Nanocomposite synthesis of silver doped magnesium oxide incorporated in PVC matrix for photocatalytic applications
This work reveals a sol–gel approach for synthesis of silver doped magnesium oxide (Ag:MgO) incorporated in PVC matrix to give Ag:MgO/PVC nanocomposite. On glass substrate three different percentages of Ag:MgO/PVC (3,7, and 10%) were deposited by spin coating method. This film of Ag:MgO/PVC nanocomp...
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| Veröffentlicht in: | Journal of polymer research 2021-05, Vol.28 (5), Article 154 |
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| creator | Rouabah, Nouhad Boudine, Boubekeur Nazir, Roshan Zaabat, Mourad Alqahtani, Ali S Alqahtani, Mohammed S Syed, Rabbani |
| description | This work reveals a sol–gel approach for synthesis of silver doped magnesium oxide (Ag:MgO) incorporated in PVC matrix to give Ag:MgO/PVC nanocomposite. On glass substrate three different percentages of Ag:MgO/PVC (3,7, and 10%) were deposited by spin coating method. This film of Ag:MgO/PVC nanocomposites were characterized using AFM, UV–Vis, XRD and FTIR analysis. The results of XRD revealed the formation of Ag doped MgO nanoparticles with two phases (MgO and metallic Ag) in the matrix of PVC with the average size of nanoparticles equal to 31.5,22.29, 23.77, 29.68 nm. The direct band gap energy for PVC and pure MgO/PVC was 4.1 eV and 3.85 eV respectively. The band gap energy value changes from 3.85 eV, 3.75 eV, 3.71 eV, 3.69 eV with increasing Ag:MgO concentration(3–10%). Atomic force microscopyalso shows a change in the roughness of the nanocomposites film with increasing Ag:MgO nanoparticles percentage. The photocatalytic activity of this nanocomposite film was evaluated for the methylene blue (MB) dye under UV light irradiation. The result demonstrated good potential of Ag:MgO/PVC nanocomposites films for MB degradation with a suitable photocatalytic reaction proposed mechanism. The kinetic studies revealed a rate constant of 6.25 × 10
–3
min
−1
for 10% Ag:MgO/PVC nanocomposite thin films. |
| doi_str_mv | 10.1007/s10965-021-02516-y |
| format | Article |
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–3
min
−1
for 10% Ag:MgO/PVC nanocomposite thin films.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-021-02516-y</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Atomic force microscopy ; Catalytic activity ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Energy gap ; Energy value ; Glass substrates ; Industrial Chemistry/Chemical Engineering ; Light irradiation ; Magnesium oxide ; Methylene blue ; Nanocomposites ; Nanoparticles ; Original Paper ; Photocatalysis ; Polymer Sciences ; Silver ; Sol-gel processes ; Spin coating ; Superconductors (materials) ; Synthesis ; Thin films ; Ultraviolet radiation</subject><ispartof>Journal of polymer research, 2021-05, Vol.28 (5), Article 154</ispartof><rights>The Polymer Society, Taipei 2021</rights><rights>The Polymer Society, Taipei 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-faf5a8b84c4fd6dfcaed8ff11254cf1b384a1a49c061e205786fb72fe9f58c743</citedby><cites>FETCH-LOGICAL-c356t-faf5a8b84c4fd6dfcaed8ff11254cf1b384a1a49c061e205786fb72fe9f58c743</cites><orcidid>0000-0002-1268-9381</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-021-02516-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-021-02516-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Rouabah, Nouhad</creatorcontrib><creatorcontrib>Boudine, Boubekeur</creatorcontrib><creatorcontrib>Nazir, Roshan</creatorcontrib><creatorcontrib>Zaabat, Mourad</creatorcontrib><creatorcontrib>Alqahtani, Ali S</creatorcontrib><creatorcontrib>Alqahtani, Mohammed S</creatorcontrib><creatorcontrib>Syed, Rabbani</creatorcontrib><title>Nanocomposite synthesis of silver doped magnesium oxide incorporated in PVC matrix for photocatalytic applications</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>This work reveals a sol–gel approach for synthesis of silver doped magnesium oxide (Ag:MgO) incorporated in PVC matrix to give Ag:MgO/PVC nanocomposite. On glass substrate three different percentages of Ag:MgO/PVC (3,7, and 10%) were deposited by spin coating method. This film of Ag:MgO/PVC nanocomposites were characterized using AFM, UV–Vis, XRD and FTIR analysis. The results of XRD revealed the formation of Ag doped MgO nanoparticles with two phases (MgO and metallic Ag) in the matrix of PVC with the average size of nanoparticles equal to 31.5,22.29, 23.77, 29.68 nm. The direct band gap energy for PVC and pure MgO/PVC was 4.1 eV and 3.85 eV respectively. The band gap energy value changes from 3.85 eV, 3.75 eV, 3.71 eV, 3.69 eV with increasing Ag:MgO concentration(3–10%). Atomic force microscopyalso shows a change in the roughness of the nanocomposites film with increasing Ag:MgO nanoparticles percentage. The photocatalytic activity of this nanocomposite film was evaluated for the methylene blue (MB) dye under UV light irradiation. The result demonstrated good potential of Ag:MgO/PVC nanocomposites films for MB degradation with a suitable photocatalytic reaction proposed mechanism. The kinetic studies revealed a rate constant of 6.25 × 10
–3
min
−1
for 10% Ag:MgO/PVC nanocomposite thin films.</description><subject>Atomic force microscopy</subject><subject>Catalytic activity</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Energy gap</subject><subject>Energy value</subject><subject>Glass substrates</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Light irradiation</subject><subject>Magnesium oxide</subject><subject>Methylene blue</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Original Paper</subject><subject>Photocatalysis</subject><subject>Polymer Sciences</subject><subject>Silver</subject><subject>Sol-gel processes</subject><subject>Spin coating</subject><subject>Superconductors (materials)</subject><subject>Synthesis</subject><subject>Thin films</subject><subject>Ultraviolet radiation</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kE9PAyEQxYnRxFr9Ap5IPK8Cu7Ds0TT-Sxr1oF4JZaGl6QICNe63F10Tbx4mM5N5703yA-Aco0uMUHuVMOoYrRDBpShm1XgAZpi2pOJdTQ_LjAipupahY3CS0hYhSlvGZyA-SueVH4JPNmuYRpc3OtkEvYHJ7j50hL0PuoeDXLty2A_Qf9peQ-uUj8FHmcvROvj8tiiaHO0nND7CsPHZK5nlbsxWQRnCzpbVepdOwZGRu6TPfvscvN7evCzuq-XT3cPielmpmrJcGWmo5CveqMb0rDdK6p4bgzGhjTJ4VfNGYtl0CjGsCaItZ2bVEqM7Q7lqm3oOLqbcEP37Xqcstn4fXXkpCiJEOo55XVRkUqnoU4raiBDtIOMoMBLfbMXEVhS24oetGIupnkypiN1ax7_of1xfy7WAtw</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Rouabah, Nouhad</creator><creator>Boudine, Boubekeur</creator><creator>Nazir, Roshan</creator><creator>Zaabat, Mourad</creator><creator>Alqahtani, Ali S</creator><creator>Alqahtani, Mohammed S</creator><creator>Syed, Rabbani</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-1268-9381</orcidid></search><sort><creationdate>20210501</creationdate><title>Nanocomposite synthesis of silver doped magnesium oxide incorporated in PVC matrix for photocatalytic applications</title><author>Rouabah, Nouhad ; Boudine, Boubekeur ; Nazir, Roshan ; Zaabat, Mourad ; Alqahtani, Ali S ; Alqahtani, Mohammed S ; Syed, Rabbani</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-faf5a8b84c4fd6dfcaed8ff11254cf1b384a1a49c061e205786fb72fe9f58c743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Atomic force microscopy</topic><topic>Catalytic activity</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Energy gap</topic><topic>Energy value</topic><topic>Glass substrates</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Light irradiation</topic><topic>Magnesium oxide</topic><topic>Methylene blue</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Original Paper</topic><topic>Photocatalysis</topic><topic>Polymer Sciences</topic><topic>Silver</topic><topic>Sol-gel processes</topic><topic>Spin coating</topic><topic>Superconductors (materials)</topic><topic>Synthesis</topic><topic>Thin films</topic><topic>Ultraviolet radiation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rouabah, Nouhad</creatorcontrib><creatorcontrib>Boudine, Boubekeur</creatorcontrib><creatorcontrib>Nazir, Roshan</creatorcontrib><creatorcontrib>Zaabat, Mourad</creatorcontrib><creatorcontrib>Alqahtani, Ali S</creatorcontrib><creatorcontrib>Alqahtani, Mohammed S</creatorcontrib><creatorcontrib>Syed, Rabbani</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rouabah, Nouhad</au><au>Boudine, Boubekeur</au><au>Nazir, Roshan</au><au>Zaabat, Mourad</au><au>Alqahtani, Ali S</au><au>Alqahtani, Mohammed S</au><au>Syed, Rabbani</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nanocomposite synthesis of silver doped magnesium oxide incorporated in PVC matrix for photocatalytic applications</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2021-05-01</date><risdate>2021</risdate><volume>28</volume><issue>5</issue><artnum>154</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>This work reveals a sol–gel approach for synthesis of silver doped magnesium oxide (Ag:MgO) incorporated in PVC matrix to give Ag:MgO/PVC nanocomposite. On glass substrate three different percentages of Ag:MgO/PVC (3,7, and 10%) were deposited by spin coating method. This film of Ag:MgO/PVC nanocomposites were characterized using AFM, UV–Vis, XRD and FTIR analysis. The results of XRD revealed the formation of Ag doped MgO nanoparticles with two phases (MgO and metallic Ag) in the matrix of PVC with the average size of nanoparticles equal to 31.5,22.29, 23.77, 29.68 nm. The direct band gap energy for PVC and pure MgO/PVC was 4.1 eV and 3.85 eV respectively. The band gap energy value changes from 3.85 eV, 3.75 eV, 3.71 eV, 3.69 eV with increasing Ag:MgO concentration(3–10%). Atomic force microscopyalso shows a change in the roughness of the nanocomposites film with increasing Ag:MgO nanoparticles percentage. The photocatalytic activity of this nanocomposite film was evaluated for the methylene blue (MB) dye under UV light irradiation. The result demonstrated good potential of Ag:MgO/PVC nanocomposites films for MB degradation with a suitable photocatalytic reaction proposed mechanism. The kinetic studies revealed a rate constant of 6.25 × 10
–3
min
−1
for 10% Ag:MgO/PVC nanocomposite thin films.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-021-02516-y</doi><orcidid>https://orcid.org/0000-0002-1268-9381</orcidid></addata></record> |
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| subjects | Atomic force microscopy Catalytic activity Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Energy gap Energy value Glass substrates Industrial Chemistry/Chemical Engineering Light irradiation Magnesium oxide Methylene blue Nanocomposites Nanoparticles Original Paper Photocatalysis Polymer Sciences Silver Sol-gel processes Spin coating Superconductors (materials) Synthesis Thin films Ultraviolet radiation |
| title | Nanocomposite synthesis of silver doped magnesium oxide incorporated in PVC matrix for photocatalytic applications |
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