Effect of Sulfide Pollution on the Corrosion Behaviour of some Ni-Based Alloys in 3.5% NaCl Solution
In this work we are interested to investigate the influence of the presence of Cr, Mo and Fe alloying additions with Ni and to investigates the corrosion resistance of these alloys in chloride and chloride-sulfide containing solutions. The corrosion behavior and the stability of Ni-20Cr, Ni-20Cr-9Mo...
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| Veröffentlicht in: | Journal of bio- and tribo-corrosion 2021, Vol.7 (3), Article 90 |
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| creator | El-Rabiei, M. M. El-Hafez, Gh.M. Abd Samy, M. Nady, H. |
| description | In this work we are interested to investigate the influence of the presence of Cr, Mo and Fe alloying additions with Ni and to investigates the corrosion resistance of these alloys in chloride and chloride-sulfide containing solutions. The corrosion behavior and the stability of Ni-20Cr, Ni-20Cr-9Mo and Ni-20Cr-9Mo-8Fe alloys in 3.5% NaCl and 3.5% NaCl + S
−
solutions was investigated. Polarization measurements and electrochemical impedance spectroscopy (EIS) were used. Surface examination and morphological studies were employed. Cr, Mo and Fe contents play a significant role against pitting corrosion in chloride and chloride-sulfide environments. Very small current densities were obtained for all investigated alloys in 3.5% NaCl solution compared with that obtained in chloride-sulfide environments. The alloy surface was covered by a barrier layer protecting it from corrosion especially in case of Mo-containing alloy. EIS showed that the resistance of the passive layer created on the different Ni-alloys increases with the increase of the immersion time. EIS measurements revelled that the role of alloyed molybdenum becomes greater in the presence of sulfide. The role of alloyed Cr, Mo and Fe on the corrosion process and the barrier layer creation was discussed. The outcomes lead to the commendation of the Ni-20Cr-9Mo-8Fe alloy for uses in sulfide polluted environments.
Graphic abstract
Ni-21Cr-9Mo-8Fe has a remarkably high corrosion resistance in neutral chloride-sulfide solutions compared to the other two investigated alloys. |
| doi_str_mv | 10.1007/s40735-021-00524-5 |
| format | Article |
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−
solutions was investigated. Polarization measurements and electrochemical impedance spectroscopy (EIS) were used. Surface examination and morphological studies were employed. Cr, Mo and Fe contents play a significant role against pitting corrosion in chloride and chloride-sulfide environments. Very small current densities were obtained for all investigated alloys in 3.5% NaCl solution compared with that obtained in chloride-sulfide environments. The alloy surface was covered by a barrier layer protecting it from corrosion especially in case of Mo-containing alloy. EIS showed that the resistance of the passive layer created on the different Ni-alloys increases with the increase of the immersion time. EIS measurements revelled that the role of alloyed molybdenum becomes greater in the presence of sulfide. The role of alloyed Cr, Mo and Fe on the corrosion process and the barrier layer creation was discussed. The outcomes lead to the commendation of the Ni-20Cr-9Mo-8Fe alloy for uses in sulfide polluted environments.
Graphic abstract
Ni-21Cr-9Mo-8Fe has a remarkably high corrosion resistance in neutral chloride-sulfide solutions compared to the other two investigated alloys.</description><identifier>ISSN: 2198-4220</identifier><identifier>EISSN: 2198-4239</identifier><identifier>DOI: 10.1007/s40735-021-00524-5</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Alloying ; Alloys ; Barrier layers ; Biomaterials ; Chemistry and Materials Science ; Chloride ; Chloride resistance ; Corrosion ; Corrosion and Coatings ; Corrosion effects ; Corrosion resistance ; Corrosion resistant alloys ; Electrochemical impedance spectroscopy ; Iron ; Materials Science ; Molybdenum ; Nickel base alloys ; Nickel chromium alloys ; Pitting (corrosion) ; Polluted environments ; Sodium chloride ; Solid Mechanics ; Spectroscopy ; Sulfide ; Tribology</subject><ispartof>Journal of bio- and tribo-corrosion, 2021, Vol.7 (3), Article 90</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2225-d65d56917932a1080ee601eb26cbd61ff3d1cd4ed5d2ba77175666941693a89b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s40735-021-00524-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s40735-021-00524-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>El-Rabiei, M. M.</creatorcontrib><creatorcontrib>El-Hafez, Gh.M. Abd</creatorcontrib><creatorcontrib>Samy, M.</creatorcontrib><creatorcontrib>Nady, H.</creatorcontrib><title>Effect of Sulfide Pollution on the Corrosion Behaviour of some Ni-Based Alloys in 3.5% NaCl Solution</title><title>Journal of bio- and tribo-corrosion</title><addtitle>J Bio Tribo Corros</addtitle><description>In this work we are interested to investigate the influence of the presence of Cr, Mo and Fe alloying additions with Ni and to investigates the corrosion resistance of these alloys in chloride and chloride-sulfide containing solutions. The corrosion behavior and the stability of Ni-20Cr, Ni-20Cr-9Mo and Ni-20Cr-9Mo-8Fe alloys in 3.5% NaCl and 3.5% NaCl + S
−
solutions was investigated. Polarization measurements and electrochemical impedance spectroscopy (EIS) were used. Surface examination and morphological studies were employed. Cr, Mo and Fe contents play a significant role against pitting corrosion in chloride and chloride-sulfide environments. Very small current densities were obtained for all investigated alloys in 3.5% NaCl solution compared with that obtained in chloride-sulfide environments. The alloy surface was covered by a barrier layer protecting it from corrosion especially in case of Mo-containing alloy. EIS showed that the resistance of the passive layer created on the different Ni-alloys increases with the increase of the immersion time. EIS measurements revelled that the role of alloyed molybdenum becomes greater in the presence of sulfide. The role of alloyed Cr, Mo and Fe on the corrosion process and the barrier layer creation was discussed. The outcomes lead to the commendation of the Ni-20Cr-9Mo-8Fe alloy for uses in sulfide polluted environments.
Graphic abstract
Ni-21Cr-9Mo-8Fe has a remarkably high corrosion resistance in neutral chloride-sulfide solutions compared to the other two investigated alloys.</description><subject>Alloying</subject><subject>Alloys</subject><subject>Barrier layers</subject><subject>Biomaterials</subject><subject>Chemistry and Materials Science</subject><subject>Chloride</subject><subject>Chloride resistance</subject><subject>Corrosion</subject><subject>Corrosion and Coatings</subject><subject>Corrosion effects</subject><subject>Corrosion resistance</subject><subject>Corrosion resistant alloys</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Iron</subject><subject>Materials Science</subject><subject>Molybdenum</subject><subject>Nickel base alloys</subject><subject>Nickel chromium alloys</subject><subject>Pitting (corrosion)</subject><subject>Polluted environments</subject><subject>Sodium chloride</subject><subject>Solid Mechanics</subject><subject>Spectroscopy</subject><subject>Sulfide</subject><subject>Tribology</subject><issn>2198-4220</issn><issn>2198-4239</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kF9LwzAUxYMoOOa-gE8B8bHz5qZJ28etzD8wpjB9DmmTuo6umckq7NvbWdE34cK9hHPOzf0Rcs1gygCSuxBDwkUEyCIAgXEkzsgIWZZGMfLs_HdGuCSTELYAgAmPE44jYhZVZcsDdRVdd01VG0tfXNN0h9q1tK_DxtLcee_C6WFuN_qzdp0_6YPbWbqqo7kO1tBZ07hjoHVL-VTc0pXOG7p2Q9AVuah0E-zkp4_J2_3iNX-Mls8PT_lsGZWIKCIjhREyY0nGUTNIwVoJzBYoy8JIVlXcsNLE1giDhU4SlggpZRYzmXGdZgUfk5shd-_dR2fDQW37v7b9SoUChUyFBOxVOKjK_qrgbaX2vt5pf1QM1AmoGoCqHqj6BqpEb-KDKfTi9t36v-h_XF_1qHYR</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>El-Rabiei, M. M.</creator><creator>El-Hafez, Gh.M. Abd</creator><creator>Samy, M.</creator><creator>Nady, H.</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>Effect of Sulfide Pollution on the Corrosion Behaviour of some Ni-Based Alloys in 3.5% NaCl Solution</title><author>El-Rabiei, M. M. ; El-Hafez, Gh.M. Abd ; Samy, M. ; Nady, H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2225-d65d56917932a1080ee601eb26cbd61ff3d1cd4ed5d2ba77175666941693a89b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Alloying</topic><topic>Alloys</topic><topic>Barrier layers</topic><topic>Biomaterials</topic><topic>Chemistry and Materials Science</topic><topic>Chloride</topic><topic>Chloride resistance</topic><topic>Corrosion</topic><topic>Corrosion and Coatings</topic><topic>Corrosion effects</topic><topic>Corrosion resistance</topic><topic>Corrosion resistant alloys</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Iron</topic><topic>Materials Science</topic><topic>Molybdenum</topic><topic>Nickel base alloys</topic><topic>Nickel chromium alloys</topic><topic>Pitting (corrosion)</topic><topic>Polluted environments</topic><topic>Sodium chloride</topic><topic>Solid Mechanics</topic><topic>Spectroscopy</topic><topic>Sulfide</topic><topic>Tribology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>El-Rabiei, M. M.</creatorcontrib><creatorcontrib>El-Hafez, Gh.M. Abd</creatorcontrib><creatorcontrib>Samy, M.</creatorcontrib><creatorcontrib>Nady, H.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of bio- and tribo-corrosion</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>El-Rabiei, M. M.</au><au>El-Hafez, Gh.M. Abd</au><au>Samy, M.</au><au>Nady, H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Sulfide Pollution on the Corrosion Behaviour of some Ni-Based Alloys in 3.5% NaCl Solution</atitle><jtitle>Journal of bio- and tribo-corrosion</jtitle><stitle>J Bio Tribo Corros</stitle><date>2021</date><risdate>2021</risdate><volume>7</volume><issue>3</issue><artnum>90</artnum><issn>2198-4220</issn><eissn>2198-4239</eissn><abstract>In this work we are interested to investigate the influence of the presence of Cr, Mo and Fe alloying additions with Ni and to investigates the corrosion resistance of these alloys in chloride and chloride-sulfide containing solutions. The corrosion behavior and the stability of Ni-20Cr, Ni-20Cr-9Mo and Ni-20Cr-9Mo-8Fe alloys in 3.5% NaCl and 3.5% NaCl + S
−
solutions was investigated. Polarization measurements and electrochemical impedance spectroscopy (EIS) were used. Surface examination and morphological studies were employed. Cr, Mo and Fe contents play a significant role against pitting corrosion in chloride and chloride-sulfide environments. Very small current densities were obtained for all investigated alloys in 3.5% NaCl solution compared with that obtained in chloride-sulfide environments. The alloy surface was covered by a barrier layer protecting it from corrosion especially in case of Mo-containing alloy. EIS showed that the resistance of the passive layer created on the different Ni-alloys increases with the increase of the immersion time. EIS measurements revelled that the role of alloyed molybdenum becomes greater in the presence of sulfide. The role of alloyed Cr, Mo and Fe on the corrosion process and the barrier layer creation was discussed. The outcomes lead to the commendation of the Ni-20Cr-9Mo-8Fe alloy for uses in sulfide polluted environments.
Graphic abstract
Ni-21Cr-9Mo-8Fe has a remarkably high corrosion resistance in neutral chloride-sulfide solutions compared to the other two investigated alloys.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s40735-021-00524-5</doi></addata></record> |
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| ispartof | Journal of bio- and tribo-corrosion, 2021, Vol.7 (3), Article 90 |
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| subjects | Alloying Alloys Barrier layers Biomaterials Chemistry and Materials Science Chloride Chloride resistance Corrosion Corrosion and Coatings Corrosion effects Corrosion resistance Corrosion resistant alloys Electrochemical impedance spectroscopy Iron Materials Science Molybdenum Nickel base alloys Nickel chromium alloys Pitting (corrosion) Polluted environments Sodium chloride Solid Mechanics Spectroscopy Sulfide Tribology |
| title | Effect of Sulfide Pollution on the Corrosion Behaviour of some Ni-Based Alloys in 3.5% NaCl Solution |
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