Hydrogenation of 1,5,9-Cyclododecatriene in a Three-Phase System in the Presence of Nickel Nanoparticles Supported on NаX Zeolite
Hydrogenation of 1,5,9-cyclododecatriene in the presence of nanostructured nickel catalysts in a flow-through reactor at atmospheric hydrogen pressure was studied. NaX zeolite was used as a support. Nickel nanoparticles on the support surface were prepared by chemical reduction of the precursor (NiC...
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| Veröffentlicht in: | Russian journal of applied chemistry 2021, Vol.94 (1), p.110-115 |
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| container_title | Russian journal of applied chemistry |
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| creator | Nebykov, D. N. Popov, Yu. V. Mokhov, V. M. Shcherbakova, K. V. Zotov, Yu. L. |
| description | Hydrogenation of 1,5,9-cyclododecatriene in the presence of nanostructured nickel catalysts in a flow-through reactor at atmospheric hydrogen pressure was studied. NaX zeolite was used as a support. Nickel nanoparticles on the support surface were prepared by chemical reduction of the precursor (NiCl
2
) with NaBH
4
and NH
2
NH
2
. The influence exerted on the yield of hydrogenation products by the nominal residence time of the gas phase in the reaction zone and by the process temperature was considered, and the catalyst operation life was analyzed. The catalysts showed high activity and allowed preparation of cyclododecane in ~100% yield at a process temperature of up to 160°С. |
| doi_str_mv | 10.1134/S107042722101016X |
| format | Article |
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2
) with NaBH
4
and NH
2
NH
2
. The influence exerted on the yield of hydrogenation products by the nominal residence time of the gas phase in the reaction zone and by the process temperature was considered, and the catalyst operation life was analyzed. The catalysts showed high activity and allowed preparation of cyclododecane in ~100% yield at a process temperature of up to 160°С.</description><identifier>ISSN: 1070-4272</identifier><identifier>EISSN: 1608-3296</identifier><identifier>DOI: 10.1134/S107042722101016X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Catalysis ; Catalysts ; Chemical reduction ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Hydrogenation ; Industrial Chemistry/Chemical Engineering ; Nanoparticles ; Nickel ; Vapor phases ; Zeolites</subject><ispartof>Russian journal of applied chemistry, 2021, Vol.94 (1), p.110-115</ispartof><rights>Pleiades Publishing, Ltd. 2021</rights><rights>Pleiades Publishing, Ltd. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c231X-f439b9ba223850a1b741f03195c88ab54dc7a515be459538b03d248ee735cca53</citedby><cites>FETCH-LOGICAL-c231X-f439b9ba223850a1b741f03195c88ab54dc7a515be459538b03d248ee735cca53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S107042722101016X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S107042722101016X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Nebykov, D. N.</creatorcontrib><creatorcontrib>Popov, Yu. V.</creatorcontrib><creatorcontrib>Mokhov, V. M.</creatorcontrib><creatorcontrib>Shcherbakova, K. V.</creatorcontrib><creatorcontrib>Zotov, Yu. L.</creatorcontrib><title>Hydrogenation of 1,5,9-Cyclododecatriene in a Three-Phase System in the Presence of Nickel Nanoparticles Supported on NаX Zeolite</title><title>Russian journal of applied chemistry</title><addtitle>Russ J Appl Chem</addtitle><description>Hydrogenation of 1,5,9-cyclododecatriene in the presence of nanostructured nickel catalysts in a flow-through reactor at atmospheric hydrogen pressure was studied. NaX zeolite was used as a support. Nickel nanoparticles on the support surface were prepared by chemical reduction of the precursor (NiCl
2
) with NaBH
4
and NH
2
NH
2
. The influence exerted on the yield of hydrogenation products by the nominal residence time of the gas phase in the reaction zone and by the process temperature was considered, and the catalyst operation life was analyzed. The catalysts showed high activity and allowed preparation of cyclododecane in ~100% yield at a process temperature of up to 160°С.</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical reduction</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Hydrogenation</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Nanoparticles</subject><subject>Nickel</subject><subject>Vapor phases</subject><subject>Zeolites</subject><issn>1070-4272</issn><issn>1608-3296</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1UM1Kw0AQXkTBWn0AbwteG92fbLJ7lKJWKFVoheIlbDaTNjXdjbvpIVefyEfxkUyp4EFkDjPM9wcfQpeUXFPK45s5JSmJWcoYJf0kyyM0oAmREWcqOe7vHo72-Ck6C2FDCFFJIgfoY9IV3q3A6rZyFrsS05EYqWjcmdoVrgCjW1-BBVxZrPFi7QGi57UOgOddaGG7_7drwM8eAlgDe4tZZd6gxjNtXaN9W5kaAp7vmsb5Fgrc58y-Ppf4FVxdtXCOTkpdB7j42UP0cn-3GE-i6dPD4_h2GhnG6TIqY65ylWvGuBRE0zyNaUk4VcJIqXMRFybVgoocYqEElznhBYslQMqFMVrwIbo6-Dbeve8gtNnG7bztIzMWK6VkogjpWfTAMt6F4KHMGl9tte8ySrJ91dmfqnsNO2hCz7Ur8L_O_4u-AQxzgHg</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Nebykov, D. N.</creator><creator>Popov, Yu. V.</creator><creator>Mokhov, V. M.</creator><creator>Shcherbakova, K. V.</creator><creator>Zotov, Yu. L.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>Hydrogenation of 1,5,9-Cyclododecatriene in a Three-Phase System in the Presence of Nickel Nanoparticles Supported on NаX Zeolite</title><author>Nebykov, D. N. ; Popov, Yu. V. ; Mokhov, V. M. ; Shcherbakova, K. V. ; Zotov, Yu. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c231X-f439b9ba223850a1b741f03195c88ab54dc7a515be459538b03d248ee735cca53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical reduction</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Hydrogenation</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Nanoparticles</topic><topic>Nickel</topic><topic>Vapor phases</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nebykov, D. N.</creatorcontrib><creatorcontrib>Popov, Yu. V.</creatorcontrib><creatorcontrib>Mokhov, V. M.</creatorcontrib><creatorcontrib>Shcherbakova, K. V.</creatorcontrib><creatorcontrib>Zotov, Yu. L.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of applied chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nebykov, D. N.</au><au>Popov, Yu. V.</au><au>Mokhov, V. M.</au><au>Shcherbakova, K. V.</au><au>Zotov, Yu. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrogenation of 1,5,9-Cyclododecatriene in a Three-Phase System in the Presence of Nickel Nanoparticles Supported on NаX Zeolite</atitle><jtitle>Russian journal of applied chemistry</jtitle><stitle>Russ J Appl Chem</stitle><date>2021</date><risdate>2021</risdate><volume>94</volume><issue>1</issue><spage>110</spage><epage>115</epage><pages>110-115</pages><issn>1070-4272</issn><eissn>1608-3296</eissn><abstract>Hydrogenation of 1,5,9-cyclododecatriene in the presence of nanostructured nickel catalysts in a flow-through reactor at atmospheric hydrogen pressure was studied. NaX zeolite was used as a support. Nickel nanoparticles on the support surface were prepared by chemical reduction of the precursor (NiCl
2
) with NaBH
4
and NH
2
NH
2
. The influence exerted on the yield of hydrogenation products by the nominal residence time of the gas phase in the reaction zone and by the process temperature was considered, and the catalyst operation life was analyzed. The catalysts showed high activity and allowed preparation of cyclododecane in ~100% yield at a process temperature of up to 160°С.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S107042722101016X</doi><tpages>6</tpages></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Catalysis Catalysts Chemical reduction Chemistry Chemistry and Materials Science Chemistry/Food Science Hydrogenation Industrial Chemistry/Chemical Engineering Nanoparticles Nickel Vapor phases Zeolites |
| title | Hydrogenation of 1,5,9-Cyclododecatriene in a Three-Phase System in the Presence of Nickel Nanoparticles Supported on NаX Zeolite |
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