Fabrication, characterization and optical properties of poly(p-phenylenediamine- co–o-aminophenol) nanostructure thin film
Poly(p-phenylenediamine- co–o-aminophenol) nanostructure thin film [PpPDoAP] TF was synthesized and prepared as a thin film with ≅ 100 ± 2 nm using the spin-coating method. Different characterization techniques for [PpPDoAP] TF like FTIR, UV–Vis spectroscopy, and optical properties have been studie...
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| creator | Al-Hossainy, Ahmed F. Zoromba, Mohamed Sh |
| description | Poly(p-phenylenediamine- co–o-aminophenol) nanostructure thin film [PpPDoAP]
TF
was synthesized and prepared as a thin film with ≅ 100 ± 2 nm using the spin-coating method. Different characterization techniques for [PpPDoAP]
TF
like FTIR, UV–Vis spectroscopy, and optical properties have been studied. The resulted x-ray diffraction (XRD) and scanning electron microscope (SEM) data have been employed to study interface composites. Density function theory (DFT) was used for optimization by DMol
3
and CASTEP. Spectroscopic and structural characteristics for the thin film have confirmed the chemical composition and XRD observations revealed the same crystal structure. Combined between experimental and TDD-DFT data, the average crystallite size and composite interface are 71.87 nm and orthorhombic symmetry (
a
= 7.38(2);
b
= 18.09(6);
c
= 26.09(4)
Å
and
α
=
β
=
γ
= 90°) with space group (P
mcn
) for the thin film. It is found that the calculated energy gap by DFT and experimental method are 2.523 and 2.504 eV, respectively. The electronic transition of [PpPDoAP]
TF
has direct allowed transition. Besides, the optoelectrical parameters have been calculated for the film like
n
(
λ
),
k
(
λ
), dielectric constant, and optical conductivity. CASTEP simulated values are consistent with the experimental values for optical parameters of [PpPDoAP]
TF
. The fabricated thin film can be used as a candidate material for optoelectronic devices and solar cells.
Graphic abstract |
| doi_str_mv | 10.1007/s00339-021-04434-8 |
| format | Article |
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TF
was synthesized and prepared as a thin film with ≅ 100 ± 2 nm using the spin-coating method. Different characterization techniques for [PpPDoAP]
TF
like FTIR, UV–Vis spectroscopy, and optical properties have been studied. The resulted x-ray diffraction (XRD) and scanning electron microscope (SEM) data have been employed to study interface composites. Density function theory (DFT) was used for optimization by DMol
3
and CASTEP. Spectroscopic and structural characteristics for the thin film have confirmed the chemical composition and XRD observations revealed the same crystal structure. Combined between experimental and TDD-DFT data, the average crystallite size and composite interface are 71.87 nm and orthorhombic symmetry (
a
= 7.38(2);
b
= 18.09(6);
c
= 26.09(4)
Å
and
α
=
β
=
γ
= 90°) with space group (P
mcn
) for the thin film. It is found that the calculated energy gap by DFT and experimental method are 2.523 and 2.504 eV, respectively. The electronic transition of [PpPDoAP]
TF
has direct allowed transition. Besides, the optoelectrical parameters have been calculated for the film like
n
(
λ
),
k
(
λ
), dielectric constant, and optical conductivity. CASTEP simulated values are consistent with the experimental values for optical parameters of [PpPDoAP]
TF
. The fabricated thin film can be used as a candidate material for optoelectronic devices and solar cells.
Graphic abstract</description><identifier>ISSN: 0947-8396</identifier><identifier>EISSN: 1432-0630</identifier><identifier>DOI: 10.1007/s00339-021-04434-8</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aminophenol ; Applied physics ; Characterization and Evaluation of Materials ; Chemical composition ; Condensed Matter Physics ; Crystal structure ; Crystallites ; Density functional theory ; Energy gap ; Machines ; Manufacturing ; Materials science ; Materials selection ; Mathematical analysis ; Nanostructure ; Nanotechnology ; Optical and Electronic Materials ; Optical properties ; Optimization ; Optoelectronic devices ; Parameters ; Phenylenediamine ; Photovoltaic cells ; Physics ; Physics and Astronomy ; Processes ; Solar cells ; Spin coating ; Surfaces and Interfaces ; Thin Films ; X-ray diffraction</subject><ispartof>Applied physics. A, Materials science & processing, 2021-04, Vol.127 (4), Article 278</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-b4cd28dead233343a0722ac61c487180f86f1419b0db7997b26ec8a464e513033</citedby><cites>FETCH-LOGICAL-c319t-b4cd28dead233343a0722ac61c487180f86f1419b0db7997b26ec8a464e513033</cites><orcidid>0000-0001-5531-6940</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00339-021-04434-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00339-021-04434-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Al-Hossainy, Ahmed F.</creatorcontrib><creatorcontrib>Zoromba, Mohamed Sh</creatorcontrib><title>Fabrication, characterization and optical properties of poly(p-phenylenediamine- co–o-aminophenol) nanostructure thin film</title><title>Applied physics. A, Materials science & processing</title><addtitle>Appl. Phys. A</addtitle><description>Poly(p-phenylenediamine- co–o-aminophenol) nanostructure thin film [PpPDoAP]
TF
was synthesized and prepared as a thin film with ≅ 100 ± 2 nm using the spin-coating method. Different characterization techniques for [PpPDoAP]
TF
like FTIR, UV–Vis spectroscopy, and optical properties have been studied. The resulted x-ray diffraction (XRD) and scanning electron microscope (SEM) data have been employed to study interface composites. Density function theory (DFT) was used for optimization by DMol
3
and CASTEP. Spectroscopic and structural characteristics for the thin film have confirmed the chemical composition and XRD observations revealed the same crystal structure. Combined between experimental and TDD-DFT data, the average crystallite size and composite interface are 71.87 nm and orthorhombic symmetry (
a
= 7.38(2);
b
= 18.09(6);
c
= 26.09(4)
Å
and
α
=
β
=
γ
= 90°) with space group (P
mcn
) for the thin film. It is found that the calculated energy gap by DFT and experimental method are 2.523 and 2.504 eV, respectively. The electronic transition of [PpPDoAP]
TF
has direct allowed transition. Besides, the optoelectrical parameters have been calculated for the film like
n
(
λ
),
k
(
λ
), dielectric constant, and optical conductivity. CASTEP simulated values are consistent with the experimental values for optical parameters of [PpPDoAP]
TF
. The fabricated thin film can be used as a candidate material for optoelectronic devices and solar cells.
Graphic abstract</description><subject>Aminophenol</subject><subject>Applied physics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical composition</subject><subject>Condensed Matter Physics</subject><subject>Crystal structure</subject><subject>Crystallites</subject><subject>Density functional theory</subject><subject>Energy gap</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Materials science</subject><subject>Materials selection</subject><subject>Mathematical analysis</subject><subject>Nanostructure</subject><subject>Nanotechnology</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Optimization</subject><subject>Optoelectronic devices</subject><subject>Parameters</subject><subject>Phenylenediamine</subject><subject>Photovoltaic cells</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Processes</subject><subject>Solar cells</subject><subject>Spin coating</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>X-ray diffraction</subject><issn>0947-8396</issn><issn>1432-0630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kM9KAzEQxoMoWKsv4CngRcFo_nU3exSxKhS86Dlks1mbsk3WJHuoePAdfEOfxLQreHMuw8x83wzzA-CU4CuCcXkdMWasQpgShDlnHIk9MCGcUYQLhvfBBFe8RIJVxSE4inGFc3BKJ-BjrupgtUrWu0uolyoonUyw77sOVK6Bvk9Z0ME--N6EZE2EvoW97zbnPeqXxm0640xj1do6g6D2359fHm0rv5367gI65XxMYdBpCAampXWwtd36GBy0qovm5DdPwcv87vn2AS2e7h9vbxZIM1IlVHPdUNEY1VDGGGcKl5QqXRDNRUkEbkXREk6qGjd1WVVlTQujheIFNzPCMpgpOBv35hfeBhOTXPkhuHxS0hnmgglBiqyio0oHH2MwreyDXauwkQTLLWU5UpaZstxRliKb2GiKWexeTfhb_Y_rB5aAgpk</recordid><startdate>20210401</startdate><enddate>20210401</enddate><creator>Al-Hossainy, Ahmed F.</creator><creator>Zoromba, Mohamed Sh</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-5531-6940</orcidid></search><sort><creationdate>20210401</creationdate><title>Fabrication, characterization and optical properties of poly(p-phenylenediamine- co–o-aminophenol) nanostructure thin film</title><author>Al-Hossainy, Ahmed F. ; Zoromba, Mohamed Sh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-b4cd28dead233343a0722ac61c487180f86f1419b0db7997b26ec8a464e513033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aminophenol</topic><topic>Applied physics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical composition</topic><topic>Condensed Matter Physics</topic><topic>Crystal structure</topic><topic>Crystallites</topic><topic>Density functional theory</topic><topic>Energy gap</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Materials science</topic><topic>Materials selection</topic><topic>Mathematical analysis</topic><topic>Nanostructure</topic><topic>Nanotechnology</topic><topic>Optical and Electronic Materials</topic><topic>Optical properties</topic><topic>Optimization</topic><topic>Optoelectronic devices</topic><topic>Parameters</topic><topic>Phenylenediamine</topic><topic>Photovoltaic cells</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Processes</topic><topic>Solar cells</topic><topic>Spin coating</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Al-Hossainy, Ahmed F.</creatorcontrib><creatorcontrib>Zoromba, Mohamed Sh</creatorcontrib><collection>CrossRef</collection><jtitle>Applied physics. A, Materials science & processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Al-Hossainy, Ahmed F.</au><au>Zoromba, Mohamed Sh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication, characterization and optical properties of poly(p-phenylenediamine- co–o-aminophenol) nanostructure thin film</atitle><jtitle>Applied physics. A, Materials science & processing</jtitle><stitle>Appl. Phys. A</stitle><date>2021-04-01</date><risdate>2021</risdate><volume>127</volume><issue>4</issue><artnum>278</artnum><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>Poly(p-phenylenediamine- co–o-aminophenol) nanostructure thin film [PpPDoAP]
TF
was synthesized and prepared as a thin film with ≅ 100 ± 2 nm using the spin-coating method. Different characterization techniques for [PpPDoAP]
TF
like FTIR, UV–Vis spectroscopy, and optical properties have been studied. The resulted x-ray diffraction (XRD) and scanning electron microscope (SEM) data have been employed to study interface composites. Density function theory (DFT) was used for optimization by DMol
3
and CASTEP. Spectroscopic and structural characteristics for the thin film have confirmed the chemical composition and XRD observations revealed the same crystal structure. Combined between experimental and TDD-DFT data, the average crystallite size and composite interface are 71.87 nm and orthorhombic symmetry (
a
= 7.38(2);
b
= 18.09(6);
c
= 26.09(4)
Å
and
α
=
β
=
γ
= 90°) with space group (P
mcn
) for the thin film. It is found that the calculated energy gap by DFT and experimental method are 2.523 and 2.504 eV, respectively. The electronic transition of [PpPDoAP]
TF
has direct allowed transition. Besides, the optoelectrical parameters have been calculated for the film like
n
(
λ
),
k
(
λ
), dielectric constant, and optical conductivity. CASTEP simulated values are consistent with the experimental values for optical parameters of [PpPDoAP]
TF
. The fabricated thin film can be used as a candidate material for optoelectronic devices and solar cells.
Graphic abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00339-021-04434-8</doi><orcidid>https://orcid.org/0000-0001-5531-6940</orcidid></addata></record> |
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| subjects | Aminophenol Applied physics Characterization and Evaluation of Materials Chemical composition Condensed Matter Physics Crystal structure Crystallites Density functional theory Energy gap Machines Manufacturing Materials science Materials selection Mathematical analysis Nanostructure Nanotechnology Optical and Electronic Materials Optical properties Optimization Optoelectronic devices Parameters Phenylenediamine Photovoltaic cells Physics Physics and Astronomy Processes Solar cells Spin coating Surfaces and Interfaces Thin Films X-ray diffraction |
| title | Fabrication, characterization and optical properties of poly(p-phenylenediamine- co–o-aminophenol) nanostructure thin film |
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