Resin, cure, and polymer properties of photopolymerizable resins containing bio‐derived isosorbide
We have developed photocurable bio‐derived isosorbide (meth)acrylates for use in photoinitiated additive manufacturing (AM). We have shown that the viscosity of isosorbide‐based resins obeyed logarithmic rule of mixtures, and the viscosity values were significantly lower than that of commercial ster...
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| Veröffentlicht in: | Journal of applied polymer science 2021-07, Vol.138 (25), p.n/a |
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| container_title | Journal of applied polymer science |
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| creator | Lastovickova, Dominika N. Toulan, Faye R. Mitchell, Joshua R. VanOosten, David Clay, Anthony M. Stanzione, Joseph F. Palmese, Giuseppe R. La Scala, John J. |
| description | We have developed photocurable bio‐derived isosorbide (meth)acrylates for use in photoinitiated additive manufacturing (AM). We have shown that the viscosity of isosorbide‐based resins obeyed logarithmic rule of mixtures, and the viscosity values were significantly lower than that of commercial stereolithography (SLA) resins as well as various other urethane (meth)acrylates and bisphenol A (meth)acrylates‐containing blends. Using isobornyl acrylate or 4‐acryloylmorpholine as reactive diluents, we were able to reduce the brittleness of the isosorbide‐based polymers and retain high glass transition temperatures (Tg) of up to 231°C. The isosorbide‐based resins were still somewhat brittle but had both greater Tg and strength relative to analogous bisphenol A dimethacrylate resins. Addition of oligomeric urethane (meth)acrylate crosslinkers further improved the mechanical properties of the polymers, whereby the strength approximately doubled to 55 MPa at 25°C, while maintaining high thermal properties, Tg > 190°C, and low viscosities, |
| doi_str_mv | 10.1002/app.50574 |
| format | Article |
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We have shown that the viscosity of isosorbide‐based resins obeyed logarithmic rule of mixtures, and the viscosity values were significantly lower than that of commercial stereolithography (SLA) resins as well as various other urethane (meth)acrylates and bisphenol A (meth)acrylates‐containing blends. Using isobornyl acrylate or 4‐acryloylmorpholine as reactive diluents, we were able to reduce the brittleness of the isosorbide‐based polymers and retain high glass transition temperatures (Tg) of up to 231°C. The isosorbide‐based resins were still somewhat brittle but had both greater Tg and strength relative to analogous bisphenol A dimethacrylate resins. Addition of oligomeric urethane (meth)acrylate crosslinkers further improved the mechanical properties of the polymers, whereby the strength approximately doubled to 55 MPa at 25°C, while maintaining high thermal properties, Tg > 190°C, and low viscosities, <140 cP, that are desirable for photoinduced AM applications. Furthermore, we were able to print this resin using SLA which produced specimens with similar moduls, but reduced strength relative to photocured resins and a commercial high temperature SLA resin.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.50574</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Acrylates ; bio‐derived resins ; Bisphenol A ; Ductile-brittle transition ; Glass transition temperature ; High temperature ; Lithography ; Materials science ; Mechanical properties ; photocure ; Polymer blends ; Polymers ; Rapid prototyping ; Resins ; Thermodynamic properties ; thermosets ; thermo‐mechanical properties ; Viscosity</subject><ispartof>Journal of applied polymer science, 2021-07, Vol.138 (25), p.n/a</ispartof><rights>2021 Wiley Periodicals LLC. 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We have shown that the viscosity of isosorbide‐based resins obeyed logarithmic rule of mixtures, and the viscosity values were significantly lower than that of commercial stereolithography (SLA) resins as well as various other urethane (meth)acrylates and bisphenol A (meth)acrylates‐containing blends. Using isobornyl acrylate or 4‐acryloylmorpholine as reactive diluents, we were able to reduce the brittleness of the isosorbide‐based polymers and retain high glass transition temperatures (Tg) of up to 231°C. The isosorbide‐based resins were still somewhat brittle but had both greater Tg and strength relative to analogous bisphenol A dimethacrylate resins. Addition of oligomeric urethane (meth)acrylate crosslinkers further improved the mechanical properties of the polymers, whereby the strength approximately doubled to 55 MPa at 25°C, while maintaining high thermal properties, Tg > 190°C, and low viscosities, <140 cP, that are desirable for photoinduced AM applications. Furthermore, we were able to print this resin using SLA which produced specimens with similar moduls, but reduced strength relative to photocured resins and a commercial high temperature SLA resin.</description><subject>Acrylates</subject><subject>bio‐derived resins</subject><subject>Bisphenol A</subject><subject>Ductile-brittle transition</subject><subject>Glass transition temperature</subject><subject>High temperature</subject><subject>Lithography</subject><subject>Materials science</subject><subject>Mechanical properties</subject><subject>photocure</subject><subject>Polymer blends</subject><subject>Polymers</subject><subject>Rapid prototyping</subject><subject>Resins</subject><subject>Thermodynamic properties</subject><subject>thermosets</subject><subject>thermo‐mechanical properties</subject><subject>Viscosity</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kE1OwzAQhS0EEqWw4AaWWCE1rX-TeFlV_EmVQAjWluNMwFUaBzsFlRVH4IychJR0y2xm8b438_QQOqdkSglhM9O2U0lkJg7QiBKVJSJl-SEa9RpNcqXkMTqJcUUIpZKkI1Q-QnTNBNtNgAk2TYlbX2_XEHAbfAuhcxCxr3D76ju_l9ynKWrAYeeM2PqmM65xzQsunP_5-i574h1K7KKPPhSuhFN0VJk6wtl-j9Hz9dXT4jZZ3t_cLebLxHIuRJIKZaTlAJQqYxmk1vJCZgqY4qYoc16VGZCCWbkbWuVcsioTWSmMFIJzPkYXw90--9sGYqdXfhOa_qVmkigmGCF5T10OlA0-xgCVboNbm7DVlOhdibovUf-V2LOzgf1wNWz_B_X84WFw_AKOxHWR</recordid><startdate>20210705</startdate><enddate>20210705</enddate><creator>Lastovickova, Dominika N.</creator><creator>Toulan, Faye R.</creator><creator>Mitchell, Joshua R.</creator><creator>VanOosten, David</creator><creator>Clay, Anthony M.</creator><creator>Stanzione, Joseph F.</creator><creator>Palmese, Giuseppe R.</creator><creator>La Scala, John J.</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-3917-3043</orcidid></search><sort><creationdate>20210705</creationdate><title>Resin, cure, and polymer properties of photopolymerizable resins containing bio‐derived isosorbide</title><author>Lastovickova, Dominika N. ; Toulan, Faye R. ; Mitchell, Joshua R. ; VanOosten, David ; Clay, Anthony M. ; Stanzione, Joseph F. ; Palmese, Giuseppe R. ; La Scala, John J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3344-649a5c3ee119ac2e6cc3b579e293abd83fd7e0b2c555551f8352f747d4a544333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acrylates</topic><topic>bio‐derived resins</topic><topic>Bisphenol A</topic><topic>Ductile-brittle transition</topic><topic>Glass transition temperature</topic><topic>High temperature</topic><topic>Lithography</topic><topic>Materials science</topic><topic>Mechanical properties</topic><topic>photocure</topic><topic>Polymer blends</topic><topic>Polymers</topic><topic>Rapid prototyping</topic><topic>Resins</topic><topic>Thermodynamic properties</topic><topic>thermosets</topic><topic>thermo‐mechanical properties</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lastovickova, Dominika N.</creatorcontrib><creatorcontrib>Toulan, Faye R.</creatorcontrib><creatorcontrib>Mitchell, Joshua R.</creatorcontrib><creatorcontrib>VanOosten, David</creatorcontrib><creatorcontrib>Clay, Anthony M.</creatorcontrib><creatorcontrib>Stanzione, Joseph F.</creatorcontrib><creatorcontrib>Palmese, Giuseppe R.</creatorcontrib><creatorcontrib>La Scala, John J.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lastovickova, Dominika N.</au><au>Toulan, Faye R.</au><au>Mitchell, Joshua R.</au><au>VanOosten, David</au><au>Clay, Anthony M.</au><au>Stanzione, Joseph F.</au><au>Palmese, Giuseppe R.</au><au>La Scala, John J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Resin, cure, and polymer properties of photopolymerizable resins containing bio‐derived isosorbide</atitle><jtitle>Journal of applied polymer science</jtitle><date>2021-07-05</date><risdate>2021</risdate><volume>138</volume><issue>25</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>We have developed photocurable bio‐derived isosorbide (meth)acrylates for use in photoinitiated additive manufacturing (AM). We have shown that the viscosity of isosorbide‐based resins obeyed logarithmic rule of mixtures, and the viscosity values were significantly lower than that of commercial stereolithography (SLA) resins as well as various other urethane (meth)acrylates and bisphenol A (meth)acrylates‐containing blends. Using isobornyl acrylate or 4‐acryloylmorpholine as reactive diluents, we were able to reduce the brittleness of the isosorbide‐based polymers and retain high glass transition temperatures (Tg) of up to 231°C. The isosorbide‐based resins were still somewhat brittle but had both greater Tg and strength relative to analogous bisphenol A dimethacrylate resins. Addition of oligomeric urethane (meth)acrylate crosslinkers further improved the mechanical properties of the polymers, whereby the strength approximately doubled to 55 MPa at 25°C, while maintaining high thermal properties, Tg > 190°C, and low viscosities, <140 cP, that are desirable for photoinduced AM applications. Furthermore, we were able to print this resin using SLA which produced specimens with similar moduls, but reduced strength relative to photocured resins and a commercial high temperature SLA resin.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.50574</doi><tpages>22</tpages><orcidid>https://orcid.org/0000-0002-3917-3043</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Acrylates bio‐derived resins Bisphenol A Ductile-brittle transition Glass transition temperature High temperature Lithography Materials science Mechanical properties photocure Polymer blends Polymers Rapid prototyping Resins Thermodynamic properties thermosets thermo‐mechanical properties Viscosity |
| title | Resin, cure, and polymer properties of photopolymerizable resins containing bio‐derived isosorbide |
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