Base activation of persulfate: an effective pretreatment method to enhance glucose production from lignocellulosic biomass
Pretreatment is a necessary process in biorefineries to overcome recalcitrance of biomass and enhance its conversion efficiency for further transformation. NaOH activation of Na 2 S 2 O 8 , which merges alkaline pretreatment and advanced oxidation processes (AOPs) into one process, was performed at...
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Veröffentlicht in: | Cellulose (London) 2021-05, Vol.28 (7), p.4039-4051 |
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creator | Yang, Jirui Wang, Xiaoqi Shen, Feng Qi, Xinhua |
description | Pretreatment is a necessary process in biorefineries to overcome recalcitrance of biomass and enhance its conversion efficiency for further transformation. NaOH activation of Na
2
S
2
O
8
, which merges alkaline pretreatment and advanced oxidation processes (AOPs) into one process, was performed at room temperature (25 °C) within a short duration (60 min). High concentration of NaOH plays a critically important role in NaOH–Na
2
S
2
O
8
pretreatment, which not only selectively removed hemicellulose in the lignocellulosic feedstock, but also activated Na
2
S
2
O
8
to produce strong oxidative radicals, leading to disruption of lignin matrix. The surface area and porosity for the pretreated feedstock were significantly increased compared with those of the pristine counterpart. After pretreatment by 5.12 M NaOH and 0.85 M Na
2
S
2
O
8
, the maximum glucose yield of the feedstock was increased by 47.4% compared with that of pristine counterpart (60.3% vs. 40.9%). This study provides an effective and easily-realizable pretreatment method for the utilization of lignocellulosic biomass.
Graphic abstract |
doi_str_mv | 10.1007/s10570-021-03796-9 |
format | Article |
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2
S
2
O
8
, which merges alkaline pretreatment and advanced oxidation processes (AOPs) into one process, was performed at room temperature (25 °C) within a short duration (60 min). High concentration of NaOH plays a critically important role in NaOH–Na
2
S
2
O
8
pretreatment, which not only selectively removed hemicellulose in the lignocellulosic feedstock, but also activated Na
2
S
2
O
8
to produce strong oxidative radicals, leading to disruption of lignin matrix. The surface area and porosity for the pretreated feedstock were significantly increased compared with those of the pristine counterpart. After pretreatment by 5.12 M NaOH and 0.85 M Na
2
S
2
O
8
, the maximum glucose yield of the feedstock was increased by 47.4% compared with that of pristine counterpart (60.3% vs. 40.9%). This study provides an effective and easily-realizable pretreatment method for the utilization of lignocellulosic biomass.
Graphic abstract</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-021-03796-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Biomass ; Bioorganic Chemistry ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Glass ; Glucose ; Lignocellulose ; Natural Materials ; Organic Chemistry ; Original Research ; Oxidation ; Physical Chemistry ; Polymer Sciences ; Pretreatment ; Raw materials ; Room temperature ; Sodium persulfate ; Sustainable Development</subject><ispartof>Cellulose (London), 2021-05, Vol.28 (7), p.4039-4051</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-5141fc9de03837329ff07dac704e9166f3d8a32008a5bc4d5fa96672caf688253</citedby><cites>FETCH-LOGICAL-c356t-5141fc9de03837329ff07dac704e9166f3d8a32008a5bc4d5fa96672caf688253</cites><orcidid>0000-0002-3227-7341</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-021-03796-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-021-03796-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Yang, Jirui</creatorcontrib><creatorcontrib>Wang, Xiaoqi</creatorcontrib><creatorcontrib>Shen, Feng</creatorcontrib><creatorcontrib>Qi, Xinhua</creatorcontrib><title>Base activation of persulfate: an effective pretreatment method to enhance glucose production from lignocellulosic biomass</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>Pretreatment is a necessary process in biorefineries to overcome recalcitrance of biomass and enhance its conversion efficiency for further transformation. NaOH activation of Na
2
S
2
O
8
, which merges alkaline pretreatment and advanced oxidation processes (AOPs) into one process, was performed at room temperature (25 °C) within a short duration (60 min). High concentration of NaOH plays a critically important role in NaOH–Na
2
S
2
O
8
pretreatment, which not only selectively removed hemicellulose in the lignocellulosic feedstock, but also activated Na
2
S
2
O
8
to produce strong oxidative radicals, leading to disruption of lignin matrix. The surface area and porosity for the pretreated feedstock were significantly increased compared with those of the pristine counterpart. After pretreatment by 5.12 M NaOH and 0.85 M Na
2
S
2
O
8
, the maximum glucose yield of the feedstock was increased by 47.4% compared with that of pristine counterpart (60.3% vs. 40.9%). This study provides an effective and easily-realizable pretreatment method for the utilization of lignocellulosic biomass.
Graphic abstract</description><subject>Biomass</subject><subject>Bioorganic Chemistry</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Glass</subject><subject>Glucose</subject><subject>Lignocellulose</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Oxidation</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Pretreatment</subject><subject>Raw materials</subject><subject>Room temperature</subject><subject>Sodium persulfate</subject><subject>Sustainable Development</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kE1LxDAQhoMouK7-AU8Bz9VJskkab7r4BYIXBW8hppO10jZrkgr66-26gjdPc3g_ZuYh5JjBKQPQZ5mB1FABZxUIbVRldsiMSc2ruubPu2QGRplJFmafHOT8BgBGczYjX5cuI3W-tB-utHGgMdA1pjx2wRU8p26gGAJudKTrhCWhKz0OhfZYXmNDS6Q4vLrBI111o495Y4vN6H_aQoo97drVED123djF3Hr60sbe5XxI9oLrMh79zjl5ur56XN5W9w83d8uL-8oLqUol2YIFbxoEUQstuAkBdOO8hgUaplQQTe0EB6idfPGLRgZnlNLcu6Cm56WYk5Nt73TX-4i52Lc4pmFaablktVSgtZlcfOvyKeacMNh1anuXPi0Du2Fst4ztxNj-MLabkNiG8mQeVpj-qv9JfQP24oG4</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Yang, Jirui</creator><creator>Wang, Xiaoqi</creator><creator>Shen, Feng</creator><creator>Qi, Xinhua</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0002-3227-7341</orcidid></search><sort><creationdate>20210501</creationdate><title>Base activation of persulfate: an effective pretreatment method to enhance glucose production from lignocellulosic biomass</title><author>Yang, Jirui ; Wang, Xiaoqi ; Shen, Feng ; Qi, Xinhua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-5141fc9de03837329ff07dac704e9166f3d8a32008a5bc4d5fa96672caf688253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Biomass</topic><topic>Bioorganic Chemistry</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Glass</topic><topic>Glucose</topic><topic>Lignocellulose</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Oxidation</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Pretreatment</topic><topic>Raw materials</topic><topic>Room temperature</topic><topic>Sodium persulfate</topic><topic>Sustainable Development</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Jirui</creatorcontrib><creatorcontrib>Wang, Xiaoqi</creatorcontrib><creatorcontrib>Shen, Feng</creatorcontrib><creatorcontrib>Qi, Xinhua</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Jirui</au><au>Wang, Xiaoqi</au><au>Shen, Feng</au><au>Qi, Xinhua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Base activation of persulfate: an effective pretreatment method to enhance glucose production from lignocellulosic biomass</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2021-05-01</date><risdate>2021</risdate><volume>28</volume><issue>7</issue><spage>4039</spage><epage>4051</epage><pages>4039-4051</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>Pretreatment is a necessary process in biorefineries to overcome recalcitrance of biomass and enhance its conversion efficiency for further transformation. NaOH activation of Na
2
S
2
O
8
, which merges alkaline pretreatment and advanced oxidation processes (AOPs) into one process, was performed at room temperature (25 °C) within a short duration (60 min). High concentration of NaOH plays a critically important role in NaOH–Na
2
S
2
O
8
pretreatment, which not only selectively removed hemicellulose in the lignocellulosic feedstock, but also activated Na
2
S
2
O
8
to produce strong oxidative radicals, leading to disruption of lignin matrix. The surface area and porosity for the pretreated feedstock were significantly increased compared with those of the pristine counterpart. After pretreatment by 5.12 M NaOH and 0.85 M Na
2
S
2
O
8
, the maximum glucose yield of the feedstock was increased by 47.4% compared with that of pristine counterpart (60.3% vs. 40.9%). This study provides an effective and easily-realizable pretreatment method for the utilization of lignocellulosic biomass.
Graphic abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-021-03796-9</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0002-3227-7341</orcidid></addata></record> |
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source | SpringerLink Journals |
subjects | Biomass Bioorganic Chemistry Ceramics Chemistry Chemistry and Materials Science Composites Glass Glucose Lignocellulose Natural Materials Organic Chemistry Original Research Oxidation Physical Chemistry Polymer Sciences Pretreatment Raw materials Room temperature Sodium persulfate Sustainable Development |
title | Base activation of persulfate: an effective pretreatment method to enhance glucose production from lignocellulosic biomass |
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