Evaluation of PE/POE/PA6 blends containing silica and clay toward nano composite packaging film
In the present study, we investigate PE/POE/PA6 blends containing nano silica and clay, which is one of the most important synthetic polymers utilized in food packaging industry. Nanocomposite films including C 0 S 0 , C 1 S 0.75 , and C 2 S 0.75 (C and S denoting nanoclay and nanosilica, respective...
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description | In the present study, we investigate PE/POE/PA6 blends containing nano silica and clay, which is one of the most important synthetic polymers utilized in food packaging industry. Nanocomposite films including C
0
S
0
, C
1
S
0.75
, and C
2
S
0.75
(C and S denoting nanoclay and nanosilica, respectively) were prepared via melt mixing method. Then, structural, mechanical, thermal, and morphological traits of the prepared films were evaluated. Analysis of variance (ANOVA) results for parameters including strain and energy in the tensile test, elasticity modulus, and work in penetration test were significant at 0.05% probability. X-ray diffraction (XRD) patterns showed that polymer mixing resulted in the removal of 2.5–3 pick and the tendency of 3.5–4.5 and 6.5–7.5 picks appear at lower angles, suggesting the layers openness and partly sheet structure of the nanoparticles. According to SEM micrographs, soil nanoparticle distribution is almost suitable and there is no accumulation at various fracture surface areas. Thermo gravimetric analysis (TGA) presented a relatively good thermos ability. The results of the Differential scanning calorimetry test in the nanocomposite packaging films showed that enthalpy (ΔH
m
and ΔH
c
) and crystallinity percentage in all nanocomposites with PA6 and LDPE polymeric components from C
0
S
0
, C
1
S
0.75
, and C
2
S
0.75
nanocomposite films had a decreasing trend. Therefore, physical, mechanical, thermal and morphological properties of PE/POE/PA6 blends containing Nano silica and clay were improved and increasing storage life, which are important in economic, marketability, and exporting terms.
Graphic abstract |
doi_str_mv | 10.1007/s11694-020-00781-x |
format | Article |
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0
S
0
, C
1
S
0.75
, and C
2
S
0.75
(C and S denoting nanoclay and nanosilica, respectively) were prepared via melt mixing method. Then, structural, mechanical, thermal, and morphological traits of the prepared films were evaluated. Analysis of variance (ANOVA) results for parameters including strain and energy in the tensile test, elasticity modulus, and work in penetration test were significant at 0.05% probability. X-ray diffraction (XRD) patterns showed that polymer mixing resulted in the removal of 2.5–3 pick and the tendency of 3.5–4.5 and 6.5–7.5 picks appear at lower angles, suggesting the layers openness and partly sheet structure of the nanoparticles. According to SEM micrographs, soil nanoparticle distribution is almost suitable and there is no accumulation at various fracture surface areas. Thermo gravimetric analysis (TGA) presented a relatively good thermos ability. The results of the Differential scanning calorimetry test in the nanocomposite packaging films showed that enthalpy (ΔH
m
and ΔH
c
) and crystallinity percentage in all nanocomposites with PA6 and LDPE polymeric components from C
0
S
0
, C
1
S
0.75
, and C
2
S
0.75
nanocomposite films had a decreasing trend. Therefore, physical, mechanical, thermal and morphological properties of PE/POE/PA6 blends containing Nano silica and clay were improved and increasing storage life, which are important in economic, marketability, and exporting terms.
Graphic abstract</description><identifier>ISSN: 2193-4126</identifier><identifier>EISSN: 2193-4134</identifier><identifier>DOI: 10.1007/s11694-020-00781-x</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Calorimetry ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Clay ; Differential scanning calorimetry ; Diffraction patterns ; Engineering ; Enthalpy ; Food industry ; Food packaging ; Food packaging industry ; Food Science ; Fracture surfaces ; Gravimetric analysis ; Marketability ; Mixtures ; Morphology ; Nanocomposites ; Nanoparticles ; Original Paper ; Photomicrographs ; Polymers ; Silica ; Silicon dioxide ; Storage life ; Strain ; Tensile tests ; Variance analysis ; X-ray diffraction</subject><ispartof>Journal of food measurement & characterization, 2021-06, Vol.15 (3), p.2297-2308</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-cb0d98c8e19e2488c1fedbe7d5095d5e7a29a80025be987469b982a8c07aeabf3</citedby><cites>FETCH-LOGICAL-c319t-cb0d98c8e19e2488c1fedbe7d5095d5e7a29a80025be987469b982a8c07aeabf3</cites><orcidid>0000-0002-8859-0409</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11694-020-00781-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11694-020-00781-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Barikloo, Hossein</creatorcontrib><creatorcontrib>Ahmadi, Ebrahim</creatorcontrib><creatorcontrib>Ahmadi, Shervin</creatorcontrib><title>Evaluation of PE/POE/PA6 blends containing silica and clay toward nano composite packaging film</title><title>Journal of food measurement & characterization</title><addtitle>Food Measure</addtitle><description>In the present study, we investigate PE/POE/PA6 blends containing nano silica and clay, which is one of the most important synthetic polymers utilized in food packaging industry. Nanocomposite films including C
0
S
0
, C
1
S
0.75
, and C
2
S
0.75
(C and S denoting nanoclay and nanosilica, respectively) were prepared via melt mixing method. Then, structural, mechanical, thermal, and morphological traits of the prepared films were evaluated. Analysis of variance (ANOVA) results for parameters including strain and energy in the tensile test, elasticity modulus, and work in penetration test were significant at 0.05% probability. X-ray diffraction (XRD) patterns showed that polymer mixing resulted in the removal of 2.5–3 pick and the tendency of 3.5–4.5 and 6.5–7.5 picks appear at lower angles, suggesting the layers openness and partly sheet structure of the nanoparticles. According to SEM micrographs, soil nanoparticle distribution is almost suitable and there is no accumulation at various fracture surface areas. Thermo gravimetric analysis (TGA) presented a relatively good thermos ability. The results of the Differential scanning calorimetry test in the nanocomposite packaging films showed that enthalpy (ΔH
m
and ΔH
c
) and crystallinity percentage in all nanocomposites with PA6 and LDPE polymeric components from C
0
S
0
, C
1
S
0.75
, and C
2
S
0.75
nanocomposite films had a decreasing trend. Therefore, physical, mechanical, thermal and morphological properties of PE/POE/PA6 blends containing Nano silica and clay were improved and increasing storage life, which are important in economic, marketability, and exporting terms.
Graphic abstract</description><subject>Calorimetry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Clay</subject><subject>Differential scanning calorimetry</subject><subject>Diffraction patterns</subject><subject>Engineering</subject><subject>Enthalpy</subject><subject>Food industry</subject><subject>Food packaging</subject><subject>Food packaging industry</subject><subject>Food Science</subject><subject>Fracture surfaces</subject><subject>Gravimetric analysis</subject><subject>Marketability</subject><subject>Mixtures</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Original Paper</subject><subject>Photomicrographs</subject><subject>Polymers</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Storage life</subject><subject>Strain</subject><subject>Tensile tests</subject><subject>Variance analysis</subject><subject>X-ray diffraction</subject><issn>2193-4126</issn><issn>2193-4134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1LAzEQhoMoWGr_gKeA57X52t3kWEr9gEJ70HOYzWZL6japyVbbf-_WFb15GGYGnncGHoRuKbmnhJTTRGmhREYYyfpV0ux4gUaMKp4JysXl78yKazRJaUsIobQUouAjpBcf0B6gc8Hj0OD1Yrpe9TUrcNVaXydsgu_Aeec3OLnWGcDga2xaOOEufEKssQcfemy3D8l1Fu_BvMHmzDeu3d2gqwbaZCc_fYxeHxYv86dsuXp8ns-WmeFUdZmpSK2kkZYqy4SUhja2rmxZ50TldW5LYAokISyvrJKlKFSlJANpSAkWqoaP0d1wdx_D-8GmTm_DIfr-pWY544oKTmRPsYEyMaQUbaP30e0gnjQl-uxSDy5171J_u9THPsSHUOphv7Hx7_Q_qS967ndY</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Barikloo, Hossein</creator><creator>Ahmadi, Ebrahim</creator><creator>Ahmadi, Shervin</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X2</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M0K</scope><scope>M7S</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-8859-0409</orcidid></search><sort><creationdate>20210601</creationdate><title>Evaluation of PE/POE/PA6 blends containing silica and clay toward nano composite packaging film</title><author>Barikloo, Hossein ; Ahmadi, Ebrahim ; Ahmadi, Shervin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-cb0d98c8e19e2488c1fedbe7d5095d5e7a29a80025be987469b982a8c07aeabf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Calorimetry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Clay</topic><topic>Differential scanning calorimetry</topic><topic>Diffraction patterns</topic><topic>Engineering</topic><topic>Enthalpy</topic><topic>Food industry</topic><topic>Food packaging</topic><topic>Food packaging industry</topic><topic>Food Science</topic><topic>Fracture surfaces</topic><topic>Gravimetric analysis</topic><topic>Marketability</topic><topic>Mixtures</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Original Paper</topic><topic>Photomicrographs</topic><topic>Polymers</topic><topic>Silica</topic><topic>Silicon dioxide</topic><topic>Storage life</topic><topic>Strain</topic><topic>Tensile tests</topic><topic>Variance analysis</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Barikloo, Hossein</creatorcontrib><creatorcontrib>Ahmadi, Ebrahim</creatorcontrib><creatorcontrib>Ahmadi, Shervin</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Agricultural Science Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>Agricultural Science Database</collection><collection>Engineering Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of food measurement & characterization</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Barikloo, Hossein</au><au>Ahmadi, Ebrahim</au><au>Ahmadi, Shervin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Evaluation of PE/POE/PA6 blends containing silica and clay toward nano composite packaging film</atitle><jtitle>Journal of food measurement & characterization</jtitle><stitle>Food Measure</stitle><date>2021-06-01</date><risdate>2021</risdate><volume>15</volume><issue>3</issue><spage>2297</spage><epage>2308</epage><pages>2297-2308</pages><issn>2193-4126</issn><eissn>2193-4134</eissn><abstract>In the present study, we investigate PE/POE/PA6 blends containing nano silica and clay, which is one of the most important synthetic polymers utilized in food packaging industry. Nanocomposite films including C
0
S
0
, C
1
S
0.75
, and C
2
S
0.75
(C and S denoting nanoclay and nanosilica, respectively) were prepared via melt mixing method. Then, structural, mechanical, thermal, and morphological traits of the prepared films were evaluated. Analysis of variance (ANOVA) results for parameters including strain and energy in the tensile test, elasticity modulus, and work in penetration test were significant at 0.05% probability. X-ray diffraction (XRD) patterns showed that polymer mixing resulted in the removal of 2.5–3 pick and the tendency of 3.5–4.5 and 6.5–7.5 picks appear at lower angles, suggesting the layers openness and partly sheet structure of the nanoparticles. According to SEM micrographs, soil nanoparticle distribution is almost suitable and there is no accumulation at various fracture surface areas. Thermo gravimetric analysis (TGA) presented a relatively good thermos ability. The results of the Differential scanning calorimetry test in the nanocomposite packaging films showed that enthalpy (ΔH
m
and ΔH
c
) and crystallinity percentage in all nanocomposites with PA6 and LDPE polymeric components from C
0
S
0
, C
1
S
0.75
, and C
2
S
0.75
nanocomposite films had a decreasing trend. Therefore, physical, mechanical, thermal and morphological properties of PE/POE/PA6 blends containing Nano silica and clay were improved and increasing storage life, which are important in economic, marketability, and exporting terms.
Graphic abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11694-020-00781-x</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-8859-0409</orcidid><oa>free_for_read</oa></addata></record> |
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source | SpringerNature Journals |
subjects | Calorimetry Chemistry Chemistry and Materials Science Chemistry/Food Science Clay Differential scanning calorimetry Diffraction patterns Engineering Enthalpy Food industry Food packaging Food packaging industry Food Science Fracture surfaces Gravimetric analysis Marketability Mixtures Morphology Nanocomposites Nanoparticles Original Paper Photomicrographs Polymers Silica Silicon dioxide Storage life Strain Tensile tests Variance analysis X-ray diffraction |
title | Evaluation of PE/POE/PA6 blends containing silica and clay toward nano composite packaging film |
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