Quasilinear 3d-metal() complexes [KM(N(Dipp)SiR)] (M = Cr-Co) - structural diversity, solution state behaviour and reactivity

The synthesis and characterization of neutral quasilinear 3d-metal( i ) complexes of chromium to cobalt of the type [KM(N(Dipp)SiMe 3 ) 2 ] (Dipp = 2,6-di-iso-propylphenyl) are reported. In solid state these metal( i ) complexes either occur as isolated molecules (Co) or are part of a potassium ion...

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