Synthesis of Optically Active V-Shaped Molecules: Studies on the Orientation of the Stacked π-Electron Systems and their Chiroptical Properties

Chiral π-stacked molecules were prepared from planar chiral bis-(para)-pseudo-meta-type [2.2]paracyclophane. π-Electron systems were stacked to form a V-shaped structure with an angle of 120°. Optical and chiroptical properties were experimentally and theoretically investigated and compared with tho...

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2021-02, Vol.94 (2), p.451-453
Hauptverfasser: Miki, Nanami, Inoue, Ryo, Morisaki, Yasuhiro
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Sprache:eng
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