Rapid method for sequential determination of Pu and Am in soil and sediment samples by sector-field inductively coupled plasma mass spectrometry
New method was developed to analyze Pu and Am sequentially for soil and sediment by inductively coupled plasma mass spectrometry (ICPMS). The developed method uses conc. HNO 3 to leach Pu and Am, Fe(OH) 3 coprecipitation to remove alkali and alkaline metals, extraction chromatographic separation usi...
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| Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2021-04, Vol.328 (1), p.137-147 |
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| creator | Wang, Zhongtang Xie, Yun Lin, Jinxian Li, Zejun Tan, Zhaoyi |
| description | New method was developed to analyze Pu and Am sequentially for soil and sediment by inductively coupled plasma mass spectrometry (ICPMS). The developed method uses conc. HNO
3
to leach Pu and Am, Fe(OH)
3
coprecipitation to remove alkali and alkaline metals, extraction chromatographic separation using UTEVA, DGA and TEVA resins to remove interfering elements (IEs) and separate Pu and Am from each other, and sector field-ICPMS to measure Pu and Am. The analysis of four standard reference materials showed that both Pu isotopes and
241
Am were accurately determined by this method, as a result of its excellent decontamination ability of IEs. Especially the high decontamination factor of Pu [DF(Pu), 4.2 × 10
2
] in Am fraction and high DF(Am) (7.0 × 10
3
) in Pu fraction sufficiently eliminated the cross interference between
241
Pu and
241
Am in ICPMS measurement. In addition, stable and high chemical recoveries were achieved for Pu (71–91%) and Am (70–88%). The low LODs of Pu isotopes, short analytical time (14 h) and high DFs of IEs allows this method to sequentially analyze Pu and Am, for both global fallout and nuclear accident sourced samples. |
| doi_str_mv | 10.1007/s10967-021-07627-w |
| format | Article |
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3
to leach Pu and Am, Fe(OH)
3
coprecipitation to remove alkali and alkaline metals, extraction chromatographic separation using UTEVA, DGA and TEVA resins to remove interfering elements (IEs) and separate Pu and Am from each other, and sector field-ICPMS to measure Pu and Am. The analysis of four standard reference materials showed that both Pu isotopes and
241
Am were accurately determined by this method, as a result of its excellent decontamination ability of IEs. Especially the high decontamination factor of Pu [DF(Pu), 4.2 × 10
2
] in Am fraction and high DF(Am) (7.0 × 10
3
) in Pu fraction sufficiently eliminated the cross interference between
241
Pu and
241
Am in ICPMS measurement. In addition, stable and high chemical recoveries were achieved for Pu (71–91%) and Am (70–88%). The low LODs of Pu isotopes, short analytical time (14 h) and high DFs of IEs allows this method to sequentially analyze Pu and Am, for both global fallout and nuclear accident sourced samples.</description><identifier>ISSN: 0236-5731</identifier><identifier>EISSN: 1588-2780</identifier><identifier>DOI: 10.1007/s10967-021-07627-w</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Alkali metals ; Analysis ; Chemistry ; Chemistry and Materials Science ; Decontamination ; Diagnostic Radiology ; Fallout ; Ferric hydroxide ; Hadrons ; Heavy Ions ; Inductively coupled plasma mass spectrometry ; Inorganic Chemistry ; Iron ; Isotopes ; Mass spectrometry ; Methods ; Nuclear accidents ; Nuclear Chemistry ; Nuclear Physics ; Physical Chemistry ; Polyurethane resins ; Scientific imaging ; Sediments (Geology) ; Soils ; Spectroscopy ; Standard reference materials</subject><ispartof>Journal of radioanalytical and nuclear chemistry, 2021-04, Vol.328 (1), p.137-147</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2021</rights><rights>COPYRIGHT 2021 Springer</rights><rights>Akadémiai Kiadó, Budapest, Hungary 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-a7eba80c975c19f52ca331c73283aee0184003b48d9abe68fe9089cb7dcabcd83</citedby><cites>FETCH-LOGICAL-c358t-a7eba80c975c19f52ca331c73283aee0184003b48d9abe68fe9089cb7dcabcd83</cites><orcidid>0000-0003-3153-6775</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10967-021-07627-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10967-021-07627-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Wang, Zhongtang</creatorcontrib><creatorcontrib>Xie, Yun</creatorcontrib><creatorcontrib>Lin, Jinxian</creatorcontrib><creatorcontrib>Li, Zejun</creatorcontrib><creatorcontrib>Tan, Zhaoyi</creatorcontrib><title>Rapid method for sequential determination of Pu and Am in soil and sediment samples by sector-field inductively coupled plasma mass spectrometry</title><title>Journal of radioanalytical and nuclear chemistry</title><addtitle>J Radioanal Nucl Chem</addtitle><description>New method was developed to analyze Pu and Am sequentially for soil and sediment by inductively coupled plasma mass spectrometry (ICPMS). The developed method uses conc. HNO
3
to leach Pu and Am, Fe(OH)
3
coprecipitation to remove alkali and alkaline metals, extraction chromatographic separation using UTEVA, DGA and TEVA resins to remove interfering elements (IEs) and separate Pu and Am from each other, and sector field-ICPMS to measure Pu and Am. The analysis of four standard reference materials showed that both Pu isotopes and
241
Am were accurately determined by this method, as a result of its excellent decontamination ability of IEs. Especially the high decontamination factor of Pu [DF(Pu), 4.2 × 10
2
] in Am fraction and high DF(Am) (7.0 × 10
3
) in Pu fraction sufficiently eliminated the cross interference between
241
Pu and
241
Am in ICPMS measurement. In addition, stable and high chemical recoveries were achieved for Pu (71–91%) and Am (70–88%). The low LODs of Pu isotopes, short analytical time (14 h) and high DFs of IEs allows this method to sequentially analyze Pu and Am, for both global fallout and nuclear accident sourced samples.</description><subject>Alkali metals</subject><subject>Analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Decontamination</subject><subject>Diagnostic Radiology</subject><subject>Fallout</subject><subject>Ferric hydroxide</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Inductively coupled plasma mass spectrometry</subject><subject>Inorganic Chemistry</subject><subject>Iron</subject><subject>Isotopes</subject><subject>Mass spectrometry</subject><subject>Methods</subject><subject>Nuclear accidents</subject><subject>Nuclear Chemistry</subject><subject>Nuclear Physics</subject><subject>Physical Chemistry</subject><subject>Polyurethane resins</subject><subject>Scientific imaging</subject><subject>Sediments (Geology)</subject><subject>Soils</subject><subject>Spectroscopy</subject><subject>Standard reference materials</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kc9uFSEUh4nRxGv1BVyRuJ7KnzsDLG8atSZN2hhdEwYOlWaAERib-xY-stgxcWdYEE6-j3NOfgi9peSSEiLeV0rUJAbC6EDExMTw-Awd6CjlwIQkz9GBMD4No-D0JXpV6wMhREnJD-jXF7MGhyO079lhnwuu8GOD1IJZsIMGJYZkWsgJZ4_vNmySw6eIQ8I1h-XpWcGF2BVcTVwXqHg-95ptuQw-wOI67Dbbwk9YztjmrTMOr4up0eBoasV17XTJfYhyfo1eeLNUePP3vkDfPn74enU93Nx--nx1uhksH2UbjIDZSGKVGC1VfmTWcE6t4ExyA0CoPBLC56N0yswwSQ-KSGVn4ayZrZP8Ar3b_11L7gvXph_yVlJvqdlIRdfpJDp1uVP3ZgEdks-tGNuPgxhsTuBDr5-mUU1MqSPvAtsFW3KtBbxeS4imnDUl-k9Ueo9K96j0U1T6sUt8l2qH0z2Uf7P8x_oNB7uaxQ</recordid><startdate>20210401</startdate><enddate>20210401</enddate><creator>Wang, Zhongtang</creator><creator>Xie, Yun</creator><creator>Lin, Jinxian</creator><creator>Li, Zejun</creator><creator>Tan, Zhaoyi</creator><general>Springer International Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-3153-6775</orcidid></search><sort><creationdate>20210401</creationdate><title>Rapid method for sequential determination of Pu and Am in soil and sediment samples by sector-field inductively coupled plasma mass spectrometry</title><author>Wang, Zhongtang ; Xie, Yun ; Lin, Jinxian ; Li, Zejun ; Tan, Zhaoyi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-a7eba80c975c19f52ca331c73283aee0184003b48d9abe68fe9089cb7dcabcd83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Alkali metals</topic><topic>Analysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Decontamination</topic><topic>Diagnostic Radiology</topic><topic>Fallout</topic><topic>Ferric hydroxide</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Inductively coupled plasma mass spectrometry</topic><topic>Inorganic Chemistry</topic><topic>Iron</topic><topic>Isotopes</topic><topic>Mass spectrometry</topic><topic>Methods</topic><topic>Nuclear accidents</topic><topic>Nuclear Chemistry</topic><topic>Nuclear Physics</topic><topic>Physical Chemistry</topic><topic>Polyurethane resins</topic><topic>Scientific imaging</topic><topic>Sediments (Geology)</topic><topic>Soils</topic><topic>Spectroscopy</topic><topic>Standard reference materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Zhongtang</creatorcontrib><creatorcontrib>Xie, Yun</creatorcontrib><creatorcontrib>Lin, Jinxian</creatorcontrib><creatorcontrib>Li, Zejun</creatorcontrib><creatorcontrib>Tan, Zhaoyi</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Zhongtang</au><au>Xie, Yun</au><au>Lin, Jinxian</au><au>Li, Zejun</au><au>Tan, Zhaoyi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rapid method for sequential determination of Pu and Am in soil and sediment samples by sector-field inductively coupled plasma mass spectrometry</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2021-04-01</date><risdate>2021</risdate><volume>328</volume><issue>1</issue><spage>137</spage><epage>147</epage><pages>137-147</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>New method was developed to analyze Pu and Am sequentially for soil and sediment by inductively coupled plasma mass spectrometry (ICPMS). The developed method uses conc. HNO
3
to leach Pu and Am, Fe(OH)
3
coprecipitation to remove alkali and alkaline metals, extraction chromatographic separation using UTEVA, DGA and TEVA resins to remove interfering elements (IEs) and separate Pu and Am from each other, and sector field-ICPMS to measure Pu and Am. The analysis of four standard reference materials showed that both Pu isotopes and
241
Am were accurately determined by this method, as a result of its excellent decontamination ability of IEs. Especially the high decontamination factor of Pu [DF(Pu), 4.2 × 10
2
] in Am fraction and high DF(Am) (7.0 × 10
3
) in Pu fraction sufficiently eliminated the cross interference between
241
Pu and
241
Am in ICPMS measurement. In addition, stable and high chemical recoveries were achieved for Pu (71–91%) and Am (70–88%). The low LODs of Pu isotopes, short analytical time (14 h) and high DFs of IEs allows this method to sequentially analyze Pu and Am, for both global fallout and nuclear accident sourced samples.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10967-021-07627-w</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0003-3153-6775</orcidid></addata></record> |
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| source | SpringerLink Journals |
| subjects | Alkali metals Analysis Chemistry Chemistry and Materials Science Decontamination Diagnostic Radiology Fallout Ferric hydroxide Hadrons Heavy Ions Inductively coupled plasma mass spectrometry Inorganic Chemistry Iron Isotopes Mass spectrometry Methods Nuclear accidents Nuclear Chemistry Nuclear Physics Physical Chemistry Polyurethane resins Scientific imaging Sediments (Geology) Soils Spectroscopy Standard reference materials |
| title | Rapid method for sequential determination of Pu and Am in soil and sediment samples by sector-field inductively coupled plasma mass spectrometry |
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