Development of a New Passive Sampling Method for the Measurement of Atmospheric Linear and Cyclic Volatile Methyl Siloxanes
A new passive sampling method was developed and characterized to measure atmospheric volatile methyl siloxanes (VMS). The infrastructure of a commercial passive air sampler (PAS) was used along with XAD-2 resin as the adsorbent. Experimental sampling rates (SR) determined using collocated active and...
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| Veröffentlicht in: | Environmental science & technology 2021-04, Vol.55 (8), p.4522-4531 |
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| container_title | Environmental science & technology |
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| creator | Okan, Fulya Odabasi, Mustafa Yaman, Baris Dumanoglu, Yetkin |
| description | A new passive sampling method was developed and characterized to measure atmospheric volatile methyl siloxanes (VMS). The infrastructure of a commercial passive air sampler (PAS) was used along with XAD-2 resin as the adsorbent. Experimental sampling rates (SR) determined using collocated active and passive samplers ranged between 0.0363 (L5) and 0.0561 (D3) m3/day and agreed well with the theoretical ones. VMS uptake was highly linear for eight weeks. The precision of the method was very good ( |
| doi_str_mv | 10.1021/acs.est.1c00227 |
| format | Article |
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The infrastructure of a commercial passive air sampler (PAS) was used along with XAD-2 resin as the adsorbent. Experimental sampling rates (SR) determined using collocated active and passive samplers ranged between 0.0363 (L5) and 0.0561 (D3) m3/day and agreed well with the theoretical ones. VMS uptake was highly linear for eight weeks. The precision of the method was very good (<10%). Compared to the other PASs used for VMS, the new method has several advantages (i.e., the sampler is much smaller, it has commercially available components, and the solvent requirement, equipment needed for extraction, and steps for sample preparation are minimal) while achieving similar or lower method detection limits. The developed method was applied to investigate the spatial distribution and possible sources of atmospheric VMS in the Izmir region. Field sampling covered 42 sites representing different source and land use areas. ΣVMS concentrations ranged between 41.4 and 981 ng/m3. The dominant VMS was D5 followed by D3 and D4. Spatial distributions indicated that the main VMS sources in the area were urban areas, wastewater treatment plants, and landfills where the VMS-containing products are used and disposed.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/acs.est.1c00227</identifier><identifier>PMID: 33769040</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Air Pollutants - analysis ; Anthropogenic Impacts on the Atmosphere ; Detection limits ; Environmental Monitoring ; Land use ; Landfills ; Sample preparation ; Samplers ; Sampling ; Sampling methods ; Siloxanes ; Siloxanes - analysis ; Spatial distribution ; Urban areas ; Waste Disposal Facilities ; Waste disposal sites ; Waste treatment ; Wastewater treatment ; Wastewater treatment plants</subject><ispartof>Environmental science & technology, 2021-04, Vol.55 (8), p.4522-4531</ispartof><rights>2021 American Chemical Society</rights><rights>Copyright American Chemical Society Apr 20, 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a361t-7c825e8f4b0fa57db99bc318ad3df355dcb1100b7127d0c91ad6c85055f535133</citedby><cites>FETCH-LOGICAL-a361t-7c825e8f4b0fa57db99bc318ad3df355dcb1100b7127d0c91ad6c85055f535133</cites><orcidid>0000-0002-0506-0470 ; 0000-0002-9136-4808</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.est.1c00227$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.est.1c00227$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33769040$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Okan, Fulya</creatorcontrib><creatorcontrib>Odabasi, Mustafa</creatorcontrib><creatorcontrib>Yaman, Baris</creatorcontrib><creatorcontrib>Dumanoglu, Yetkin</creatorcontrib><title>Development of a New Passive Sampling Method for the Measurement of Atmospheric Linear and Cyclic Volatile Methyl Siloxanes</title><title>Environmental science & technology</title><addtitle>Environ. Sci. Technol</addtitle><description>A new passive sampling method was developed and characterized to measure atmospheric volatile methyl siloxanes (VMS). The infrastructure of a commercial passive air sampler (PAS) was used along with XAD-2 resin as the adsorbent. Experimental sampling rates (SR) determined using collocated active and passive samplers ranged between 0.0363 (L5) and 0.0561 (D3) m3/day and agreed well with the theoretical ones. VMS uptake was highly linear for eight weeks. The precision of the method was very good (<10%). Compared to the other PASs used for VMS, the new method has several advantages (i.e., the sampler is much smaller, it has commercially available components, and the solvent requirement, equipment needed for extraction, and steps for sample preparation are minimal) while achieving similar or lower method detection limits. The developed method was applied to investigate the spatial distribution and possible sources of atmospheric VMS in the Izmir region. Field sampling covered 42 sites representing different source and land use areas. ΣVMS concentrations ranged between 41.4 and 981 ng/m3. The dominant VMS was D5 followed by D3 and D4. Spatial distributions indicated that the main VMS sources in the area were urban areas, wastewater treatment plants, and landfills where the VMS-containing products are used and disposed.</description><subject>Air Pollutants - analysis</subject><subject>Anthropogenic Impacts on the Atmosphere</subject><subject>Detection limits</subject><subject>Environmental Monitoring</subject><subject>Land use</subject><subject>Landfills</subject><subject>Sample preparation</subject><subject>Samplers</subject><subject>Sampling</subject><subject>Sampling methods</subject><subject>Siloxanes</subject><subject>Siloxanes - analysis</subject><subject>Spatial distribution</subject><subject>Urban areas</subject><subject>Waste Disposal Facilities</subject><subject>Waste disposal sites</subject><subject>Waste treatment</subject><subject>Wastewater treatment</subject><subject>Wastewater treatment plants</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp1kE1P4zAQhi20CArLmdvK0h5R2pm4bpIj6i4fUoGVCohb5NiTbVASBzsFKv48Li3cOI1m9LzvSA9jxwhDhBhHSvsh-X6IGiCOkx02QBlDJFOJP9gAAEWUicnDPjvw_hECIyDdY_tCJJMMxjBgb3_omWrbNdT23JZc8Wt64f-U99Uz8blqurpq__Mr6hfW8NI63i8orMovHX2GTvvG-m5BrtJ8VrWkHFet4dOVrsPl3taqr2r6KFnVfF7V9lW15H-y3VLVno6285Ddnf29nV5Es5vzy-npLFJign2U6DSWlJbjAkolE1NkWaEFpsoIUwopjS4QAYoE48SAzlCZiU4lSFlKIVGIQ_Z709s5-7QMuvJHu3RteJnHEtNxjCgwUKMNpZ313lGZd65qlFvlCPladh5k5-v0VnZI_Nr2LouGzBf_aTcAJxtgnfz6-V3dO1Udivk</recordid><startdate>20210420</startdate><enddate>20210420</enddate><creator>Okan, Fulya</creator><creator>Odabasi, Mustafa</creator><creator>Yaman, Baris</creator><creator>Dumanoglu, Yetkin</creator><general>American Chemical Society</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7ST</scope><scope>7T7</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0002-0506-0470</orcidid><orcidid>https://orcid.org/0000-0002-9136-4808</orcidid></search><sort><creationdate>20210420</creationdate><title>Development of a New Passive Sampling Method for the Measurement of Atmospheric Linear and Cyclic Volatile Methyl Siloxanes</title><author>Okan, Fulya ; Odabasi, Mustafa ; Yaman, Baris ; Dumanoglu, Yetkin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a361t-7c825e8f4b0fa57db99bc318ad3df355dcb1100b7127d0c91ad6c85055f535133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Air Pollutants - analysis</topic><topic>Anthropogenic Impacts on the Atmosphere</topic><topic>Detection limits</topic><topic>Environmental Monitoring</topic><topic>Land use</topic><topic>Landfills</topic><topic>Sample preparation</topic><topic>Samplers</topic><topic>Sampling</topic><topic>Sampling methods</topic><topic>Siloxanes</topic><topic>Siloxanes - analysis</topic><topic>Spatial distribution</topic><topic>Urban areas</topic><topic>Waste Disposal Facilities</topic><topic>Waste disposal sites</topic><topic>Waste treatment</topic><topic>Wastewater treatment</topic><topic>Wastewater treatment plants</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Okan, Fulya</creatorcontrib><creatorcontrib>Odabasi, Mustafa</creatorcontrib><creatorcontrib>Yaman, Baris</creatorcontrib><creatorcontrib>Dumanoglu, Yetkin</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Environmental science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Okan, Fulya</au><au>Odabasi, Mustafa</au><au>Yaman, Baris</au><au>Dumanoglu, Yetkin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Development of a New Passive Sampling Method for the Measurement of Atmospheric Linear and Cyclic Volatile Methyl Siloxanes</atitle><jtitle>Environmental science & technology</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>2021-04-20</date><risdate>2021</risdate><volume>55</volume><issue>8</issue><spage>4522</spage><epage>4531</epage><pages>4522-4531</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><abstract>A new passive sampling method was developed and characterized to measure atmospheric volatile methyl siloxanes (VMS). The infrastructure of a commercial passive air sampler (PAS) was used along with XAD-2 resin as the adsorbent. Experimental sampling rates (SR) determined using collocated active and passive samplers ranged between 0.0363 (L5) and 0.0561 (D3) m3/day and agreed well with the theoretical ones. VMS uptake was highly linear for eight weeks. The precision of the method was very good (<10%). Compared to the other PASs used for VMS, the new method has several advantages (i.e., the sampler is much smaller, it has commercially available components, and the solvent requirement, equipment needed for extraction, and steps for sample preparation are minimal) while achieving similar or lower method detection limits. The developed method was applied to investigate the spatial distribution and possible sources of atmospheric VMS in the Izmir region. Field sampling covered 42 sites representing different source and land use areas. ΣVMS concentrations ranged between 41.4 and 981 ng/m3. The dominant VMS was D5 followed by D3 and D4. Spatial distributions indicated that the main VMS sources in the area were urban areas, wastewater treatment plants, and landfills where the VMS-containing products are used and disposed.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>33769040</pmid><doi>10.1021/acs.est.1c00227</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-0506-0470</orcidid><orcidid>https://orcid.org/0000-0002-9136-4808</orcidid></addata></record> |
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| source | MEDLINE; American Chemical Society Journals |
| subjects | Air Pollutants - analysis Anthropogenic Impacts on the Atmosphere Detection limits Environmental Monitoring Land use Landfills Sample preparation Samplers Sampling Sampling methods Siloxanes Siloxanes - analysis Spatial distribution Urban areas Waste Disposal Facilities Waste disposal sites Waste treatment Wastewater treatment Wastewater treatment plants |
| title | Development of a New Passive Sampling Method for the Measurement of Atmospheric Linear and Cyclic Volatile Methyl Siloxanes |
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