The Effect of Viscosity on the Coupling and Hydrogen-Abstraction Reaction between Transient and Persistent Radicals

The effect of viscosity on the radical termination reaction between a transient radical and a persistent radical undergoing a coupling reaction (Coup) or hydrogen abstraction (Abst) was examined. In a non-viscous solvent, such as benzene (bulk viscosity ηbulk < 1 mPa s), all the transient radical...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2021-03, Vol.94 (3), p.966-972
Hauptverfasser:	Li, Xiaopei, Kato, Tatsuhisa, Nakamura, Yasuyuki, Yamago, Shigeru
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzene Bromine compounds Coupling Frontiers of Molecular Science Hydrogen Parameters Polymethyl methacrylate Polystyrene resins Selectivity Solvents Thermal stability Viscosity
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