Prediction of Joule–Thomson and Deviation Functions of Refrigerants at Low Pressure Using the Correlation Function

In this paper, we calculate Joule–Thomson, the enthalpy changes relative to the pressure and deviation functions at low pressure for refrigerant fluids in order to evaluate the performance of their correlation function. The studied refrigerants are R11, R123, R124, R134a, R143a, R152a, R141b, R142b,...

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2021-04, Vol.95 (Suppl 1), p.S140-S148
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description In this paper, we calculate Joule–Thomson, the enthalpy changes relative to the pressure and deviation functions at low pressure for refrigerant fluids in order to evaluate the performance of their correlation function. The studied refrigerants are R11, R123, R124, R134a, R143a, R152a, R141b, R142b, R227ea, and R236ea. The studied corresponding state principle is the one suggested by Meng et al. In addition, to compare with the data obtained by others, Boyle temperature, Boyle volume, and maximum inversion temperature were also calculated using the correlation. The obtained results show that the correlation equation presented has a good ability to predict the thermophysical properties of materials and their deviation from the ideal state over a wide range of temperatures.
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The studied refrigerants are R11, R123, R124, R134a, R143a, R152a, R141b, R142b, R227ea, and R236ea. The studied corresponding state principle is the one suggested by Meng et al. In addition, to compare with the data obtained by others, Boyle temperature, Boyle volume, and maximum inversion temperature were also calculated using the correlation. 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subjects Chemistry
Chemistry and Materials Science
Corresponding states
Deviation
Enthalpy
Low pressure
Material properties
Mathematical analysis
Physical Chemistry
Refrigerants
Structure of Matter and Quantum Chemistry
Thermophysical properties
title Prediction of Joule–Thomson and Deviation Functions of Refrigerants at Low Pressure Using the Correlation Function
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