Synthesis of Optically Active V-Shaped Molecules: Studies on the Orientation of the Stacked π-Electron Systems and their Chiroptical Properties
Chiral π-stacked molecules were prepared from planar chiral bis-(para)-pseudo-meta-type [2.2]paracyclophane. π-Electron systems were stacked to form a V-shaped structure with an angle of 120°. Optical and chiroptical properties were experimentally and theoretically investigated and compared with tho...
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| Veröffentlicht in: | Bulletin of the Chemical Society of Japan 2021-02, Vol.94 (2), p.451-453 |
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| container_end_page | 453 |
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| container_issue | 2 |
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| container_title | Bulletin of the Chemical Society of Japan |
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| creator | Miki, Nanami Inoue, Ryo Morisaki, Yasuhiro |
| description | Chiral π-stacked molecules were prepared from planar chiral bis-(para)-pseudo-meta-type [2.2]paracyclophane. π-Electron systems were stacked to form a V-shaped structure with an angle of 120°. Optical and chiroptical properties were experimentally and theoretically investigated and compared with those of the V-shaped molecules comprising the same π-electron systems based on bis-(para)-pseudo-ortho-type [2.2]paracyclophane with an angle of 60°. |
| doi_str_mv | 10.1246/bcsj.20200294 |
| format | Article |
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| fulltext | fulltext |
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| ispartof | Bulletin of the Chemical Society of Japan, 2021-02, Vol.94 (2), p.451-453 |
| issn | 0009-2673 1348-0634 |
| language | eng |
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| source | Oxford University Press Journals All Titles (1996-Current) |
| subjects | Chemical synthesis Optical activity Optical properties Pi-electrons |
| title | Synthesis of Optically Active V-Shaped Molecules: Studies on the Orientation of the Stacked π-Electron Systems and their Chiroptical Properties |
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