Dynamics of Water Absorption by the Copolymer of Dimethyldiallylammonium Chloride and Acrylic Acid
The swelling of the cyclochain copolymer of N , N -dimethyl- N , N -diallylammonium chloride with acrylic acid in water was studied. For the first time, an increase in the maximum possible moisture capacity of the copolymer with increasing relative volume of the water used was shown. The results obt...
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Veröffentlicht in: | Russian journal of general chemistry 2021-03, Vol.91 (3), p.554-558 |
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creator | Borisov, I. M. Rashidova, S. T. Luksha, R. S. |
description | The swelling of the cyclochain copolymer of
N
,
N
-dimethyl-
N
,
N
-diallylammonium chloride with acrylic acid in water was studied. For the first time, an increase in the maximum possible moisture capacity of the copolymer with increasing relative volume of the water used was shown. The results obtained were interpreted on the basis of the two-stage equilibrium water absorption scheme: water + hydrogel ↔ hydrated associates of linear macromolecules ↔ insoluble microparticles with absorbed water. |
doi_str_mv | 10.1134/S1070363221030257 |
format | Article |
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N
,
N
-dimethyl-
N
,
N
-diallylammonium chloride with acrylic acid in water was studied. For the first time, an increase in the maximum possible moisture capacity of the copolymer with increasing relative volume of the water used was shown. The results obtained were interpreted on the basis of the two-stage equilibrium water absorption scheme: water + hydrogel ↔ hydrated associates of linear macromolecules ↔ insoluble microparticles with absorbed water.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363221030257</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Acrylic acid ; Acrylics ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Chlorides ; Copolymers ; Hydrogels ; Macromolecules ; Microparticles ; Water absorption</subject><ispartof>Russian journal of general chemistry, 2021-03, Vol.91 (3), p.554-558</ispartof><rights>Pleiades Publishing, Ltd. 2021</rights><rights>COPYRIGHT 2021 Springer</rights><rights>Pleiades Publishing, Ltd. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c307t-898a25aa623385c756f8e0a6914537a5722338ac7b6f40bbd96e022b9ba69dbd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363221030257$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363221030257$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27926,27927,41490,42559,51321</link.rule.ids></links><search><creatorcontrib>Borisov, I. M.</creatorcontrib><creatorcontrib>Rashidova, S. T.</creatorcontrib><creatorcontrib>Luksha, R. S.</creatorcontrib><title>Dynamics of Water Absorption by the Copolymer of Dimethyldiallylammonium Chloride and Acrylic Acid</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>The swelling of the cyclochain copolymer of
N
,
N
-dimethyl-
N
,
N
-diallylammonium chloride with acrylic acid in water was studied. For the first time, an increase in the maximum possible moisture capacity of the copolymer with increasing relative volume of the water used was shown. The results obtained were interpreted on the basis of the two-stage equilibrium water absorption scheme: water + hydrogel ↔ hydrated associates of linear macromolecules ↔ insoluble microparticles with absorbed water.</description><subject>Acrylic acid</subject><subject>Acrylics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Chlorides</subject><subject>Copolymers</subject><subject>Hydrogels</subject><subject>Macromolecules</subject><subject>Microparticles</subject><subject>Water absorption</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kM1KxDAURoMoOI4-gLuA6443Sdu0y9LxDwZcqLgsSZvOZEibmnQWfXtTKrgQyeKGfOck4UPolsCGEBbfvxHgwFJGKQEGNOFnaEVSyCLGEjgP-xBHc36Jrrw_AhCAlK6Q3E696HTtsW3xpxiVw4X01g2jtj2WEx4PCpd2sGbqQhagre7UeJhMo4UxkxFdZ3t96nB5MNbpRmHRN7io3WR0HaZurtFFK4xXNz9zjT4eH97L52j3-vRSFruoZsDHKMszQRMhUspYltQ8SdtMgUhzEieMi4TTORA1l2kbg5RNniqgVOYyMI1s2BrdLfcOzn6dlB-roz25PjxZ0YTEnJCcxYHaLNReGFXpvrWjE3VYjQo12F61OpwXnGQsB5rNAlmE2lnvnWqrwelOuKkiUM3dV3-6Dw5dHB_Yfq_c71f-l74BZ0eE0Q</recordid><startdate>20210301</startdate><enddate>20210301</enddate><creator>Borisov, I. M.</creator><creator>Rashidova, S. T.</creator><creator>Luksha, R. S.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210301</creationdate><title>Dynamics of Water Absorption by the Copolymer of Dimethyldiallylammonium Chloride and Acrylic Acid</title><author>Borisov, I. M. ; Rashidova, S. T. ; Luksha, R. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c307t-898a25aa623385c756f8e0a6914537a5722338ac7b6f40bbd96e022b9ba69dbd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acrylic acid</topic><topic>Acrylics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Chlorides</topic><topic>Copolymers</topic><topic>Hydrogels</topic><topic>Macromolecules</topic><topic>Microparticles</topic><topic>Water absorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Borisov, I. M.</creatorcontrib><creatorcontrib>Rashidova, S. T.</creatorcontrib><creatorcontrib>Luksha, R. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Borisov, I. M.</au><au>Rashidova, S. T.</au><au>Luksha, R. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dynamics of Water Absorption by the Copolymer of Dimethyldiallylammonium Chloride and Acrylic Acid</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2021-03-01</date><risdate>2021</risdate><volume>91</volume><issue>3</issue><spage>554</spage><epage>558</epage><pages>554-558</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>The swelling of the cyclochain copolymer of
N
,
N
-dimethyl-
N
,
N
-diallylammonium chloride with acrylic acid in water was studied. For the first time, an increase in the maximum possible moisture capacity of the copolymer with increasing relative volume of the water used was shown. The results obtained were interpreted on the basis of the two-stage equilibrium water absorption scheme: water + hydrogel ↔ hydrated associates of linear macromolecules ↔ insoluble microparticles with absorbed water.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363221030257</doi><tpages>5</tpages></addata></record> |
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subjects | Acrylic acid Acrylics Chemistry Chemistry and Materials Science Chemistry/Food Science Chlorides Copolymers Hydrogels Macromolecules Microparticles Water absorption |
title | Dynamics of Water Absorption by the Copolymer of Dimethyldiallylammonium Chloride and Acrylic Acid |
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