Biogeochemical causes of sixty-year trends and seasonal variations of river water properties in a large European basin
We evaluated long-term trends and seasonal variations in the major physical–chemical properties of the circum-neutral Slapy reservoir (Vltava, Czech Republic) from 1960 to 2019. Mean annual water temperature increased by 2.1 °C, flow maxima shifted by ~ 13 days from the early April to mid-March, and...
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| Veröffentlicht in: | Biogeochemistry 2021-05, Vol.154 (1), p.81-98 |
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| description | We evaluated long-term trends and seasonal variations in the major physical–chemical properties of the circum-neutral Slapy reservoir (Vltava, Czech Republic) from 1960 to 2019. Mean annual water temperature increased by 2.1 °C, flow maxima shifted by ~ 13 days from the early April to mid-March, and the onset of thermal stratification of water column and spring algal peaks advanced by 19 and 21 days, respectively, due to climate warming. Concentrations of major ions, phosphorus (P), and chlorophyll increased from the 1960s to the 1990–2000s, then decreased due to changing agricultural practices and legislation, intensified wastewater treatment, and decreasing atmospheric pollution. Concentrations of dissolved organic carbon (DOC) decreased from 1960 to the 1990s due to improved wastewater treatment, then began to increase in response to climate change and reduced acidic deposition. Concentrations of water constituents exhibited varying individual long-term and seasonal patterns due to the differing effects of following major processes on their production/removal in the catchment-river system: (1) applications of synthetic fertilizers, liming and farmland draining (NO
3
−
, SO
4
2−
, Cl
−
, Ca
2+
, Mg
2+
, K
+
, and HCO
3
−
), (2) wastewater production and treatment (DOC, P, N forms), (3) road de-icing (Cl
−
and Na
+
), (4) atmospheric pollution (SO
4
2−
), (5) climate change (DOC), and (6) the aging of reservoirs (NH
4
+
). The water pH increased until the early 1990s, then decreased and exhibited pronounced seasonal variations, integrating the effects of changing external acidity sources and in-lake H
+
sources and sinks (i.e., microbial CO
2
production/consumption and availability and transformations of inorganic N), and changes in water buffering capacity. Anthropogenic and climatic effects, reservoir aging, and changes in water eutrophication thus may significantly affect water pH also in circum-neutral systems. |
| doi_str_mv | 10.1007/s10533-021-00800-z |
| format | Article |
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3
−
, SO
4
2−
, Cl
−
, Ca
2+
, Mg
2+
, K
+
, and HCO
3
−
), (2) wastewater production and treatment (DOC, P, N forms), (3) road de-icing (Cl
−
and Na
+
), (4) atmospheric pollution (SO
4
2−
), (5) climate change (DOC), and (6) the aging of reservoirs (NH
4
+
). The water pH increased until the early 1990s, then decreased and exhibited pronounced seasonal variations, integrating the effects of changing external acidity sources and in-lake H
+
sources and sinks (i.e., microbial CO
2
production/consumption and availability and transformations of inorganic N), and changes in water buffering capacity. Anthropogenic and climatic effects, reservoir aging, and changes in water eutrophication thus may significantly affect water pH also in circum-neutral systems.</description><identifier>ISSN: 0168-2563</identifier><identifier>EISSN: 1573-515X</identifier><identifier>DOI: 10.1007/s10533-021-00800-z</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Acid deposition ; Acidity ; Ageing ; Aging ; Agricultural land ; Agricultural practices ; Agricultural wastes ; Agrochemicals ; Air pollution ; Algae ; Anthropogenic factors ; Biogeochemistry ; Biogeosciences ; Calcium ; Calcium ions ; Carbon dioxide ; Catchment area ; Chemical properties ; Chemicophysical properties ; Chlorophyll ; Chlorophylls ; Climate change ; Climate effects ; Deicing ; Dissolved organic carbon ; Drainage systems ; Earth and Environmental Science ; Earth Sciences ; Ecosystems ; Environmental Chemistry ; Eutrophication ; Fertilizers ; Global warming ; Lakes ; Legislation ; Life Sciences ; Liming ; Magnesium ; Microorganisms ; pH effects ; Phosphorus ; Pollution ; Pollution control ; Reservoirs ; River catchments ; River water ; Rivers ; Seasonal variation ; Seasonal variations ; Thermal stratification ; Trends ; Wastewater treatment ; Water circulation ; Water column ; Water properties ; Water stratification ; Water temperature ; Water treatment</subject><ispartof>Biogeochemistry, 2021-05, Vol.154 (1), p.81-98</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-ad13c53e128568b3ee0e9dda0e97eaa1d88a21f23911c466ebc599ae40fd42713</citedby><cites>FETCH-LOGICAL-c363t-ad13c53e128568b3ee0e9dda0e97eaa1d88a21f23911c466ebc599ae40fd42713</cites><orcidid>0000-0002-4409-4032</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10533-021-00800-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10533-021-00800-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Kopáček, Jiří</creatorcontrib><creatorcontrib>Hejzlar, Josef</creatorcontrib><creatorcontrib>Porcal, Petr</creatorcontrib><creatorcontrib>Znachor, Petr</creatorcontrib><title>Biogeochemical causes of sixty-year trends and seasonal variations of river water properties in a large European basin</title><title>Biogeochemistry</title><addtitle>Biogeochemistry</addtitle><description>We evaluated long-term trends and seasonal variations in the major physical–chemical properties of the circum-neutral Slapy reservoir (Vltava, Czech Republic) from 1960 to 2019. Mean annual water temperature increased by 2.1 °C, flow maxima shifted by ~ 13 days from the early April to mid-March, and the onset of thermal stratification of water column and spring algal peaks advanced by 19 and 21 days, respectively, due to climate warming. Concentrations of major ions, phosphorus (P), and chlorophyll increased from the 1960s to the 1990–2000s, then decreased due to changing agricultural practices and legislation, intensified wastewater treatment, and decreasing atmospheric pollution. Concentrations of dissolved organic carbon (DOC) decreased from 1960 to the 1990s due to improved wastewater treatment, then began to increase in response to climate change and reduced acidic deposition. Concentrations of water constituents exhibited varying individual long-term and seasonal patterns due to the differing effects of following major processes on their production/removal in the catchment-river system: (1) applications of synthetic fertilizers, liming and farmland draining (NO
3
−
, SO
4
2−
, Cl
−
, Ca
2+
, Mg
2+
, K
+
, and HCO
3
−
), (2) wastewater production and treatment (DOC, P, N forms), (3) road de-icing (Cl
−
and Na
+
), (4) atmospheric pollution (SO
4
2−
), (5) climate change (DOC), and (6) the aging of reservoirs (NH
4
+
). The water pH increased until the early 1990s, then decreased and exhibited pronounced seasonal variations, integrating the effects of changing external acidity sources and in-lake H
+
sources and sinks (i.e., microbial CO
2
production/consumption and availability and transformations of inorganic N), and changes in water buffering capacity. Anthropogenic and climatic effects, reservoir aging, and changes in water eutrophication thus may significantly affect water pH also in circum-neutral systems.</description><subject>Acid deposition</subject><subject>Acidity</subject><subject>Ageing</subject><subject>Aging</subject><subject>Agricultural land</subject><subject>Agricultural practices</subject><subject>Agricultural wastes</subject><subject>Agrochemicals</subject><subject>Air pollution</subject><subject>Algae</subject><subject>Anthropogenic factors</subject><subject>Biogeochemistry</subject><subject>Biogeosciences</subject><subject>Calcium</subject><subject>Calcium ions</subject><subject>Carbon dioxide</subject><subject>Catchment area</subject><subject>Chemical properties</subject><subject>Chemicophysical properties</subject><subject>Chlorophyll</subject><subject>Chlorophylls</subject><subject>Climate change</subject><subject>Climate effects</subject><subject>Deicing</subject><subject>Dissolved organic carbon</subject><subject>Drainage systems</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Ecosystems</subject><subject>Environmental Chemistry</subject><subject>Eutrophication</subject><subject>Fertilizers</subject><subject>Global warming</subject><subject>Lakes</subject><subject>Legislation</subject><subject>Life Sciences</subject><subject>Liming</subject><subject>Magnesium</subject><subject>Microorganisms</subject><subject>pH effects</subject><subject>Phosphorus</subject><subject>Pollution</subject><subject>Pollution control</subject><subject>Reservoirs</subject><subject>River catchments</subject><subject>River water</subject><subject>Rivers</subject><subject>Seasonal variation</subject><subject>Seasonal variations</subject><subject>Thermal stratification</subject><subject>Trends</subject><subject>Wastewater treatment</subject><subject>Water circulation</subject><subject>Water column</subject><subject>Water properties</subject><subject>Water stratification</subject><subject>Water temperature</subject><subject>Water treatment</subject><issn>0168-2563</issn><issn>1573-515X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kM1LAzEQxYMoWKv_gKeA5-gkafbjqMUvKHhR8Bam2dma0u7WZLfa_vWmreDNOczA8HuPx2PsUsK1BMhvogSjtQAlBUABILZHbCBNroWR5v2YDUBmhVAm06fsLMY5AJQ56AFb3_l2Rq37oKV3uOAO-0iRtzWP_rvbiA1h4F2gpoocm4pHwtg2CVxj8Nj5ttnDwa8p8C_s0l6FdkWh88nGNxz5AsOM-H2_e2PDpxh9c85OalxEuvi9Q_b2cP86fhKTl8fn8e1EOJ3pTmAltTOapCpMVkw1EVBZVZh2ToiyKgpUsla6lNKNsoymzpQl0gjqaqRyqYfs6uCbQn32FDs7b_uQ8kerjCq0VGkSpQ6UC22MgWq7Cn6JYWMl2F2_9tCvTf3afb92m0T6IIoJbmYU_qz_Uf0AgB6Adw</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Kopáček, Jiří</creator><creator>Hejzlar, Josef</creator><creator>Porcal, Petr</creator><creator>Znachor, Petr</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QL</scope><scope>7SN</scope><scope>7ST</scope><scope>7T7</scope><scope>7UA</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88I</scope><scope>8AO</scope><scope>8FD</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>FR3</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>H96</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>L.G</scope><scope>LK8</scope><scope>M0S</scope><scope>M2P</scope><scope>M7P</scope><scope>P64</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0002-4409-4032</orcidid></search><sort><creationdate>20210501</creationdate><title>Biogeochemical causes of sixty-year trends and seasonal variations of river water properties in a large European basin</title><author>Kopáček, Jiří ; Hejzlar, Josef ; Porcal, Petr ; Znachor, Petr</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-ad13c53e128568b3ee0e9dda0e97eaa1d88a21f23911c466ebc599ae40fd42713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acid deposition</topic><topic>Acidity</topic><topic>Ageing</topic><topic>Aging</topic><topic>Agricultural land</topic><topic>Agricultural practices</topic><topic>Agricultural wastes</topic><topic>Agrochemicals</topic><topic>Air pollution</topic><topic>Algae</topic><topic>Anthropogenic factors</topic><topic>Biogeochemistry</topic><topic>Biogeosciences</topic><topic>Calcium</topic><topic>Calcium ions</topic><topic>Carbon dioxide</topic><topic>Catchment area</topic><topic>Chemical properties</topic><topic>Chemicophysical properties</topic><topic>Chlorophyll</topic><topic>Chlorophylls</topic><topic>Climate change</topic><topic>Climate effects</topic><topic>Deicing</topic><topic>Dissolved organic carbon</topic><topic>Drainage systems</topic><topic>Earth and Environmental Science</topic><topic>Earth Sciences</topic><topic>Ecosystems</topic><topic>Environmental Chemistry</topic><topic>Eutrophication</topic><topic>Fertilizers</topic><topic>Global warming</topic><topic>Lakes</topic><topic>Legislation</topic><topic>Life Sciences</topic><topic>Liming</topic><topic>Magnesium</topic><topic>Microorganisms</topic><topic>pH effects</topic><topic>Phosphorus</topic><topic>Pollution</topic><topic>Pollution control</topic><topic>Reservoirs</topic><topic>River catchments</topic><topic>River water</topic><topic>Rivers</topic><topic>Seasonal variation</topic><topic>Seasonal variations</topic><topic>Thermal stratification</topic><topic>Trends</topic><topic>Wastewater treatment</topic><topic>Water circulation</topic><topic>Water column</topic><topic>Water properties</topic><topic>Water stratification</topic><topic>Water temperature</topic><topic>Water treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kopáček, Jiří</creatorcontrib><creatorcontrib>Hejzlar, Josef</creatorcontrib><creatorcontrib>Porcal, Petr</creatorcontrib><creatorcontrib>Znachor, Petr</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Water Resources Abstracts</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Science 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basin</atitle><jtitle>Biogeochemistry</jtitle><stitle>Biogeochemistry</stitle><date>2021-05-01</date><risdate>2021</risdate><volume>154</volume><issue>1</issue><spage>81</spage><epage>98</epage><pages>81-98</pages><issn>0168-2563</issn><eissn>1573-515X</eissn><abstract>We evaluated long-term trends and seasonal variations in the major physical–chemical properties of the circum-neutral Slapy reservoir (Vltava, Czech Republic) from 1960 to 2019. Mean annual water temperature increased by 2.1 °C, flow maxima shifted by ~ 13 days from the early April to mid-March, and the onset of thermal stratification of water column and spring algal peaks advanced by 19 and 21 days, respectively, due to climate warming. Concentrations of major ions, phosphorus (P), and chlorophyll increased from the 1960s to the 1990–2000s, then decreased due to changing agricultural practices and legislation, intensified wastewater treatment, and decreasing atmospheric pollution. Concentrations of dissolved organic carbon (DOC) decreased from 1960 to the 1990s due to improved wastewater treatment, then began to increase in response to climate change and reduced acidic deposition. Concentrations of water constituents exhibited varying individual long-term and seasonal patterns due to the differing effects of following major processes on their production/removal in the catchment-river system: (1) applications of synthetic fertilizers, liming and farmland draining (NO
3
−
, SO
4
2−
, Cl
−
, Ca
2+
, Mg
2+
, K
+
, and HCO
3
−
), (2) wastewater production and treatment (DOC, P, N forms), (3) road de-icing (Cl
−
and Na
+
), (4) atmospheric pollution (SO
4
2−
), (5) climate change (DOC), and (6) the aging of reservoirs (NH
4
+
). The water pH increased until the early 1990s, then decreased and exhibited pronounced seasonal variations, integrating the effects of changing external acidity sources and in-lake H
+
sources and sinks (i.e., microbial CO
2
production/consumption and availability and transformations of inorganic N), and changes in water buffering capacity. Anthropogenic and climatic effects, reservoir aging, and changes in water eutrophication thus may significantly affect water pH also in circum-neutral systems.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10533-021-00800-z</doi><tpages>18</tpages><orcidid>https://orcid.org/0000-0002-4409-4032</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| ispartof | Biogeochemistry, 2021-05, Vol.154 (1), p.81-98 |
| issn | 0168-2563 1573-515X |
| language | eng |
| recordid | cdi_proquest_journals_2528312222 |
| source | SpringerLink Journals |
| subjects | Acid deposition Acidity Ageing Aging Agricultural land Agricultural practices Agricultural wastes Agrochemicals Air pollution Algae Anthropogenic factors Biogeochemistry Biogeosciences Calcium Calcium ions Carbon dioxide Catchment area Chemical properties Chemicophysical properties Chlorophyll Chlorophylls Climate change Climate effects Deicing Dissolved organic carbon Drainage systems Earth and Environmental Science Earth Sciences Ecosystems Environmental Chemistry Eutrophication Fertilizers Global warming Lakes Legislation Life Sciences Liming Magnesium Microorganisms pH effects Phosphorus Pollution Pollution control Reservoirs River catchments River water Rivers Seasonal variation Seasonal variations Thermal stratification Trends Wastewater treatment Water circulation Water column Water properties Water stratification Water temperature Water treatment |
| title | Biogeochemical causes of sixty-year trends and seasonal variations of river water properties in a large European basin |
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