">0.90 \times 10^{20} </tex-math></inline-formula> and <inline-formula> <tex-math notation="LaTeX">8.62 \times 10^{17} </tex-math></inline-formula>/cm 3 , respectively. The increased hydrogen quantity in the a-IGZO thin-film layer can contribute to increase in carrier concentration by providing free electrons through the hydrogen reaction with oxygen ions or transition of hydrogen state. Here, we attempted to correlate the hydrogen effect to the increase of the carrier concentration through various physical analysis.]]></abstract><cop>New York</cop><pub>IEEE</pub><doi>10.1109/TED.2021.3074120</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-8877-5297</orcidid></addata></record>
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subjects Amorphous In–Ga–Zn–O (a-IGZO)
band alignment
Bonding
Carrier density
elastic recoil detection (ERD)
Etching
Free electrons
gate insulator (GI)
Hydrogen
hydrogen behavior
Indium gallium zinc oxide
Insulators
Ions
Logic gates
Mathematical analysis
Oxygen ions
Silicon compounds
Thin film transistors
title Hydrogen Behavior in Top Gate Amorphous In-Ga-Zn-O Device Fabrication Process During Gate Insulator Deposition and Gate Insulator Etching
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