The impact of the counterion in the performance of ionic hydrotropes

The impact of the counterion in the performance of ionic hydrotropes

The efficiency of an ionic hydrotrope is shown to increase with the hydrophobicity of its counterion, challenging the common view that ionic hydrotropes should possess a small, densely charged counterion such as sodium or chloride. Highly hydrophilic counterions such as sodium or chloride are not go...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-03, Vol.57 (23), p.2951-2954
Hauptverfasser: Abranches, Dinis O, Benfica, Jordana, Soares, Bruna P, Ferreira, Ana M, Sintra, Tânia E, Shimizu, Seishi, Coutinho, João A. P
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Sprache:eng
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Hydrophobicity
Hydrotropes
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container_end_page 2954
container_issue 23
container_start_page 2951
container_title Chemical communications (Cambridge, England)
container_volume 57
creator Abranches, Dinis O
Benfica, Jordana
Soares, Bruna P
Ferreira, Ana M
Sintra, Tânia E
Shimizu, Seishi
Coutinho, João A. P
description The efficiency of an ionic hydrotrope is shown to increase with the hydrophobicity of its counterion, challenging the common view that ionic hydrotropes should possess a small, densely charged counterion such as sodium or chloride. Highly hydrophilic counterions such as sodium or chloride are not good choices as counterions to achieve efficient hydrotropy.
doi_str_mv 10.1039/d0cc08092f
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Hydrophobicity
Hydrotropes
title The impact of the counterion in the performance of ionic hydrotropes
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