Square plate shaped magnetite nanocrystals

•Square plate-shaped magnetite nanocrystals were synthesized using arabinogalactan.•Stratification of the particles reduces blocking temperature and exchange constant.•Micromagnetic simulation showed extraordinary magnetization switching anisotropy. Square plate shaped magnetite nanocrystals have be...

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Veröffentlicht in:Journal of magnetism and magnetic materials 2021-06, Vol.527, p.167730, Article 167730
Hauptverfasser: Komogortsev, S.V., Stolyar, S.V., Chekanova, L.A., Yaroslavtsev, R.N., Bayukov, O.A., Velikanov, D.A., Volochaev, M.N., Eroshenko, P.E., Iskhakov, R.S.
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container_start_page 167730
container_title Journal of magnetism and magnetic materials
container_volume 527
creator Komogortsev, S.V.
Stolyar, S.V.
Chekanova, L.A.
Yaroslavtsev, R.N.
Bayukov, O.A.
Velikanov, D.A.
Volochaev, M.N.
Eroshenko, P.E.
Iskhakov, R.S.
description •Square plate-shaped magnetite nanocrystals were synthesized using arabinogalactan.•Stratification of the particles reduces blocking temperature and exchange constant.•Micromagnetic simulation showed extraordinary magnetization switching anisotropy. Square plate shaped magnetite nanocrystals have been synthesized by chemical precipitation from solution using arabinogalactan. A high crystal quality was observed in the plate plane while, across the plate, there is some stratification. The magnetic hysteresis in such particles is determined by the bulk magnetocrystalline anisotropy, plate shape anisotropy, and surface magnetic anisotropy. It is shown using the micromagnetic simulation that the ferromagnetic square nanoplates exhibit the extraordinary magnetization switching anisotropy, which should be taken into account for understanding the hysteretic properties of the particles.
doi_str_mv 10.1016/j.jmmm.2021.167730
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source Elsevier ScienceDirect Journals
subjects Anisotropy
Chemical precipitation
Chemical synthesis
Ferromagnetism
Hysteresis
Magnetic anisotropy
Magnetite
Nanocrystals
Nanoparticles
Square plates
title Square plate shaped magnetite nanocrystals
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