Electronic Effects in the Structure of 1-Ethyl-3-Methylimidazolium Ionic Liquids
In this study, ten 1-ethyl-3-methylimidazolium ionic liquids are analyzed by X-ray photoelectron spectroscopy. A reliable charge correction method is established based upon the binding energy difference between cationic N 1 s and C 2 1 s . It is found that the C aliphatic 1 s component is applicable...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2021-04, Vol.95 (4), p.736-740 |
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| container_title | Russian Journal of Physical Chemistry A |
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| creator | Li Wei Wang, Shengqun Men, Shuang |
| description | In this study, ten 1-ethyl-3-methylimidazolium ionic liquids are analyzed by X-ray photoelectron spectroscopy. A reliable charge correction method is established based upon the binding energy difference between cationic N 1
s
and C
2
1
s
. It is found that the C
aliphatic
1
s
component is applicable for charge correction only if the Kamlet-Taft hydrogen bond acceptor ability value is larger than 0.77. The electronic environment of nitrogen and sulfur atoms is demonstrated in detail. The impact of the substituent on the binding energy of P 2
p
and B 1
s
is discussed. |
| doi_str_mv | 10.1134/S0036024421040270 |
| format | Article |
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s
and C
2
1
s
. It is found that the C
aliphatic
1
s
component is applicable for charge correction only if the Kamlet-Taft hydrogen bond acceptor ability value is larger than 0.77. The electronic environment of nitrogen and sulfur atoms is demonstrated in detail. The impact of the substituent on the binding energy of P 2
p
and B 1
s
is discussed.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024421040270</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Binding energy ; Chemistry ; Chemistry and Materials Science ; Electronic properties ; Hydrogen bonds ; Ionic liquids ; Ions ; Nitrogen ; Photoelectrons ; Physical Chemistry ; Structure of Matter and Quantum Chemistry</subject><ispartof>Russian Journal of Physical Chemistry A, 2021-04, Vol.95 (4), p.736-740</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 0036-0244, Russian Journal of Physical Chemistry A, 2021, Vol. 95, No. 4, pp. 736–740. © Pleiades Publishing, Ltd., 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-9eedf83142e2a82ae9a325638c9a29e77c1484acb02ea797e0fd80ebda9f142c3</citedby><cites>FETCH-LOGICAL-c316t-9eedf83142e2a82ae9a325638c9a29e77c1484acb02ea797e0fd80ebda9f142c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036024421040270$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036024421040270$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Li Wei</creatorcontrib><creatorcontrib>Wang, Shengqun</creatorcontrib><creatorcontrib>Men, Shuang</creatorcontrib><title>Electronic Effects in the Structure of 1-Ethyl-3-Methylimidazolium Ionic Liquids</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>In this study, ten 1-ethyl-3-methylimidazolium ionic liquids are analyzed by X-ray photoelectron spectroscopy. A reliable charge correction method is established based upon the binding energy difference between cationic N 1
s
and C
2
1
s
. It is found that the C
aliphatic
1
s
component is applicable for charge correction only if the Kamlet-Taft hydrogen bond acceptor ability value is larger than 0.77. The electronic environment of nitrogen and sulfur atoms is demonstrated in detail. The impact of the substituent on the binding energy of P 2
p
and B 1
s
is discussed.</description><subject>Binding energy</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electronic properties</subject><subject>Hydrogen bonds</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Nitrogen</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Structure of Matter and Quantum Chemistry</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEUxIMoWKsfwFvAczR5yf47Slm1UFGogrclzb7YlO1um2QP-undtYIH8fQGZn7zYAi5FPxaCKlulpzLlINSILjikPEjMhGJFCxP5dsxmYw2G_1TchbChnOllFAT8lw2aKLvWmdoae2gA3UtjWuky-h7E3uPtLNUsDKuPxom2SOOwm1drT-7xvVbOv-mF27fuzqckxOrm4AXP3dKXu_Kl9kDWzzdz2e3C2akSCMrEGubS6EAQeegsdASklTmptBQYJYZoXKlzYoD6qzIkNs657iqdWEHyMgpuTr07ny37zHEatP1vh1eVpAIkAUkCoaUOKSM70LwaKudd1vtPyrBq3G46s9wAwMHJgzZ9h39b_P_0BdBim7N</recordid><startdate>20210401</startdate><enddate>20210401</enddate><creator>Li Wei</creator><creator>Wang, Shengqun</creator><creator>Men, Shuang</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210401</creationdate><title>Electronic Effects in the Structure of 1-Ethyl-3-Methylimidazolium Ionic Liquids</title><author>Li Wei ; Wang, Shengqun ; Men, Shuang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-9eedf83142e2a82ae9a325638c9a29e77c1484acb02ea797e0fd80ebda9f142c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Binding energy</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electronic properties</topic><topic>Hydrogen bonds</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Nitrogen</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Structure of Matter and Quantum Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li Wei</creatorcontrib><creatorcontrib>Wang, Shengqun</creatorcontrib><creatorcontrib>Men, Shuang</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li Wei</au><au>Wang, Shengqun</au><au>Men, Shuang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electronic Effects in the Structure of 1-Ethyl-3-Methylimidazolium Ionic Liquids</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2021-04-01</date><risdate>2021</risdate><volume>95</volume><issue>4</issue><spage>736</spage><epage>740</epage><pages>736-740</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>In this study, ten 1-ethyl-3-methylimidazolium ionic liquids are analyzed by X-ray photoelectron spectroscopy. A reliable charge correction method is established based upon the binding energy difference between cationic N 1
s
and C
2
1
s
. It is found that the C
aliphatic
1
s
component is applicable for charge correction only if the Kamlet-Taft hydrogen bond acceptor ability value is larger than 0.77. The electronic environment of nitrogen and sulfur atoms is demonstrated in detail. The impact of the substituent on the binding energy of P 2
p
and B 1
s
is discussed.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036024421040270</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
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| issn | 0036-0244 1531-863X |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Binding energy Chemistry Chemistry and Materials Science Electronic properties Hydrogen bonds Ionic liquids Ions Nitrogen Photoelectrons Physical Chemistry Structure of Matter and Quantum Chemistry |
| title | Electronic Effects in the Structure of 1-Ethyl-3-Methylimidazolium Ionic Liquids |
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