In-situ to ex-situ in-plane structure evolution of stern layers on Pt(111) surface: Surface X-ray scattering studies
In-situ to ex-situ evolution of the Cs+ in-plane structure in electrochemical Stern layers are investigated on Pt(111) surface with surface X-ray scattering studies. The Cs+ single-sublattice (2 × 2) structure of the Stern layer formed in situ in 0.1 M CsF electrolyte [Liu et al., J. Phys. Chem. Let...
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| Veröffentlicht in: | Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2020-10, Vol.875 (SI), p.114495, Article 114495 |
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| container_title | Journal of electroanalytical chemistry (Lausanne, Switzerland) |
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| creator | Kawaguchi, Tomoya Liu, Yihua Karapetrova, Evguenia A. Komanicky, Vladimir You, Hoydoo |
| description | In-situ to ex-situ evolution of the Cs+ in-plane structure in electrochemical Stern layers are investigated on Pt(111) surface with surface X-ray scattering studies. The Cs+ single-sublattice (2 × 2) structure of the Stern layer formed in situ in 0.1 M CsF electrolyte [Liu et al., J. Phys. Chem. Lett., 9 (2018) 1265] evolves eventually to the two-sublattice (2 × 2) structure upon emersion from the electrolyte. While the Cs+ layers maintain the (2 × 2) symmetry, the ex situ layer increases the density progressively over several minutes by incorporating Cs+ ions of the electrolyte during the emersion process. |
| doi_str_mv | 10.1016/j.jelechem.2020.114495 |
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(ANL), Argonne, IL (United States). Advanced Photon Source (APS)</creatorcontrib><description>In-situ to ex-situ evolution of the Cs+ in-plane structure in electrochemical Stern layers are investigated on Pt(111) surface with surface X-ray scattering studies. The Cs+ single-sublattice (2 × 2) structure of the Stern layer formed in situ in 0.1 M CsF electrolyte [Liu et al., J. Phys. Chem. Lett., 9 (2018) 1265] evolves eventually to the two-sublattice (2 × 2) structure upon emersion from the electrolyte. While the Cs+ layers maintain the (2 × 2) symmetry, the ex situ layer increases the density progressively over several minutes by incorporating Cs+ ions of the electrolyte during the emersion process.</description><identifier>ISSN: 1572-6657</identifier><identifier>EISSN: 1873-2569</identifier><identifier>DOI: 10.1016/j.jelechem.2020.114495</identifier><language>eng</language><publisher>LAUSANNE: Elsevier B.V</publisher><subject>Cesium fluorides ; Cesium ions ; Chemistry ; Chemistry, Analytical ; Electrochemical double layer ; Electrochemistry ; Electrolytes ; Evolution ; Hydrogen evolution reaction ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; Physical Sciences ; Science & Technology ; Stern layer ; Surface electrochemistry ; Surface X-ray scattering ; X-ray scattering</subject><ispartof>Journal of electroanalytical chemistry (Lausanne, Switzerland), 2020-10, Vol.875 (SI), p.114495, Article 114495</ispartof><rights>2020</rights><rights>Copyright Elsevier Science Ltd. 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(ANL), Argonne, IL (United States). Advanced Photon Source (APS)</creatorcontrib><title>In-situ to ex-situ in-plane structure evolution of stern layers on Pt(111) surface: Surface X-ray scattering studies</title><title>Journal of electroanalytical chemistry (Lausanne, Switzerland)</title><addtitle>J ELECTROANAL CHEM</addtitle><description>In-situ to ex-situ evolution of the Cs+ in-plane structure in electrochemical Stern layers are investigated on Pt(111) surface with surface X-ray scattering studies. The Cs+ single-sublattice (2 × 2) structure of the Stern layer formed in situ in 0.1 M CsF electrolyte [Liu et al., J. Phys. Chem. Lett., 9 (2018) 1265] evolves eventually to the two-sublattice (2 × 2) structure upon emersion from the electrolyte. While the Cs+ layers maintain the (2 × 2) symmetry, the ex situ layer increases the density progressively over several minutes by incorporating Cs+ ions of the electrolyte during the emersion process.</description><subject>Cesium fluorides</subject><subject>Cesium ions</subject><subject>Chemistry</subject><subject>Chemistry, Analytical</subject><subject>Electrochemical double layer</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Evolution</subject><subject>Hydrogen evolution reaction</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>Physical Sciences</subject><subject>Science & Technology</subject><subject>Stern layer</subject><subject>Surface electrochemistry</subject><subject>Surface X-ray scattering</subject><subject>X-ray scattering</subject><issn>1572-6657</issn><issn>1873-2569</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNkV1rFTEQhhdRsLb-BQl6o8ieTnI2H8erysGPQqGCCt6FbDKrWbbJMclWz783y1Zvay6SYXif4c28TfOMwoYCFefjZsQJ7Q-82TBgtUm7bscfNCdUyW3LuNg9rDWXrBWCy8fNk5xHAKYUZSdNuQxt9mUmJRL8vZY-tIfJBCS5pNmWOSHB2zjNxcdA4lDbmAKZzBFTJrX1qbyklL4ieU6DsfiGfF4L8q1N5kiyNaUSPnyv5Ow85rPm0WCmjE_v3tPm6_t3X_Yf26vrD5f7t1et7RQtLe8BOHUguJVMSWRbx52pVy8Y0o53olPCMDDcGuiF2_XSSSkc5YCDtN32tHm-zo25eJ2tL3VNNoaAtmgqRd0CraIXq-iQ4s8Zc9FjnFOovjTjoLhS0PGqEqvKpphzwkEfkr8x6agp6CUGPeq_MeglBr3GUMHXK_gL-zhUDxgs_oMBQADr2BaWs5hR_6_e-2KWTPZxDqWiFyuKdaO3HpO-w51Py39d9Pd5_QPUFrO0</recordid><startdate>20201015</startdate><enddate>20201015</enddate><creator>Kawaguchi, Tomoya</creator><creator>Liu, Yihua</creator><creator>Karapetrova, Evguenia A.</creator><creator>Komanicky, Vladimir</creator><creator>You, Hoydoo</creator><general>Elsevier B.V</general><general>Elsevier</general><general>Elsevier Science Ltd</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0001-8649-1987</orcidid><orcidid>https://orcid.org/0000-0002-7600-4847</orcidid></search><sort><creationdate>20201015</creationdate><title>In-situ to ex-situ in-plane structure evolution of stern layers on Pt(111) surface: Surface X-ray scattering studies</title><author>Kawaguchi, Tomoya ; Liu, Yihua ; Karapetrova, Evguenia A. ; Komanicky, Vladimir ; You, Hoydoo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c481t-5b0051d065c7287e23d5da3d5b62e14546486a20a5ca0b6d9b7d776d150ef7c43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Cesium fluorides</topic><topic>Cesium ions</topic><topic>Chemistry</topic><topic>Chemistry, Analytical</topic><topic>Electrochemical double layer</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Evolution</topic><topic>Hydrogen evolution reaction</topic><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>Physical Sciences</topic><topic>Science & Technology</topic><topic>Stern layer</topic><topic>Surface electrochemistry</topic><topic>Surface X-ray scattering</topic><topic>X-ray scattering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kawaguchi, Tomoya</creatorcontrib><creatorcontrib>Liu, Yihua</creatorcontrib><creatorcontrib>Karapetrova, Evguenia A.</creatorcontrib><creatorcontrib>Komanicky, Vladimir</creatorcontrib><creatorcontrib>You, Hoydoo</creatorcontrib><creatorcontrib>Argonne National Lab. 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Advanced Photon Source (APS)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In-situ to ex-situ in-plane structure evolution of stern layers on Pt(111) surface: Surface X-ray scattering studies</atitle><jtitle>Journal of electroanalytical chemistry (Lausanne, Switzerland)</jtitle><stitle>J ELECTROANAL CHEM</stitle><date>2020-10-15</date><risdate>2020</risdate><volume>875</volume><issue>SI</issue><spage>114495</spage><pages>114495-</pages><artnum>114495</artnum><issn>1572-6657</issn><eissn>1873-2569</eissn><abstract>In-situ to ex-situ evolution of the Cs+ in-plane structure in electrochemical Stern layers are investigated on Pt(111) surface with surface X-ray scattering studies. The Cs+ single-sublattice (2 × 2) structure of the Stern layer formed in situ in 0.1 M CsF electrolyte [Liu et al., J. Phys. Chem. Lett., 9 (2018) 1265] evolves eventually to the two-sublattice (2 × 2) structure upon emersion from the electrolyte. 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| subjects | Cesium fluorides Cesium ions Chemistry Chemistry, Analytical Electrochemical double layer Electrochemistry Electrolytes Evolution Hydrogen evolution reaction INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Physical Sciences Science & Technology Stern layer Surface electrochemistry Surface X-ray scattering X-ray scattering |
| title | In-situ to ex-situ in-plane structure evolution of stern layers on Pt(111) surface: Surface X-ray scattering studies |
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