Corrosion resistant nanostructured eutectic high entropy alloy

•A nanostructured eutectic high-entropy alloy (EHEA) with composition of FeCrNiCoNb0.5 was developed.•The EHEA shows superior corrosion-preventive and repassivation ability in 1 M NaCl.•Amorphous passive film formed on EHEA is compact and protective.•The unique nanostructure effectively prohibited p...

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Veröffentlicht in:Corrosion science 2020-03, Vol.164, p.108315, Article 108315
Hauptverfasser: Shuang, S., Ding, Z.Y., Chung, D., Shi, S.Q., Yang, Y.
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container_start_page 108315
container_title Corrosion science
container_volume 164
creator Shuang, S.
Ding, Z.Y.
Chung, D.
Shi, S.Q.
Yang, Y.
description •A nanostructured eutectic high-entropy alloy (EHEA) with composition of FeCrNiCoNb0.5 was developed.•The EHEA shows superior corrosion-preventive and repassivation ability in 1 M NaCl.•Amorphous passive film formed on EHEA is compact and protective.•The unique nanostructure effectively prohibited pitting corrosion. In this work, we developed a nanostructured eutectic high entropy alloy (EHEA) of composition FeCrNiCoNb0.5 (atomic %). Due to the formation of a compact amorphous high entropy passive film and the two-phase nanostructure, our EHEA exhibits unique combination of a low corrosion current density, a large passivation region and a superior repassivation ability in 1 M NaCl, outperforming the variety of conventional alloys and other high entropy alloys hitherto reported. The outcome of our research suggests that the notion of EHEAs could be explored to design corrosion resistant chemically complex alloys.
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subjects A. High entropy alloy
Alloys
C. Passivity
C. Pitting corrosion
C. Repassivation
Corrosion
Corrosion currents
Corrosion resistance
Corrosion resistant alloys
Eutectic alloys
High entropy alloys
Nanostructure
title Corrosion resistant nanostructured eutectic high entropy alloy
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