Green synthesis and characterization of poly(glycerol‐azelaic acid) and its nanocomposites for applications in regenerative medicine
A series of novel bio‐polyester nanocomposites based on glycerin and azelaic acid as monomers incorporating hydroxyapatite (HA) nanoparticles were fabricated via in situ polymerization method. Chemical structure of the samples was investigated by 1H‐NMR, 13C‐NMR, and Fourier‐transform infrared spect...
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| Veröffentlicht in: | Journal of applied polymer science 2021-06, Vol.138 (24), p.n/a |
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| creator | Hosseini Chenani, Fatemeh Rezaei, Vahid Faghihi Fakhri, Vafa Wurm, Frederik R. Uzun, Lokman Goodarzi, Vahabodin |
| description | A series of novel bio‐polyester nanocomposites based on glycerin and azelaic acid as monomers incorporating hydroxyapatite (HA) nanoparticles were fabricated via in situ polymerization method. Chemical structure of the samples was investigated by 1H‐NMR, 13C‐NMR, and Fourier‐transform infrared spectroscopy (FTIR). Energy dispersive X‐ray‐mapping analysis illustrated that the nanoparticles were well dispersed in the poly (glycerol azelaic acid) (PGAZ) matrix. Viscoelastic properties of the samples under various frequencies were examined in which the PGAZ specimen containing 1.0 wt% of HA nanoparticles (PGAZH1.0) exhibited superlative properties. Furthermore, the alterations in the glass transition temperature of the samples were comprehensively discussed. Thermal gravimetric analysis displayed that nanocomposites generally have a difference in degradation patterns from that of the pristine sample. Dynamic contact angle demonstrated that the presence of HA nanoparticles imposed a significant influence on hydrophilicity. The hydrolytic degradation values at pH = 7 and pH = 11 were measured and determined that the degradation rate for the PGAZ sample containing 1.5 wt% HA (PGAZH1.5) was higher than those of the other samples. Moreover, in vitro studies elucidated that cell attachment on PGAZH1.0 and PAZH1.5 surfaces were acceptable. |
| doi_str_mv | 10.1002/app.50563 |
| format | Article |
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Chemical structure of the samples was investigated by 1H‐NMR, 13C‐NMR, and Fourier‐transform infrared spectroscopy (FTIR). Energy dispersive X‐ray‐mapping analysis illustrated that the nanoparticles were well dispersed in the poly (glycerol azelaic acid) (PGAZ) matrix. Viscoelastic properties of the samples under various frequencies were examined in which the PGAZ specimen containing 1.0 wt% of HA nanoparticles (PGAZH1.0) exhibited superlative properties. Furthermore, the alterations in the glass transition temperature of the samples were comprehensively discussed. Thermal gravimetric analysis displayed that nanocomposites generally have a difference in degradation patterns from that of the pristine sample. Dynamic contact angle demonstrated that the presence of HA nanoparticles imposed a significant influence on hydrophilicity. The hydrolytic degradation values at pH = 7 and pH = 11 were measured and determined that the degradation rate for the PGAZ sample containing 1.5 wt% HA (PGAZH1.5) was higher than those of the other samples. Moreover, in vitro studies elucidated that cell attachment on PGAZH1.0 and PAZH1.5 surfaces were acceptable.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.50563</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>biopolymers and renewable polymers ; biosynthesis of polymers ; Contact angle ; Degradation ; Dispersion ; Glass transition temperature ; Glycerol ; Gravimetric analysis ; Hydroxyapatite ; Infrared analysis ; Materials science ; Nanocomposites ; Nanoparticles ; NMR ; Nuclear magnetic resonance ; Polymers</subject><ispartof>Journal of applied polymer science, 2021-06, Vol.138 (24), p.n/a</ispartof><rights>2021 Wiley Periodicals LLC.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3693-2ddc8bfd4668b1e1d3f2af6db4adc2e5d00730bebc752bac9a4cb931a4a50b9e3</citedby><cites>FETCH-LOGICAL-c3693-2ddc8bfd4668b1e1d3f2af6db4adc2e5d00730bebc752bac9a4cb931a4a50b9e3</cites><orcidid>0000-0002-7295-5434</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.50563$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.50563$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Hosseini Chenani, Fatemeh</creatorcontrib><creatorcontrib>Rezaei, Vahid Faghihi</creatorcontrib><creatorcontrib>Fakhri, Vafa</creatorcontrib><creatorcontrib>Wurm, Frederik R.</creatorcontrib><creatorcontrib>Uzun, Lokman</creatorcontrib><creatorcontrib>Goodarzi, Vahabodin</creatorcontrib><title>Green synthesis and characterization of poly(glycerol‐azelaic acid) and its nanocomposites for applications in regenerative medicine</title><title>Journal of applied polymer science</title><description>A series of novel bio‐polyester nanocomposites based on glycerin and azelaic acid as monomers incorporating hydroxyapatite (HA) nanoparticles were fabricated via in situ polymerization method. Chemical structure of the samples was investigated by 1H‐NMR, 13C‐NMR, and Fourier‐transform infrared spectroscopy (FTIR). Energy dispersive X‐ray‐mapping analysis illustrated that the nanoparticles were well dispersed in the poly (glycerol azelaic acid) (PGAZ) matrix. Viscoelastic properties of the samples under various frequencies were examined in which the PGAZ specimen containing 1.0 wt% of HA nanoparticles (PGAZH1.0) exhibited superlative properties. Furthermore, the alterations in the glass transition temperature of the samples were comprehensively discussed. Thermal gravimetric analysis displayed that nanocomposites generally have a difference in degradation patterns from that of the pristine sample. Dynamic contact angle demonstrated that the presence of HA nanoparticles imposed a significant influence on hydrophilicity. The hydrolytic degradation values at pH = 7 and pH = 11 were measured and determined that the degradation rate for the PGAZ sample containing 1.5 wt% HA (PGAZH1.5) was higher than those of the other samples. Moreover, in vitro studies elucidated that cell attachment on PGAZH1.0 and PAZH1.5 surfaces were acceptable.</description><subject>biopolymers and renewable polymers</subject><subject>biosynthesis of polymers</subject><subject>Contact angle</subject><subject>Degradation</subject><subject>Dispersion</subject><subject>Glass transition temperature</subject><subject>Glycerol</subject><subject>Gravimetric analysis</subject><subject>Hydroxyapatite</subject><subject>Infrared analysis</subject><subject>Materials science</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kLFOwzAQhi0EEqUw8AaWWOiQ1o6TNBmrCgpSJTrAHF3sS-sqtYOdgtKJiZln5EkIDSvTSXff__93R8g1Z2POWDiBuh7HLE7ECRlwlk2DKAnTUzLoZjxIsyw-JxfebxnjPGbJgHwuHKKhvjXNBr32FIyicgMOZINOH6DR1lBb0tpW7e26aiU6W31_fMEBK9CSgtRqdFTpxlMDxkq7q63XDXpaWke7jSotjz6eakMdrtGg6xpvSHeotNQGL8lZCZXHq786JC_3d8_zh2D5tHicz5aBFEkmglApmRalipIkLThyJcoQykQVESgZYqwYmwpWYCGncViAzCCSRSY4RBCzIkMxJDe9b-3s6x59k2_t3pkuMg9jxoTIeJczJKOeks5677DMa6d34Nqcs_z3zXl3VH58c8dOevZdV9j-D-az1apX_AAsHoQb</recordid><startdate>20210620</startdate><enddate>20210620</enddate><creator>Hosseini Chenani, Fatemeh</creator><creator>Rezaei, Vahid Faghihi</creator><creator>Fakhri, Vafa</creator><creator>Wurm, Frederik R.</creator><creator>Uzun, Lokman</creator><creator>Goodarzi, Vahabodin</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-7295-5434</orcidid></search><sort><creationdate>20210620</creationdate><title>Green synthesis and characterization of poly(glycerol‐azelaic acid) and its nanocomposites for applications in regenerative medicine</title><author>Hosseini Chenani, Fatemeh ; Rezaei, Vahid Faghihi ; Fakhri, Vafa ; Wurm, Frederik R. ; Uzun, Lokman ; Goodarzi, Vahabodin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3693-2ddc8bfd4668b1e1d3f2af6db4adc2e5d00730bebc752bac9a4cb931a4a50b9e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>biopolymers and renewable polymers</topic><topic>biosynthesis of polymers</topic><topic>Contact angle</topic><topic>Degradation</topic><topic>Dispersion</topic><topic>Glass transition temperature</topic><topic>Glycerol</topic><topic>Gravimetric analysis</topic><topic>Hydroxyapatite</topic><topic>Infrared analysis</topic><topic>Materials science</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hosseini Chenani, Fatemeh</creatorcontrib><creatorcontrib>Rezaei, Vahid Faghihi</creatorcontrib><creatorcontrib>Fakhri, Vafa</creatorcontrib><creatorcontrib>Wurm, Frederik R.</creatorcontrib><creatorcontrib>Uzun, Lokman</creatorcontrib><creatorcontrib>Goodarzi, Vahabodin</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hosseini Chenani, Fatemeh</au><au>Rezaei, Vahid Faghihi</au><au>Fakhri, Vafa</au><au>Wurm, Frederik R.</au><au>Uzun, Lokman</au><au>Goodarzi, Vahabodin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Green synthesis and characterization of poly(glycerol‐azelaic acid) and its nanocomposites for applications in regenerative medicine</atitle><jtitle>Journal of applied polymer science</jtitle><date>2021-06-20</date><risdate>2021</risdate><volume>138</volume><issue>24</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>A series of novel bio‐polyester nanocomposites based on glycerin and azelaic acid as monomers incorporating hydroxyapatite (HA) nanoparticles were fabricated via in situ polymerization method. Chemical structure of the samples was investigated by 1H‐NMR, 13C‐NMR, and Fourier‐transform infrared spectroscopy (FTIR). Energy dispersive X‐ray‐mapping analysis illustrated that the nanoparticles were well dispersed in the poly (glycerol azelaic acid) (PGAZ) matrix. Viscoelastic properties of the samples under various frequencies were examined in which the PGAZ specimen containing 1.0 wt% of HA nanoparticles (PGAZH1.0) exhibited superlative properties. Furthermore, the alterations in the glass transition temperature of the samples were comprehensively discussed. Thermal gravimetric analysis displayed that nanocomposites generally have a difference in degradation patterns from that of the pristine sample. Dynamic contact angle demonstrated that the presence of HA nanoparticles imposed a significant influence on hydrophilicity. The hydrolytic degradation values at pH = 7 and pH = 11 were measured and determined that the degradation rate for the PGAZ sample containing 1.5 wt% HA (PGAZH1.5) was higher than those of the other samples. Moreover, in vitro studies elucidated that cell attachment on PGAZH1.0 and PAZH1.5 surfaces were acceptable.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.50563</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-7295-5434</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | biopolymers and renewable polymers biosynthesis of polymers Contact angle Degradation Dispersion Glass transition temperature Glycerol Gravimetric analysis Hydroxyapatite Infrared analysis Materials science Nanocomposites Nanoparticles NMR Nuclear magnetic resonance Polymers |
| title | Green synthesis and characterization of poly(glycerol‐azelaic acid) and its nanocomposites for applications in regenerative medicine |
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