Mechanical and optical evaluation of alginate hydrospheres produced with different cross-linking salts for industrial application
Alginate spheres complexed with various divalent cations and various counterions associated with calcium were characterized mechanically and optically. Zinc exhibited the most intense absorbance increase from the visible to ultraviolet wavelength range, a desirable characteristic for use in sunscree...
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| Veröffentlicht in: | Colloid and polymer science 2021-04, Vol.299 (4), p.693-703 |
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| creator | Cendon, Fernando Villaverde Salomão, Bárbara Busnardo Jorge, Regina Maria Matos Mathias, Alvaro Luiz |
| description | Alginate spheres complexed with various divalent cations and various counterions associated with calcium were characterized mechanically and optically. Zinc exhibited the most intense absorbance increase from the visible to ultraviolet wavelength range, a desirable characteristic for use in sunscreens. Among the calcium salts, only chloride and lactate exhibited the same behavior, although with a lower intensity. The values of the Young’s moduli of alginate spheres produced with zinc and lead were similar to the highest values that have been reported thus far, for cadmium and copper. Spheres produced with calcium gluconate were also among the stiffest. The mass of the beads decreased when they reacted with most of the saline solutions used, except in the case of calcium chloride and calcium lactate. Cations having high atomic numbers produced stiffer alginate spheres, due to the interaction mechanisms involved in polysaccharide reticulation. The present analyses are important for the development of new products and processes for the pharmaceutical, food, environmental, and biotechnological industries. |
| doi_str_mv | 10.1007/s00396-020-04787-1 |
| format | Article |
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Zinc exhibited the most intense absorbance increase from the visible to ultraviolet wavelength range, a desirable characteristic for use in sunscreens. Among the calcium salts, only chloride and lactate exhibited the same behavior, although with a lower intensity. The values of the Young’s moduli of alginate spheres produced with zinc and lead were similar to the highest values that have been reported thus far, for cadmium and copper. Spheres produced with calcium gluconate were also among the stiffest. The mass of the beads decreased when they reacted with most of the saline solutions used, except in the case of calcium chloride and calcium lactate. Cations having high atomic numbers produced stiffer alginate spheres, due to the interaction mechanisms involved in polysaccharide reticulation. 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Zinc exhibited the most intense absorbance increase from the visible to ultraviolet wavelength range, a desirable characteristic for use in sunscreens. Among the calcium salts, only chloride and lactate exhibited the same behavior, although with a lower intensity. The values of the Young’s moduli of alginate spheres produced with zinc and lead were similar to the highest values that have been reported thus far, for cadmium and copper. Spheres produced with calcium gluconate were also among the stiffest. The mass of the beads decreased when they reacted with most of the saline solutions used, except in the case of calcium chloride and calcium lactate. Cations having high atomic numbers produced stiffer alginate spheres, due to the interaction mechanisms involved in polysaccharide reticulation. 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| subjects | Adsorption Alginates Beads Binding sites Biopolymers Calcium chloride Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Cosmetics Crosslinking Divalent cations Food Food Science Heavy metals Hydrogels Industrial applications Microorganisms Nanotechnology and Microengineering Original Contribution Pharmaceuticals Photocatalysis Physical Chemistry Pollutants Polymer Sciences Polysaccharides Radiation Saline solutions Soft and Granular Matter Spectrum analysis Spheres Sun screens Sunscreen Tissue engineering Zinc |
| title | Mechanical and optical evaluation of alginate hydrospheres produced with different cross-linking salts for industrial application |
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