Close band center and rapid adsorption kinetics facilitate selective electrochemical sensing of heavy metal ions
Combining density functional theory calculation with experiments and kinetics simulation, a multiscale framework describing the influence of reactant - substrate interaction on electrochemical performance was proposed. It was found that the close band center and the rapid adsorption kinetics facilit...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-04, Vol.57 (31), p.382-3823 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Song, Zong-Yin Li, Pei-Hua Yang, Meng Chen, Shi-Hua Xiao, Xiang-Yu Duan, Wanchun Lin, Chu-Hong Huang, Xing-Jiu |
| description | Combining density functional theory calculation with experiments and kinetics simulation, a multiscale framework describing the influence of reactant
-
substrate interaction on electrochemical performance was proposed. It was found that the close band center and the rapid adsorption kinetics facilitated the highly selective response of Ni(111) toward Cu(
ii
), providing a useful tactic to investigate the mechanism of electro-selectivity. This work not only verified that the interaction strength in the
ex situ
conditions, and kinetics rate could be applied to evaluate the electrochemical selectivity, but also contributed to the options and forecasting of selective electrode materials for heavy metal ions.
Combination of density functional theory calculation and kinetics simulation reveals the mechanism of electrochemical selectivity towards Cu(
ii
). |
| doi_str_mv | 10.1039/d1cc00735a |
| format | Article |
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-
substrate interaction on electrochemical performance was proposed. It was found that the close band center and the rapid adsorption kinetics facilitated the highly selective response of Ni(111) toward Cu(
ii
), providing a useful tactic to investigate the mechanism of electro-selectivity. This work not only verified that the interaction strength in the
ex situ
conditions, and kinetics rate could be applied to evaluate the electrochemical selectivity, but also contributed to the options and forecasting of selective electrode materials for heavy metal ions.
Combination of density functional theory calculation and kinetics simulation reveals the mechanism of electrochemical selectivity towards Cu(
ii
).</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d1cc00735a</identifier><identifier>PMID: 33876131</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Adsorption ; Density functional theory ; Electrochemical analysis ; Electrode materials ; Heavy metals ; Kinetics ; Materials selection ; Mathematical analysis ; Metal ions ; Selectivity ; Substrates</subject><ispartof>Chemical communications (Cambridge, England), 2021-04, Vol.57 (31), p.382-3823</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-251710f55ac75b8f43a81e942b3927373580156177e14afae78add3f89e5b3933</citedby><cites>FETCH-LOGICAL-c337t-251710f55ac75b8f43a81e942b3927373580156177e14afae78add3f89e5b3933</cites><orcidid>0000-0002-0395-4892 ; 0000-0001-8479-9291</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33876131$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Song, Zong-Yin</creatorcontrib><creatorcontrib>Li, Pei-Hua</creatorcontrib><creatorcontrib>Yang, Meng</creatorcontrib><creatorcontrib>Chen, Shi-Hua</creatorcontrib><creatorcontrib>Xiao, Xiang-Yu</creatorcontrib><creatorcontrib>Duan, Wanchun</creatorcontrib><creatorcontrib>Lin, Chu-Hong</creatorcontrib><creatorcontrib>Huang, Xing-Jiu</creatorcontrib><title>Close band center and rapid adsorption kinetics facilitate selective electrochemical sensing of heavy metal ions</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>Combining density functional theory calculation with experiments and kinetics simulation, a multiscale framework describing the influence of reactant
-
substrate interaction on electrochemical performance was proposed. It was found that the close band center and the rapid adsorption kinetics facilitated the highly selective response of Ni(111) toward Cu(
ii
), providing a useful tactic to investigate the mechanism of electro-selectivity. This work not only verified that the interaction strength in the
ex situ
conditions, and kinetics rate could be applied to evaluate the electrochemical selectivity, but also contributed to the options and forecasting of selective electrode materials for heavy metal ions.
Combination of density functional theory calculation and kinetics simulation reveals the mechanism of electrochemical selectivity towards Cu(
ii
).</description><subject>Adsorption</subject><subject>Density functional theory</subject><subject>Electrochemical analysis</subject><subject>Electrode materials</subject><subject>Heavy metals</subject><subject>Kinetics</subject><subject>Materials selection</subject><subject>Mathematical analysis</subject><subject>Metal ions</subject><subject>Selectivity</subject><subject>Substrates</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpFkctLAzEQxoMotlYv3pWAN2E12Ww22WNZn1DwouBtyWZnbeq-TNJC_3vTh3Uu85H58Q3zBaFLSu4oYdl9RbUmRDCujtCYsjSJeCI_jzeaZ5FgCR-hM-cWJBTl8hSNGJMipYyO0ZA3vQNcqq7CGjoPFm-kVYOpsKpcbwdv-g5_mw680Q7XSpvGeOUBO2hAe7MCvBW213NojVZNmHTOdF-4r_Ec1GqNW_DhORi5c3RSq8bBxb5P0MfT43v-Es3enl_z6SzSjAkfxZwKSmrOlRa8lHXClKSQJXHJsliwcKwMt6RUCKCJqhUIqaqK1TIDHhDGJuhm5zvY_mcJzheLfmm7sLII3nEqiCQ8ULc7StveOQt1MVjTKrsuKCk24RYPNM-34U4DfL23XJYtVAf0L80AXO0A6_Rh-v877BdzLX7S</recordid><startdate>20210421</startdate><enddate>20210421</enddate><creator>Song, Zong-Yin</creator><creator>Li, Pei-Hua</creator><creator>Yang, Meng</creator><creator>Chen, Shi-Hua</creator><creator>Xiao, Xiang-Yu</creator><creator>Duan, Wanchun</creator><creator>Lin, Chu-Hong</creator><creator>Huang, Xing-Jiu</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-0395-4892</orcidid><orcidid>https://orcid.org/0000-0001-8479-9291</orcidid></search><sort><creationdate>20210421</creationdate><title>Close band center and rapid adsorption kinetics facilitate selective electrochemical sensing of heavy metal ions</title><author>Song, Zong-Yin ; Li, Pei-Hua ; Yang, Meng ; Chen, Shi-Hua ; Xiao, Xiang-Yu ; Duan, Wanchun ; Lin, Chu-Hong ; Huang, Xing-Jiu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-251710f55ac75b8f43a81e942b3927373580156177e14afae78add3f89e5b3933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Adsorption</topic><topic>Density functional theory</topic><topic>Electrochemical analysis</topic><topic>Electrode materials</topic><topic>Heavy metals</topic><topic>Kinetics</topic><topic>Materials selection</topic><topic>Mathematical analysis</topic><topic>Metal ions</topic><topic>Selectivity</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Song, Zong-Yin</creatorcontrib><creatorcontrib>Li, Pei-Hua</creatorcontrib><creatorcontrib>Yang, Meng</creatorcontrib><creatorcontrib>Chen, Shi-Hua</creatorcontrib><creatorcontrib>Xiao, Xiang-Yu</creatorcontrib><creatorcontrib>Duan, Wanchun</creatorcontrib><creatorcontrib>Lin, Chu-Hong</creatorcontrib><creatorcontrib>Huang, Xing-Jiu</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Song, Zong-Yin</au><au>Li, Pei-Hua</au><au>Yang, Meng</au><au>Chen, Shi-Hua</au><au>Xiao, Xiang-Yu</au><au>Duan, Wanchun</au><au>Lin, Chu-Hong</au><au>Huang, Xing-Jiu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Close band center and rapid adsorption kinetics facilitate selective electrochemical sensing of heavy metal ions</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2021-04-21</date><risdate>2021</risdate><volume>57</volume><issue>31</issue><spage>382</spage><epage>3823</epage><pages>382-3823</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Combining density functional theory calculation with experiments and kinetics simulation, a multiscale framework describing the influence of reactant
-
substrate interaction on electrochemical performance was proposed. It was found that the close band center and the rapid adsorption kinetics facilitated the highly selective response of Ni(111) toward Cu(
ii
), providing a useful tactic to investigate the mechanism of electro-selectivity. This work not only verified that the interaction strength in the
ex situ
conditions, and kinetics rate could be applied to evaluate the electrochemical selectivity, but also contributed to the options and forecasting of selective electrode materials for heavy metal ions.
Combination of density functional theory calculation and kinetics simulation reveals the mechanism of electrochemical selectivity towards Cu(
ii
).</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>33876131</pmid><doi>10.1039/d1cc00735a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-0395-4892</orcidid><orcidid>https://orcid.org/0000-0001-8479-9291</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2021-04, Vol.57 (31), p.382-3823 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_journals_2512670805 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Adsorption Density functional theory Electrochemical analysis Electrode materials Heavy metals Kinetics Materials selection Mathematical analysis Metal ions Selectivity Substrates |
| title | Close band center and rapid adsorption kinetics facilitate selective electrochemical sensing of heavy metal ions |
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