Swelling and dissolution of cellulose in binary systems of three ionic liquids and three co-solvents
The dissolution of cellulose is a critical step for the efficient utilization of this renewable resource as a starting material for high value-added chemical and biofuel production. In this study, three aprotic solvents were chosen to couple with three ionic liquids (ILs) as binary solvent systems f...
Gespeichert in:
| Veröffentlicht in: | Cellulose (London) 2021-05, Vol.28 (8), p.4643-4653 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4653 |
|---|---|
| container_issue | 8 |
| container_start_page | 4643 |
| container_title | Cellulose (London) |
| container_volume | 28 |
| creator | Zhang, Lihua Huang, Cong Zhang, Chenrui Pan, Hui |
| description | The dissolution of cellulose is a critical step for the efficient utilization of this renewable resource as a starting material for high value-added chemical and biofuel production. In this study, three aprotic solvents were chosen to couple with three ionic liquids (ILs) as binary solvent systems for cellulose dissolution. The percentage of dissolved cellulose of each IL/co-solvent was evaluated and the crystallinity index (CrI) of the undissolved cellulose residues after dissolution were investigated by XRD. Dimethyl sulfoxide exhibited the most effective synergistic interaction with the ILs among three co-solvents for cellulose dissolution. In general, the higher percentage of dissolved cellulose of the IL/co-solvent binary system, the lower CrI value of the undissolved cellulose residue after dissolution. In addition, the dissolution of cellulosic materials with different crystallinity and degree of polymerization indicated that the crystallinity of a cellulosic material played a more dominating role than degree of polymerization in its dissolution process. The hydrogen bond basicity (
β
value) of selected IL/co-solvent binary system was also calculated. The results showed that the
β
value of a binary IL/co-solvent system exhibited different trend than neat IL in terms of the cellulose dissolution ability, which should be attributed to the co-solvent effect.
Graphic abstract |
| doi_str_mv | 10.1007/s10570-021-03844-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2528312297</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2528312297</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-cc3ca3101b0bb6eed28191ccab9503b896fbd2a3d96f220c87301b6e0996291a3</originalsourceid><addsrcrecordid>eNp9kEtLAzEUhYMoWKt_wFXAdfQmmVeWUnxBwYUK7sJMJlNTpkmbO6P47007gjtXN9zvnHPJIeSSwzUHKG-QQ14CA8EZyCrLWHZEZjwvBasq8X5MZqAKlbBUp-QMcQ0AqhR8RtqXL9v3zq9o7VvaOsTQj4MLnoaOmoTGPqClztPG-Tp-U_zGwW5wj4ePaBMK3hnau93oWjykTHsTWMr6tH7Ac3LS1T3ai985J2_3d6-LR7Z8fnha3C6ZkXkxMGOkqSUH3kDTFNa2ouKKG1M3KgfZVKromlbUsk0PIcBUpUzawoJShVC8lnNyNeVuY9iNFge9DmP06aQWuagkF0KVSSUmlYkBMdpOb6PbpL9pDnrfpp7a1KlNfWhTZ8kkJxMmsV_Z-Bf9j-sHz9d4_w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2528312297</pqid></control><display><type>article</type><title>Swelling and dissolution of cellulose in binary systems of three ionic liquids and three co-solvents</title><source>SpringerLink (Online service)</source><creator>Zhang, Lihua ; Huang, Cong ; Zhang, Chenrui ; Pan, Hui</creator><creatorcontrib>Zhang, Lihua ; Huang, Cong ; Zhang, Chenrui ; Pan, Hui</creatorcontrib><description>The dissolution of cellulose is a critical step for the efficient utilization of this renewable resource as a starting material for high value-added chemical and biofuel production. In this study, three aprotic solvents were chosen to couple with three ionic liquids (ILs) as binary solvent systems for cellulose dissolution. The percentage of dissolved cellulose of each IL/co-solvent was evaluated and the crystallinity index (CrI) of the undissolved cellulose residues after dissolution were investigated by XRD. Dimethyl sulfoxide exhibited the most effective synergistic interaction with the ILs among three co-solvents for cellulose dissolution. In general, the higher percentage of dissolved cellulose of the IL/co-solvent binary system, the lower CrI value of the undissolved cellulose residue after dissolution. In addition, the dissolution of cellulosic materials with different crystallinity and degree of polymerization indicated that the crystallinity of a cellulosic material played a more dominating role than degree of polymerization in its dissolution process. The hydrogen bond basicity (
β
value) of selected IL/co-solvent binary system was also calculated. The results showed that the
β
value of a binary IL/co-solvent system exhibited different trend than neat IL in terms of the cellulose dissolution ability, which should be attributed to the co-solvent effect.
Graphic abstract</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-021-03844-4</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Basicity ; Binary system ; Binary systems ; Biofuels ; Bioorganic Chemistry ; Cellulose ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Crystal structure ; Crystallinity ; Degree of polymerization ; Dimethyl sulfoxide ; Dissolution ; Glass ; Hydrogen bonds ; Ionic liquids ; Natural Materials ; Organic Chemistry ; Original Research ; Physical Chemistry ; Polymer Sciences ; Polymerization ; Renewable resources ; Residues ; Solvent effect ; Solvents ; Sustainable Development</subject><ispartof>Cellulose (London), 2021-05, Vol.28 (8), p.4643-4653</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-cc3ca3101b0bb6eed28191ccab9503b896fbd2a3d96f220c87301b6e0996291a3</citedby><cites>FETCH-LOGICAL-c356t-cc3ca3101b0bb6eed28191ccab9503b896fbd2a3d96f220c87301b6e0996291a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-021-03844-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-021-03844-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Zhang, Lihua</creatorcontrib><creatorcontrib>Huang, Cong</creatorcontrib><creatorcontrib>Zhang, Chenrui</creatorcontrib><creatorcontrib>Pan, Hui</creatorcontrib><title>Swelling and dissolution of cellulose in binary systems of three ionic liquids and three co-solvents</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>The dissolution of cellulose is a critical step for the efficient utilization of this renewable resource as a starting material for high value-added chemical and biofuel production. In this study, three aprotic solvents were chosen to couple with three ionic liquids (ILs) as binary solvent systems for cellulose dissolution. The percentage of dissolved cellulose of each IL/co-solvent was evaluated and the crystallinity index (CrI) of the undissolved cellulose residues after dissolution were investigated by XRD. Dimethyl sulfoxide exhibited the most effective synergistic interaction with the ILs among three co-solvents for cellulose dissolution. In general, the higher percentage of dissolved cellulose of the IL/co-solvent binary system, the lower CrI value of the undissolved cellulose residue after dissolution. In addition, the dissolution of cellulosic materials with different crystallinity and degree of polymerization indicated that the crystallinity of a cellulosic material played a more dominating role than degree of polymerization in its dissolution process. The hydrogen bond basicity (
β
value) of selected IL/co-solvent binary system was also calculated. The results showed that the
β
value of a binary IL/co-solvent system exhibited different trend than neat IL in terms of the cellulose dissolution ability, which should be attributed to the co-solvent effect.
Graphic abstract</description><subject>Basicity</subject><subject>Binary system</subject><subject>Binary systems</subject><subject>Biofuels</subject><subject>Bioorganic Chemistry</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Degree of polymerization</subject><subject>Dimethyl sulfoxide</subject><subject>Dissolution</subject><subject>Glass</subject><subject>Hydrogen bonds</subject><subject>Ionic liquids</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Renewable resources</subject><subject>Residues</subject><subject>Solvent effect</subject><subject>Solvents</subject><subject>Sustainable Development</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kEtLAzEUhYMoWKt_wFXAdfQmmVeWUnxBwYUK7sJMJlNTpkmbO6P47007gjtXN9zvnHPJIeSSwzUHKG-QQ14CA8EZyCrLWHZEZjwvBasq8X5MZqAKlbBUp-QMcQ0AqhR8RtqXL9v3zq9o7VvaOsTQj4MLnoaOmoTGPqClztPG-Tp-U_zGwW5wj4ePaBMK3hnau93oWjykTHsTWMr6tH7Ac3LS1T3ai985J2_3d6-LR7Z8fnha3C6ZkXkxMGOkqSUH3kDTFNa2ouKKG1M3KgfZVKromlbUsk0PIcBUpUzawoJShVC8lnNyNeVuY9iNFge9DmP06aQWuagkF0KVSSUmlYkBMdpOb6PbpL9pDnrfpp7a1KlNfWhTZ8kkJxMmsV_Z-Bf9j-sHz9d4_w</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Zhang, Lihua</creator><creator>Huang, Cong</creator><creator>Zhang, Chenrui</creator><creator>Pan, Hui</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20210501</creationdate><title>Swelling and dissolution of cellulose in binary systems of three ionic liquids and three co-solvents</title><author>Zhang, Lihua ; Huang, Cong ; Zhang, Chenrui ; Pan, Hui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-cc3ca3101b0bb6eed28191ccab9503b896fbd2a3d96f220c87301b6e0996291a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Basicity</topic><topic>Binary system</topic><topic>Binary systems</topic><topic>Biofuels</topic><topic>Bioorganic Chemistry</topic><topic>Cellulose</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Degree of polymerization</topic><topic>Dimethyl sulfoxide</topic><topic>Dissolution</topic><topic>Glass</topic><topic>Hydrogen bonds</topic><topic>Ionic liquids</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Renewable resources</topic><topic>Residues</topic><topic>Solvent effect</topic><topic>Solvents</topic><topic>Sustainable Development</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Lihua</creatorcontrib><creatorcontrib>Huang, Cong</creatorcontrib><creatorcontrib>Zhang, Chenrui</creatorcontrib><creatorcontrib>Pan, Hui</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>https://resources.nclive.org/materials</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Lihua</au><au>Huang, Cong</au><au>Zhang, Chenrui</au><au>Pan, Hui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Swelling and dissolution of cellulose in binary systems of three ionic liquids and three co-solvents</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2021-05-01</date><risdate>2021</risdate><volume>28</volume><issue>8</issue><spage>4643</spage><epage>4653</epage><pages>4643-4653</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>The dissolution of cellulose is a critical step for the efficient utilization of this renewable resource as a starting material for high value-added chemical and biofuel production. In this study, three aprotic solvents were chosen to couple with three ionic liquids (ILs) as binary solvent systems for cellulose dissolution. The percentage of dissolved cellulose of each IL/co-solvent was evaluated and the crystallinity index (CrI) of the undissolved cellulose residues after dissolution were investigated by XRD. Dimethyl sulfoxide exhibited the most effective synergistic interaction with the ILs among three co-solvents for cellulose dissolution. In general, the higher percentage of dissolved cellulose of the IL/co-solvent binary system, the lower CrI value of the undissolved cellulose residue after dissolution. In addition, the dissolution of cellulosic materials with different crystallinity and degree of polymerization indicated that the crystallinity of a cellulosic material played a more dominating role than degree of polymerization in its dissolution process. The hydrogen bond basicity (
β
value) of selected IL/co-solvent binary system was also calculated. The results showed that the
β
value of a binary IL/co-solvent system exhibited different trend than neat IL in terms of the cellulose dissolution ability, which should be attributed to the co-solvent effect.
Graphic abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-021-03844-4</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0969-0239 |
| ispartof | Cellulose (London), 2021-05, Vol.28 (8), p.4643-4653 |
| issn | 0969-0239 1572-882X |
| language | eng |
| recordid | cdi_proquest_journals_2528312297 |
| source | SpringerLink (Online service) |
| subjects | Basicity Binary system Binary systems Biofuels Bioorganic Chemistry Cellulose Ceramics Chemistry Chemistry and Materials Science Composites Crystal structure Crystallinity Degree of polymerization Dimethyl sulfoxide Dissolution Glass Hydrogen bonds Ionic liquids Natural Materials Organic Chemistry Original Research Physical Chemistry Polymer Sciences Polymerization Renewable resources Residues Solvent effect Solvents Sustainable Development |
| title | Swelling and dissolution of cellulose in binary systems of three ionic liquids and three co-solvents |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T08%3A19%3A26IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Swelling%20and%20dissolution%20of%20cellulose%20in%20binary%20systems%20of%20three%20ionic%20liquids%20and%20three%20co-solvents&rft.jtitle=Cellulose%20(London)&rft.au=Zhang,%20Lihua&rft.date=2021-05-01&rft.volume=28&rft.issue=8&rft.spage=4643&rft.epage=4653&rft.pages=4643-4653&rft.issn=0969-0239&rft.eissn=1572-882X&rft_id=info:doi/10.1007/s10570-021-03844-4&rft_dat=%3Cproquest_cross%3E2528312297%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2528312297&rft_id=info:pmid/&rfr_iscdi=true |