Groundwater quality evolution based on geochemical modeling and aptness testing for ingestion using entropy water quality and total hazard indexes in an urban-industrial area (Tiruppur) of Southern India

This study used geochemical modeling to understand the chemical evolution of groundwater, entropy water quality index to assess the aptness of groundwater for human consumption, and total hazard index to determine the possible non-carcinogenic risks among children, women, and men in an urban-industr...

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Veröffentlicht in:Environmental science and pollution research international 2021-04, Vol.28 (15), p.18523-18538
Hauptverfasser: Karunanidhi, D., Aravinthasamy, P., Deepali, M., Subramani, T., Bellows, Barbara C., Li, Peiyue
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container_end_page 18538
container_issue 15
container_start_page 18523
container_title Environmental science and pollution research international
container_volume 28
creator Karunanidhi, D.
Aravinthasamy, P.
Deepali, M.
Subramani, T.
Bellows, Barbara C.
Li, Peiyue
description This study used geochemical modeling to understand the chemical evolution of groundwater, entropy water quality index to assess the aptness of groundwater for human consumption, and total hazard index to determine the possible non-carcinogenic risks among children, women, and men in an urban-industrial area (Tiruppur region) of southern India. For the above purposes, 40 groundwater samples were collected from tube and dug wells, and they were tested for various physicochemical parameters. Fluoride and nitrate levels ranged from 0.10 to 2.70 mg/l and 10 to 290 mg/l, respectively. Nearly, 50% of the fluoride samples and 58% of the nitrate samples exceeded the WHO limits of 1.5 and 45 mg/l, respectively. The majority of the groundwater samples (22.5%) represented Ca 2+ -Na + -Cl − water type while the remaining samples exhibited mixed water types. Approximately, 85% of the samples indicated high levels of salinization since they had Revelle index > 0.5 meq/l. The saturation index (SI) revealed that mineral weathering; dissolution of halite, gypsum, and anhydrite; and precipitation of calcite and dolomite contributed to groundwater chemistry. Based on the entropy water quality index (EWQI), none of the groundwater samples was characterized as excellent or good water quality while 57.5% of the samples had medium water quality, and 32.5% and 10% of the samples exhibited poor and extremely poor water qualities, respectively. The last two categories are designated as unfit for consumption. The cumulative health risk (nitrate and fluoride together) ranged from 0.97 to 11.16 for children, 0.60 to 10.54 for women, and 0.39 to 6.92 for men. These values represent health risks among 88%, 80%, and 73% of the groundwater samples for children, women, and men, respectively. Therefore, proper measures should to be done to reduce the health risks associated with high nitrate and fluoride in the groundwater of the study area, which is used for drinking purposes.
doi_str_mv 10.1007/s11356-020-10724-0
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For the above purposes, 40 groundwater samples were collected from tube and dug wells, and they were tested for various physicochemical parameters. Fluoride and nitrate levels ranged from 0.10 to 2.70 mg/l and 10 to 290 mg/l, respectively. Nearly, 50% of the fluoride samples and 58% of the nitrate samples exceeded the WHO limits of 1.5 and 45 mg/l, respectively. The majority of the groundwater samples (22.5%) represented Ca 2+ -Na + -Cl − water type while the remaining samples exhibited mixed water types. Approximately, 85% of the samples indicated high levels of salinization since they had Revelle index &gt; 0.5 meq/l. The saturation index (SI) revealed that mineral weathering; dissolution of halite, gypsum, and anhydrite; and precipitation of calcite and dolomite contributed to groundwater chemistry. Based on the entropy water quality index (EWQI), none of the groundwater samples was characterized as excellent or good water quality while 57.5% of the samples had medium water quality, and 32.5% and 10% of the samples exhibited poor and extremely poor water qualities, respectively. The last two categories are designated as unfit for consumption. The cumulative health risk (nitrate and fluoride together) ranged from 0.97 to 11.16 for children, 0.60 to 10.54 for women, and 0.39 to 6.92 for men. These values represent health risks among 88%, 80%, and 73% of the groundwater samples for children, women, and men, respectively. 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For the above purposes, 40 groundwater samples were collected from tube and dug wells, and they were tested for various physicochemical parameters. Fluoride and nitrate levels ranged from 0.10 to 2.70 mg/l and 10 to 290 mg/l, respectively. Nearly, 50% of the fluoride samples and 58% of the nitrate samples exceeded the WHO limits of 1.5 and 45 mg/l, respectively. The majority of the groundwater samples (22.5%) represented Ca 2+ -Na + -Cl − water type while the remaining samples exhibited mixed water types. Approximately, 85% of the samples indicated high levels of salinization since they had Revelle index &gt; 0.5 meq/l. The saturation index (SI) revealed that mineral weathering; dissolution of halite, gypsum, and anhydrite; and precipitation of calcite and dolomite contributed to groundwater chemistry. 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For the above purposes, 40 groundwater samples were collected from tube and dug wells, and they were tested for various physicochemical parameters. Fluoride and nitrate levels ranged from 0.10 to 2.70 mg/l and 10 to 290 mg/l, respectively. Nearly, 50% of the fluoride samples and 58% of the nitrate samples exceeded the WHO limits of 1.5 and 45 mg/l, respectively. The majority of the groundwater samples (22.5%) represented Ca 2+ -Na + -Cl − water type while the remaining samples exhibited mixed water types. Approximately, 85% of the samples indicated high levels of salinization since they had Revelle index &gt; 0.5 meq/l. The saturation index (SI) revealed that mineral weathering; dissolution of halite, gypsum, and anhydrite; and precipitation of calcite and dolomite contributed to groundwater chemistry. Based on the entropy water quality index (EWQI), none of the groundwater samples was characterized as excellent or good water quality while 57.5% of the samples had medium water quality, and 32.5% and 10% of the samples exhibited poor and extremely poor water qualities, respectively. The last two categories are designated as unfit for consumption. The cumulative health risk (nitrate and fluoride together) ranged from 0.97 to 11.16 for children, 0.60 to 10.54 for women, and 0.39 to 6.92 for men. These values represent health risks among 88%, 80%, and 73% of the groundwater samples for children, women, and men, respectively. 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source MEDLINE; SpringerNature Journals
subjects Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
Calcite
Calcium
Calcium ions
Carcinogens
Chemical evolution
Child
Children
Consumption
Dolomite
Dug wells
Earth and Environmental Science
Eating
Ecotoxicology
Entropy
Environment
Environmental Chemistry
Environmental Health
Environmental Monitoring
Environmental science
Female
Fluorides
Geochemistry
Groundwater
Groundwater chemistry
Groundwater quality
Gypsum
Health risk assessment
Health risks
Humans
India
Industrial areas
Ingestion
Male
Modelling
Nitrates
Physicochemical properties
Quality assessment
Recent Environmental Geochemical Trends
Salinization
Saturation index
Urban areas
Waste Water Technology
Water analysis
Water Management
Water Pollutants, Chemical - analysis
Water Pollution Control
Water Quality
Water sampling
title Groundwater quality evolution based on geochemical modeling and aptness testing for ingestion using entropy water quality and total hazard indexes in an urban-industrial area (Tiruppur) of Southern India
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