Evaluation of PE/POE/PA6 blends containing silica and clay toward nano composite packaging film

In the present study, we investigate PE/POE/PA6 blends containing nano silica and clay, which is one of the most important synthetic polymers utilized in food packaging industry. Nanocomposite films including C 0 S 0 , C 1 S 0.75 , and C 2 S 0.75 (C and S denoting nanoclay and nanosilica, respective...

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Veröffentlicht in:Journal of food measurement & characterization 2021-06, Vol.15 (3), p.2297-2308
Hauptverfasser: Barikloo, Hossein, Ahmadi, Ebrahim, Ahmadi, Shervin
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Ahmadi, Ebrahim
Ahmadi, Shervin
description In the present study, we investigate PE/POE/PA6 blends containing nano silica and clay, which is one of the most important synthetic polymers utilized in food packaging industry. Nanocomposite films including C 0 S 0 , C 1 S 0.75 , and C 2 S 0.75 (C and S denoting nanoclay and nanosilica, respectively) were prepared via melt mixing method. Then, structural, mechanical, thermal, and morphological traits of the prepared films were evaluated. Analysis of variance (ANOVA) results for parameters including strain and energy in the tensile test, elasticity modulus, and work in penetration test were significant at 0.05% probability. X-ray diffraction (XRD) patterns showed that polymer mixing resulted in the removal of 2.5–3 pick and the tendency of 3.5–4.5 and 6.5–7.5 picks appear at lower angles, suggesting the layers openness and partly sheet structure of the nanoparticles. According to SEM micrographs, soil nanoparticle distribution is almost suitable and there is no accumulation at various fracture surface areas. Thermo gravimetric analysis (TGA) presented a relatively good thermos ability. The results of the Differential scanning calorimetry test in the nanocomposite packaging films showed that enthalpy (ΔH m and ΔH c ) and crystallinity percentage in all nanocomposites with PA6 and LDPE polymeric components from C 0 S 0 , C 1 S 0.75 , and C 2 S 0.75 nanocomposite films had a decreasing trend. Therefore, physical, mechanical, thermal and morphological properties of PE/POE/PA6 blends containing Nano silica and clay were improved and increasing storage life, which are important in economic, marketability, and exporting terms. Graphic abstract
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Nanocomposite films including C 0 S 0 , C 1 S 0.75 , and C 2 S 0.75 (C and S denoting nanoclay and nanosilica, respectively) were prepared via melt mixing method. Then, structural, mechanical, thermal, and morphological traits of the prepared films were evaluated. Analysis of variance (ANOVA) results for parameters including strain and energy in the tensile test, elasticity modulus, and work in penetration test were significant at 0.05% probability. X-ray diffraction (XRD) patterns showed that polymer mixing resulted in the removal of 2.5–3 pick and the tendency of 3.5–4.5 and 6.5–7.5 picks appear at lower angles, suggesting the layers openness and partly sheet structure of the nanoparticles. According to SEM micrographs, soil nanoparticle distribution is almost suitable and there is no accumulation at various fracture surface areas. Thermo gravimetric analysis (TGA) presented a relatively good thermos ability. The results of the Differential scanning calorimetry test in the nanocomposite packaging films showed that enthalpy (ΔH m and ΔH c ) and crystallinity percentage in all nanocomposites with PA6 and LDPE polymeric components from C 0 S 0 , C 1 S 0.75 , and C 2 S 0.75 nanocomposite films had a decreasing trend. Therefore, physical, mechanical, thermal and morphological properties of PE/POE/PA6 blends containing Nano silica and clay were improved and increasing storage life, which are important in economic, marketability, and exporting terms. 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Nanocomposite films including C 0 S 0 , C 1 S 0.75 , and C 2 S 0.75 (C and S denoting nanoclay and nanosilica, respectively) were prepared via melt mixing method. Then, structural, mechanical, thermal, and morphological traits of the prepared films were evaluated. Analysis of variance (ANOVA) results for parameters including strain and energy in the tensile test, elasticity modulus, and work in penetration test were significant at 0.05% probability. X-ray diffraction (XRD) patterns showed that polymer mixing resulted in the removal of 2.5–3 pick and the tendency of 3.5–4.5 and 6.5–7.5 picks appear at lower angles, suggesting the layers openness and partly sheet structure of the nanoparticles. According to SEM micrographs, soil nanoparticle distribution is almost suitable and there is no accumulation at various fracture surface areas. Thermo gravimetric analysis (TGA) presented a relatively good thermos ability. The results of the Differential scanning calorimetry test in the nanocomposite packaging films showed that enthalpy (ΔH m and ΔH c ) and crystallinity percentage in all nanocomposites with PA6 and LDPE polymeric components from C 0 S 0 , C 1 S 0.75 , and C 2 S 0.75 nanocomposite films had a decreasing trend. Therefore, physical, mechanical, thermal and morphological properties of PE/POE/PA6 blends containing Nano silica and clay were improved and increasing storage life, which are important in economic, marketability, and exporting terms. Graphic abstract</description><subject>Calorimetry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Clay</subject><subject>Differential scanning calorimetry</subject><subject>Diffraction patterns</subject><subject>Engineering</subject><subject>Enthalpy</subject><subject>Food industry</subject><subject>Food packaging</subject><subject>Food packaging industry</subject><subject>Food Science</subject><subject>Fracture surfaces</subject><subject>Gravimetric analysis</subject><subject>Marketability</subject><subject>Mixtures</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Original Paper</subject><subject>Photomicrographs</subject><subject>Polymers</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Storage life</subject><subject>Strain</subject><subject>Tensile tests</subject><subject>Variance analysis</subject><subject>X-ray diffraction</subject><issn>2193-4126</issn><issn>2193-4134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1LAzEQhoMoWGr_gKeA57X52t3kWEr9gEJ70HOYzWZL6japyVbbf-_WFb15GGYGnncGHoRuKbmnhJTTRGmhREYYyfpV0ux4gUaMKp4JysXl78yKazRJaUsIobQUouAjpBcf0B6gc8Hj0OD1Yrpe9TUrcNVaXydsgu_Aeec3OLnWGcDga2xaOOEufEKssQcfemy3D8l1Fu_BvMHmzDeu3d2gqwbaZCc_fYxeHxYv86dsuXp8ns-WmeFUdZmpSK2kkZYqy4SUhja2rmxZ50TldW5LYAokISyvrJKlKFSlJANpSAkWqoaP0d1wdx_D-8GmTm_DIfr-pWY544oKTmRPsYEyMaQUbaP30e0gnjQl-uxSDy5171J_u9THPsSHUOphv7Hx7_Q_qS967ndY</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Barikloo, Hossein</creator><creator>Ahmadi, Ebrahim</creator><creator>Ahmadi, Shervin</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X2</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M0K</scope><scope>M7S</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-8859-0409</orcidid></search><sort><creationdate>20210601</creationdate><title>Evaluation of PE/POE/PA6 blends containing silica and clay toward nano composite packaging film</title><author>Barikloo, Hossein ; Ahmadi, Ebrahim ; Ahmadi, Shervin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-cb0d98c8e19e2488c1fedbe7d5095d5e7a29a80025be987469b982a8c07aeabf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Calorimetry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Clay</topic><topic>Differential scanning calorimetry</topic><topic>Diffraction patterns</topic><topic>Engineering</topic><topic>Enthalpy</topic><topic>Food industry</topic><topic>Food packaging</topic><topic>Food packaging industry</topic><topic>Food Science</topic><topic>Fracture surfaces</topic><topic>Gravimetric analysis</topic><topic>Marketability</topic><topic>Mixtures</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Original Paper</topic><topic>Photomicrographs</topic><topic>Polymers</topic><topic>Silica</topic><topic>Silicon dioxide</topic><topic>Storage life</topic><topic>Strain</topic><topic>Tensile tests</topic><topic>Variance analysis</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Barikloo, Hossein</creatorcontrib><creatorcontrib>Ahmadi, Ebrahim</creatorcontrib><creatorcontrib>Ahmadi, Shervin</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Agricultural Science Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science &amp; 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Nanocomposite films including C 0 S 0 , C 1 S 0.75 , and C 2 S 0.75 (C and S denoting nanoclay and nanosilica, respectively) were prepared via melt mixing method. Then, structural, mechanical, thermal, and morphological traits of the prepared films were evaluated. Analysis of variance (ANOVA) results for parameters including strain and energy in the tensile test, elasticity modulus, and work in penetration test were significant at 0.05% probability. X-ray diffraction (XRD) patterns showed that polymer mixing resulted in the removal of 2.5–3 pick and the tendency of 3.5–4.5 and 6.5–7.5 picks appear at lower angles, suggesting the layers openness and partly sheet structure of the nanoparticles. According to SEM micrographs, soil nanoparticle distribution is almost suitable and there is no accumulation at various fracture surface areas. Thermo gravimetric analysis (TGA) presented a relatively good thermos ability. The results of the Differential scanning calorimetry test in the nanocomposite packaging films showed that enthalpy (ΔH m and ΔH c ) and crystallinity percentage in all nanocomposites with PA6 and LDPE polymeric components from C 0 S 0 , C 1 S 0.75 , and C 2 S 0.75 nanocomposite films had a decreasing trend. Therefore, physical, mechanical, thermal and morphological properties of PE/POE/PA6 blends containing Nano silica and clay were improved and increasing storage life, which are important in economic, marketability, and exporting terms. Graphic abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11694-020-00781-x</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-8859-0409</orcidid><oa>free_for_read</oa></addata></record>
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source SpringerNature Journals
subjects Calorimetry
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Clay
Differential scanning calorimetry
Diffraction patterns
Engineering
Enthalpy
Food industry
Food packaging
Food packaging industry
Food Science
Fracture surfaces
Gravimetric analysis
Marketability
Mixtures
Morphology
Nanocomposites
Nanoparticles
Original Paper
Photomicrographs
Polymers
Silica
Silicon dioxide
Storage life
Strain
Tensile tests
Variance analysis
X-ray diffraction
title Evaluation of PE/POE/PA6 blends containing silica and clay toward nano composite packaging film
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