Creating New Battery Configuration Associated with the Functions of Primary and Rechargeable Lithium Metal Batteries
Although the primary lithium/fluorinated graphite battery has a high energy density of 3725 Wh kg−1, its complete irreversibility based on a conversion reaction between Li and fluorinated graphite hampers wide applications in rechargeable systems. Here, a new rechargeable three‐electrode battery con...
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| Veröffentlicht in: | Advanced energy materials 2021-04, Vol.11 (14), p.n/a |
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| creator | Chen, Hao Cao, Zhenjiang Gu, Jianan Cui, Yanglansen Zhang, Yongzheng Zhao, Zehua Cheng, Zongju Zhao, Qi Li, Bin Yang, Shubin |
| description | Although the primary lithium/fluorinated graphite battery has a high energy density of 3725 Wh kg−1, its complete irreversibility based on a conversion reaction between Li and fluorinated graphite hampers wide applications in rechargeable systems. Here, a new rechargeable three‐electrode battery configuration involving lithium, fluorinated graphite, and sulfur electrodes is developed, in which the initial middle‐fluorinated graphite cathode can be electrochemically transformed into a hybrid lithium anode, showing a low overpotential (12 mV), long cycle life (2000 h) and good deep stripping/plating features. This rechargeable battery delivers a high gravimetric energy density of 507.7 Wh kg−1 on the basis of the total mass of the three‐electrode materials. Moreover, the excessive consumption of lithium in the system can be in situ replenished, further lengthening the lifespan.
A rechargeable three‐electrode battery configuration involving in lithium, fluorinated graphite and sulfur electrodes is developed, in which the initial middle‐fluorinated graphite cathodes can be electrochemically transformed into hybrid lithium anodes. This rechargeable battery configuration delivers a high energy density up to 507.7 Wh kg‐1 and good cycle stability. Moreover, the excessive consumption of lithium can be in situ replenished, lengthening the lifespan. |
| doi_str_mv | 10.1002/aenm.202003746 |
| format | Article |
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A rechargeable three‐electrode battery configuration involving in lithium, fluorinated graphite and sulfur electrodes is developed, in which the initial middle‐fluorinated graphite cathodes can be electrochemically transformed into hybrid lithium anodes. This rechargeable battery configuration delivers a high energy density up to 507.7 Wh kg‐1 and good cycle stability. Moreover, the excessive consumption of lithium can be in situ replenished, lengthening the lifespan.</description><identifier>ISSN: 1614-6832</identifier><identifier>EISSN: 1614-6840</identifier><identifier>DOI: 10.1002/aenm.202003746</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>anodes ; Batteries ; Configurations ; Electrode materials ; fluorinated graphite ; Fluorination ; Flux density ; Graphite ; Gravimetry ; Lithium ; Lithium batteries ; lithium replenishment ; primary lithium batteries ; Rechargeable batteries ; rechargeable lithium batteries</subject><ispartof>Advanced energy materials, 2021-04, Vol.11 (14), p.n/a</ispartof><rights>2021 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3546-cde010670e4d189f4a0cb036c8014db3d199bc898e5e439ed8a2a0835486b6903</citedby><cites>FETCH-LOGICAL-c3546-cde010670e4d189f4a0cb036c8014db3d199bc898e5e439ed8a2a0835486b6903</cites><orcidid>0000-0002-6526-1274 ; 0000-0001-9973-9785</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faenm.202003746$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faenm.202003746$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Chen, Hao</creatorcontrib><creatorcontrib>Cao, Zhenjiang</creatorcontrib><creatorcontrib>Gu, Jianan</creatorcontrib><creatorcontrib>Cui, Yanglansen</creatorcontrib><creatorcontrib>Zhang, Yongzheng</creatorcontrib><creatorcontrib>Zhao, Zehua</creatorcontrib><creatorcontrib>Cheng, Zongju</creatorcontrib><creatorcontrib>Zhao, Qi</creatorcontrib><creatorcontrib>Li, Bin</creatorcontrib><creatorcontrib>Yang, Shubin</creatorcontrib><title>Creating New Battery Configuration Associated with the Functions of Primary and Rechargeable Lithium Metal Batteries</title><title>Advanced energy materials</title><description>Although the primary lithium/fluorinated graphite battery has a high energy density of 3725 Wh kg−1, its complete irreversibility based on a conversion reaction between Li and fluorinated graphite hampers wide applications in rechargeable systems. Here, a new rechargeable three‐electrode battery configuration involving lithium, fluorinated graphite, and sulfur electrodes is developed, in which the initial middle‐fluorinated graphite cathode can be electrochemically transformed into a hybrid lithium anode, showing a low overpotential (12 mV), long cycle life (2000 h) and good deep stripping/plating features. This rechargeable battery delivers a high gravimetric energy density of 507.7 Wh kg−1 on the basis of the total mass of the three‐electrode materials. Moreover, the excessive consumption of lithium in the system can be in situ replenished, further lengthening the lifespan.
A rechargeable three‐electrode battery configuration involving in lithium, fluorinated graphite and sulfur electrodes is developed, in which the initial middle‐fluorinated graphite cathodes can be electrochemically transformed into hybrid lithium anodes. This rechargeable battery configuration delivers a high energy density up to 507.7 Wh kg‐1 and good cycle stability. Moreover, the excessive consumption of lithium can be in situ replenished, lengthening the lifespan.</description><subject>anodes</subject><subject>Batteries</subject><subject>Configurations</subject><subject>Electrode materials</subject><subject>fluorinated graphite</subject><subject>Fluorination</subject><subject>Flux density</subject><subject>Graphite</subject><subject>Gravimetry</subject><subject>Lithium</subject><subject>Lithium batteries</subject><subject>lithium replenishment</subject><subject>primary lithium batteries</subject><subject>Rechargeable batteries</subject><subject>rechargeable lithium batteries</subject><issn>1614-6832</issn><issn>1614-6840</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkEFLw0AQhRdRsNRePS94Tp3NbjbJsYZWhbaK6HnZbCZtSprU3Q2l_96UFD06lxl475thHiH3DKYMIHzU2OynIYQAPBbyioyYZCKQiYDr35mHt2Ti3A76EikDzkfEZxa1r5oNXeORPmnv0Z5o1jZltelsr7QNnTnXmkp7LOix8lvqt0gXXWPOoqNtSd9ttdc9ppuCfqDZartBnddIl7296vZ0hV7Xl-0VujtyU-ra4eTSx-RrMf_MXoLl2_NrNlsGhkdCBqZAYCBjQFGwJC2FBpMDlyYBJoqcFyxNc5OkCUYoeIpFokMNSc8mMpcp8DF5GPYebPvdofNq13a26U-qMGKhDKM4Zr1rOriMbZ2zWKrD8I9ioM7hqnO46jfcHkgH4FjVePrHrWbz9eqP_QEJWX5K</recordid><startdate>20210401</startdate><enddate>20210401</enddate><creator>Chen, Hao</creator><creator>Cao, Zhenjiang</creator><creator>Gu, Jianan</creator><creator>Cui, Yanglansen</creator><creator>Zhang, Yongzheng</creator><creator>Zhao, Zehua</creator><creator>Cheng, Zongju</creator><creator>Zhao, Qi</creator><creator>Li, Bin</creator><creator>Yang, Shubin</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-6526-1274</orcidid><orcidid>https://orcid.org/0000-0001-9973-9785</orcidid></search><sort><creationdate>20210401</creationdate><title>Creating New Battery Configuration Associated with the Functions of Primary and Rechargeable Lithium Metal Batteries</title><author>Chen, Hao ; Cao, Zhenjiang ; Gu, Jianan ; Cui, Yanglansen ; Zhang, Yongzheng ; Zhao, Zehua ; Cheng, Zongju ; Zhao, Qi ; Li, Bin ; Yang, Shubin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3546-cde010670e4d189f4a0cb036c8014db3d199bc898e5e439ed8a2a0835486b6903</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>anodes</topic><topic>Batteries</topic><topic>Configurations</topic><topic>Electrode materials</topic><topic>fluorinated graphite</topic><topic>Fluorination</topic><topic>Flux density</topic><topic>Graphite</topic><topic>Gravimetry</topic><topic>Lithium</topic><topic>Lithium batteries</topic><topic>lithium replenishment</topic><topic>primary lithium batteries</topic><topic>Rechargeable batteries</topic><topic>rechargeable lithium batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Hao</creatorcontrib><creatorcontrib>Cao, Zhenjiang</creatorcontrib><creatorcontrib>Gu, Jianan</creatorcontrib><creatorcontrib>Cui, Yanglansen</creatorcontrib><creatorcontrib>Zhang, Yongzheng</creatorcontrib><creatorcontrib>Zhao, Zehua</creatorcontrib><creatorcontrib>Cheng, Zongju</creatorcontrib><creatorcontrib>Zhao, Qi</creatorcontrib><creatorcontrib>Li, Bin</creatorcontrib><creatorcontrib>Yang, Shubin</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced energy materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Hao</au><au>Cao, Zhenjiang</au><au>Gu, Jianan</au><au>Cui, Yanglansen</au><au>Zhang, Yongzheng</au><au>Zhao, Zehua</au><au>Cheng, Zongju</au><au>Zhao, Qi</au><au>Li, Bin</au><au>Yang, Shubin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Creating New Battery Configuration Associated with the Functions of Primary and Rechargeable Lithium Metal Batteries</atitle><jtitle>Advanced energy materials</jtitle><date>2021-04-01</date><risdate>2021</risdate><volume>11</volume><issue>14</issue><epage>n/a</epage><issn>1614-6832</issn><eissn>1614-6840</eissn><abstract>Although the primary lithium/fluorinated graphite battery has a high energy density of 3725 Wh kg−1, its complete irreversibility based on a conversion reaction between Li and fluorinated graphite hampers wide applications in rechargeable systems. Here, a new rechargeable three‐electrode battery configuration involving lithium, fluorinated graphite, and sulfur electrodes is developed, in which the initial middle‐fluorinated graphite cathode can be electrochemically transformed into a hybrid lithium anode, showing a low overpotential (12 mV), long cycle life (2000 h) and good deep stripping/plating features. This rechargeable battery delivers a high gravimetric energy density of 507.7 Wh kg−1 on the basis of the total mass of the three‐electrode materials. Moreover, the excessive consumption of lithium in the system can be in situ replenished, further lengthening the lifespan.
A rechargeable three‐electrode battery configuration involving in lithium, fluorinated graphite and sulfur electrodes is developed, in which the initial middle‐fluorinated graphite cathodes can be electrochemically transformed into hybrid lithium anodes. This rechargeable battery configuration delivers a high energy density up to 507.7 Wh kg‐1 and good cycle stability. Moreover, the excessive consumption of lithium can be in situ replenished, lengthening the lifespan.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aenm.202003746</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-6526-1274</orcidid><orcidid>https://orcid.org/0000-0001-9973-9785</orcidid></addata></record> |
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| subjects | anodes Batteries Configurations Electrode materials fluorinated graphite Fluorination Flux density Graphite Gravimetry Lithium Lithium batteries lithium replenishment primary lithium batteries Rechargeable batteries rechargeable lithium batteries |
| title | Creating New Battery Configuration Associated with the Functions of Primary and Rechargeable Lithium Metal Batteries |
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