Natural cork agglomerate enabled mechanically robust rigid polyurethane foams with outstanding viscoelastic damping properties

This study investigates the mechanical and damping properties of natural cork particle reinforced rigid polyurethane (PU) composite foams, and also the structure-properties relationship between their cellular microstructural morphology and their thermomechanical properties. The linear relation betwe...

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Veröffentlicht in:Polymer (Guilford) 2021-03, Vol.217, p.123437, Article 123437
Hauptverfasser: Park, Sung Jun, Cho, Seung-Hyun, Seo, Hee Won, Nam, Jae-Do, Suhr, Jonghwan
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container_start_page 123437
container_title Polymer (Guilford)
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creator Park, Sung Jun
Cho, Seung-Hyun
Seo, Hee Won
Nam, Jae-Do
Suhr, Jonghwan
description This study investigates the mechanical and damping properties of natural cork particle reinforced rigid polyurethane (PU) composite foams, and also the structure-properties relationship between their cellular microstructural morphology and their thermomechanical properties. The linear relation between reaction rate, cell size, and free rise density (FRD) of Cork/PU composite with respect to the cork loading fraction was experimentally observed and analytically confirmed. It was found that the cork particles could effectively tailor the static and dynamic viscoelastic properties of composite foams. Importantly, it was observed in the dynamic viscoelastic characterization that the Cork/PU composite foams exhibited the increase in both storage and loss moduli, which is typically compromised for each other. These results could provide broad insight and guidance in developing a novel polymeric foam with mechanical robustness and energy absorbing capability for various structural applications including electrical vehicle and drone, which requires both lightweight and strength/stiffness. [Display omitted] •Effects of cork particle on structure-properties relationship of polyurethane foam.•Mechanical behavior of cork particle filled polyurethane foam.•Increasing of hard segment due to reaction between cork particle and isocyanate.•Improvement of both storage and loss modulus.
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The linear relation between reaction rate, cell size, and free rise density (FRD) of Cork/PU composite with respect to the cork loading fraction was experimentally observed and analytically confirmed. It was found that the cork particles could effectively tailor the static and dynamic viscoelastic properties of composite foams. Importantly, it was observed in the dynamic viscoelastic characterization that the Cork/PU composite foams exhibited the increase in both storage and loss moduli, which is typically compromised for each other. These results could provide broad insight and guidance in developing a novel polymeric foam with mechanical robustness and energy absorbing capability for various structural applications including electrical vehicle and drone, which requires both lightweight and strength/stiffness. 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source Elsevier ScienceDirect Journals
subjects Cell size
Cellular structure
Cork
Cytology
Damping properties
Drone vehicles
Electric vehicles
Energy absorption
Foams
Loss modulus
Morphology
Particulate composites
Plastic foam
Polyurethane
Polyurethane foam
Properties (attributes)
Stiffness
Thermomechanical properties
Viscoelastic damping
Viscoelasticity
title Natural cork agglomerate enabled mechanically robust rigid polyurethane foams with outstanding viscoelastic damping properties
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