Acid Generation and Heavy Metal Leachability from Lignite Spoil Heaps: Impact to the Topsoils of Oropos Basin, North Attica, Greece
The disposal of lignite spoil and tailings poses a major environmental problem in lignite mining sites which is associated with the oxidation of sulfide minerals contained in the primary ore. This process renders acidic effluents. Lignite mining in the Oropos Neogene basin, North Attica, Greece oper...
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Veröffentlicht in: | Bulletin of environmental contamination and toxicology 2021-03, Vol.106 (3), p.465-474 |
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creator | Kampouroglou, Evdokia Kollias, Konstantinos Stouraiti, Christina Arvaniti, Lamprini Papassiopi, Nymphodora |
description | The disposal of lignite spoil and tailings poses a major environmental problem in lignite mining sites which is associated with the oxidation of sulfide minerals contained in the primary ore. This process renders acidic effluents. Lignite mining in the Oropos Neogene basin, North Attica, Greece operated since the last century and ceased in the late 1960s. Piles of complex waste material are dispersed close to the mining sites. The high sulfur content and low Net Neutralization Potential, i.e. values |
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3
kg/t in most analyzed waste samples, indicate that the waste is prone to acid generation. The leachates (EN12457) from the lignite spoils showed high concentrations in Ni and Zn exceeding the EU regulatory limits for the non-hazardous wastes. GIS-based geochemical maps of the topsoil showed enrichment in Ni (Cr, V) associated with the regional geogenic enrichment but also local accumulation around the hot spot sites of lignite spoil heaps.</description><identifier>ISSN: 0007-4861</identifier><identifier>EISSN: 1432-0800</identifier><identifier>DOI: 10.1007/s00128-021-03122-w</identifier><identifier>PMID: 33587150</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aquatic Pollution ; Calcium carbonate ; Chromium ; Coal ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental Monitoring ; Greece ; Hazardous wastes ; Heavy metals ; Leachates ; Leaching ; Lignite ; Metals, Heavy - analysis ; Mine tailings ; Minerals ; Mining ; Neogene ; Neutralization ; Oxidation ; Pollution ; Soil ; Soil Pollutants - analysis ; Soil Science & Conservation ; Sulfides ; Sulfur ; Sulfur content ; Topsoil ; Waste materials ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Bulletin of environmental contamination and toxicology, 2021-03, Vol.106 (3), p.465-474</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c375t-a07008701a94a1b17aa51ecc765fe91923a9512c633450f3878eccbe5dc303013</citedby><cites>FETCH-LOGICAL-c375t-a07008701a94a1b17aa51ecc765fe91923a9512c633450f3878eccbe5dc303013</cites><orcidid>0000-0001-9269-1555</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00128-021-03122-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00128-021-03122-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33587150$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kampouroglou, Evdokia</creatorcontrib><creatorcontrib>Kollias, Konstantinos</creatorcontrib><creatorcontrib>Stouraiti, Christina</creatorcontrib><creatorcontrib>Arvaniti, Lamprini</creatorcontrib><creatorcontrib>Papassiopi, Nymphodora</creatorcontrib><title>Acid Generation and Heavy Metal Leachability from Lignite Spoil Heaps: Impact to the Topsoils of Oropos Basin, North Attica, Greece</title><title>Bulletin of environmental contamination and toxicology</title><addtitle>Bull Environ Contam Toxicol</addtitle><addtitle>Bull Environ Contam Toxicol</addtitle><description>The disposal of lignite spoil and tailings poses a major environmental problem in lignite mining sites which is associated with the oxidation of sulfide minerals contained in the primary ore. This process renders acidic effluents. Lignite mining in the Oropos Neogene basin, North Attica, Greece operated since the last century and ceased in the late 1960s. Piles of complex waste material are dispersed close to the mining sites. The high sulfur content and low Net Neutralization Potential, i.e. values < − 20 CaCO
3
kg/t in most analyzed waste samples, indicate that the waste is prone to acid generation. The leachates (EN12457) from the lignite spoils showed high concentrations in Ni and Zn exceeding the EU regulatory limits for the non-hazardous wastes. GIS-based geochemical maps of the topsoil showed enrichment in Ni (Cr, V) associated with the regional geogenic enrichment but also local accumulation around the hot spot sites of lignite spoil heaps.</description><subject>Aquatic Pollution</subject><subject>Calcium carbonate</subject><subject>Chromium</subject><subject>Coal</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental Monitoring</subject><subject>Greece</subject><subject>Hazardous wastes</subject><subject>Heavy metals</subject><subject>Leachates</subject><subject>Leaching</subject><subject>Lignite</subject><subject>Metals, Heavy - analysis</subject><subject>Mine tailings</subject><subject>Minerals</subject><subject>Mining</subject><subject>Neogene</subject><subject>Neutralization</subject><subject>Oxidation</subject><subject>Pollution</subject><subject>Soil</subject><subject>Soil Pollutants - analysis</subject><subject>Soil Science & Conservation</subject><subject>Sulfides</subject><subject>Sulfur</subject><subject>Sulfur content</subject><subject>Topsoil</subject><subject>Waste materials</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>0007-4861</issn><issn>1432-0800</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kEFvEzEQhS0EoqHwBzigkbh2YWzHWS-3tIK0UqAHytmaOLONq2S92A5VzvxxXFLgxmkO73tvpE-I1xLfScT2fUaUyjaoZINaKtXcPxETOdWqQYv4VEywUs3UzuSJeJHzXcWNVeq5ONHa2FYanIifcx_WsOCBE5UQB6BhDZdMPw7wmQttYcnkN7QK21AO0Ke4g2W4HUJh-DrGsH1gx_wBrnYj-QIlQtkw3MQx1zBD7OE6xTFmOKcchjP4ElPZwLyU4OkMFonZ80vxrKdt5leP91R8-_Tx5uKyWV4vri7my8br1pSGsEW0LUrqpiRXsiUykr1vZ6bnTnZKU2ek8jOtpwZ7bVtb0xWbtdeoUepT8fa4O6b4fc-5uLu4T0N96ZTB6qRTM1spdaR8ijkn7t2Ywo7SwUl0D97d0bur3t1v7-6-lt48Tu9XO17_rfwRXQF9BHKNhltO_37_Z_YXuJWNGg</recordid><startdate>20210301</startdate><enddate>20210301</enddate><creator>Kampouroglou, Evdokia</creator><creator>Kollias, Konstantinos</creator><creator>Stouraiti, Christina</creator><creator>Arvaniti, Lamprini</creator><creator>Papassiopi, Nymphodora</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7T7</scope><scope>7TK</scope><scope>7TV</scope><scope>7U7</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>88I</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>P64</scope><scope>PATMY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><orcidid>https://orcid.org/0000-0001-9269-1555</orcidid></search><sort><creationdate>20210301</creationdate><title>Acid Generation and Heavy Metal Leachability from Lignite Spoil Heaps: Impact to the Topsoils of Oropos Basin, North Attica, Greece</title><author>Kampouroglou, Evdokia ; Kollias, Konstantinos ; Stouraiti, Christina ; Arvaniti, Lamprini ; Papassiopi, Nymphodora</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c375t-a07008701a94a1b17aa51ecc765fe91923a9512c633450f3878eccbe5dc303013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aquatic Pollution</topic><topic>Calcium carbonate</topic><topic>Chromium</topic><topic>Coal</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental Monitoring</topic><topic>Greece</topic><topic>Hazardous wastes</topic><topic>Heavy metals</topic><topic>Leachates</topic><topic>Leaching</topic><topic>Lignite</topic><topic>Metals, Heavy - 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This process renders acidic effluents. Lignite mining in the Oropos Neogene basin, North Attica, Greece operated since the last century and ceased in the late 1960s. Piles of complex waste material are dispersed close to the mining sites. The high sulfur content and low Net Neutralization Potential, i.e. values < − 20 CaCO
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kg/t in most analyzed waste samples, indicate that the waste is prone to acid generation. The leachates (EN12457) from the lignite spoils showed high concentrations in Ni and Zn exceeding the EU regulatory limits for the non-hazardous wastes. GIS-based geochemical maps of the topsoil showed enrichment in Ni (Cr, V) associated with the regional geogenic enrichment but also local accumulation around the hot spot sites of lignite spoil heaps.</abstract><cop>New York</cop><pub>Springer US</pub><pmid>33587150</pmid><doi>10.1007/s00128-021-03122-w</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-9269-1555</orcidid></addata></record> |
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subjects | Aquatic Pollution Calcium carbonate Chromium Coal Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Environmental Monitoring Greece Hazardous wastes Heavy metals Leachates Leaching Lignite Metals, Heavy - analysis Mine tailings Minerals Mining Neogene Neutralization Oxidation Pollution Soil Soil Pollutants - analysis Soil Science & Conservation Sulfides Sulfur Sulfur content Topsoil Waste materials Waste Water Technology Water Management Water Pollution Control |
title | Acid Generation and Heavy Metal Leachability from Lignite Spoil Heaps: Impact to the Topsoils of Oropos Basin, North Attica, Greece |
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