Effect of the Composition of Mixed Aqueous Organic Solvents on the Stability of Copper(II) Complexes with Anions of Succinic and Maleic Acids
The effect aqueous ethanol solvents have on the stability of coordination compounds between Cu(II) ions and anions of succinic (Y 2– ) and maleic (L 2– ) acids is studied via UV–Vis spectrophotometry. Logarithms of stability constants for succinate and maleate complexes are compared to ones obtained...
Gespeichert in:
| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2021-02, Vol.95 (2), p.292-297 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 297 |
|---|---|
| container_issue | 2 |
| container_start_page | 292 |
| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 95 |
| creator | Tukumova, N. V. Belova, N. V. Usacheva, T. R. Thuan, Tran Thi Dieu |
| description | The effect aqueous ethanol solvents have on the stability of coordination compounds between Cu(II) ions and anions of succinic (Y
2–
) and maleic (L
2–
) acids is studied via UV–Vis spectrophotometry. Logarithms of stability constants for succinate and maleate complexes are compared to ones obtained via potentiometric titration. Quantum chemistry calculations are performed for the structures of maleic and succinic acids and complexes of them with Cu(II) ions to explain the difference between the stabilities of succinate and maleate complexes. |
| doi_str_mv | 10.1134/S0036024421020278 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2499404845</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2499404845</sourcerecordid><originalsourceid>FETCH-LOGICAL-c268t-61eb1fb0c92d4d8260259e1a41ce7d59ed5d53a3ec4bd11fed00db601d53c5b13</originalsourceid><addsrcrecordid>eNp1kLFOwzAQhi0EEqXwAGyWWGAI-BwnTceqKlCpqENBYosS-9K6SuNgu9A-BO-MQ5EYEJNPd9_3W3eEXAK7BYjF3YKxOGVcCA6MMz7IjkgPkhiiLI1fj0mvG0fd_JScObdmTAgBokc-J1WF0lNTUb9COjab1jjttWm61pPeoaKjty2araNzuywaLenC1O_YeEcD1EkLX5S61n7fKWPTtmivp9Ob77Aad-joh_YrOmpCquuYxVZK3SUVjaJPRY2hHEmt3Dk5qYra4cXP2ycv95Pn8WM0mz9Mx6NZJHma-SgFLKEqmRxyJVTGw-LJEKEQIHGgQqkSlcRFjFKUCqBCxZgqUwahK5MS4j65OuS21oTlnM_XZmub8GXOxXAomMhEEig4UNIa5yxWeWv1prD7HFjeXT3_c_Xg8IPjAtss0f4m_y99AZkFhHM</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2499404845</pqid></control><display><type>article</type><title>Effect of the Composition of Mixed Aqueous Organic Solvents on the Stability of Copper(II) Complexes with Anions of Succinic and Maleic Acids</title><source>SpringerLink Journals - AutoHoldings</source><creator>Tukumova, N. V. ; Belova, N. V. ; Usacheva, T. R. ; Thuan, Tran Thi Dieu</creator><creatorcontrib>Tukumova, N. V. ; Belova, N. V. ; Usacheva, T. R. ; Thuan, Tran Thi Dieu</creatorcontrib><description>The effect aqueous ethanol solvents have on the stability of coordination compounds between Cu(II) ions and anions of succinic (Y
2–
) and maleic (L
2–
) acids is studied via UV–Vis spectrophotometry. Logarithms of stability constants for succinate and maleate complexes are compared to ones obtained via potentiometric titration. Quantum chemistry calculations are performed for the structures of maleic and succinic acids and complexes of them with Cu(II) ions to explain the difference between the stabilities of succinate and maleate complexes.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024421020278</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anions ; Chemistry ; Chemistry and Materials Science ; Composition effects ; Coordination compounds ; Copper ; Copper compounds ; Ethanol ; Logarithms ; Physical Chemistry ; Physical Chemistry of Solutions ; Quantum chemistry ; Solvents ; Spectrophotometry ; Stability ; Stability constants ; Titration</subject><ispartof>Russian Journal of Physical Chemistry A, 2021-02, Vol.95 (2), p.292-297</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 0036-0244, Russian Journal of Physical Chemistry A, 2021, Vol. 95, No. 2, pp. 292–297. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Zhurnal Fizicheskoi Khimii, 2021, Vol. 95, No. 2, pp. 220–225.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-61eb1fb0c92d4d8260259e1a41ce7d59ed5d53a3ec4bd11fed00db601d53c5b13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036024421020278$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036024421020278$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Tukumova, N. V.</creatorcontrib><creatorcontrib>Belova, N. V.</creatorcontrib><creatorcontrib>Usacheva, T. R.</creatorcontrib><creatorcontrib>Thuan, Tran Thi Dieu</creatorcontrib><title>Effect of the Composition of Mixed Aqueous Organic Solvents on the Stability of Copper(II) Complexes with Anions of Succinic and Maleic Acids</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>The effect aqueous ethanol solvents have on the stability of coordination compounds between Cu(II) ions and anions of succinic (Y
2–
) and maleic (L
2–
) acids is studied via UV–Vis spectrophotometry. Logarithms of stability constants for succinate and maleate complexes are compared to ones obtained via potentiometric titration. Quantum chemistry calculations are performed for the structures of maleic and succinic acids and complexes of them with Cu(II) ions to explain the difference between the stabilities of succinate and maleate complexes.</description><subject>Anions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composition effects</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Ethanol</subject><subject>Logarithms</subject><subject>Physical Chemistry</subject><subject>Physical Chemistry of Solutions</subject><subject>Quantum chemistry</subject><subject>Solvents</subject><subject>Spectrophotometry</subject><subject>Stability</subject><subject>Stability constants</subject><subject>Titration</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kLFOwzAQhi0EEqXwAGyWWGAI-BwnTceqKlCpqENBYosS-9K6SuNgu9A-BO-MQ5EYEJNPd9_3W3eEXAK7BYjF3YKxOGVcCA6MMz7IjkgPkhiiLI1fj0mvG0fd_JScObdmTAgBokc-J1WF0lNTUb9COjab1jjttWm61pPeoaKjty2araNzuywaLenC1O_YeEcD1EkLX5S61n7fKWPTtmivp9Ob77Aad-joh_YrOmpCquuYxVZK3SUVjaJPRY2hHEmt3Dk5qYra4cXP2ycv95Pn8WM0mz9Mx6NZJHma-SgFLKEqmRxyJVTGw-LJEKEQIHGgQqkSlcRFjFKUCqBCxZgqUwahK5MS4j65OuS21oTlnM_XZmub8GXOxXAomMhEEig4UNIa5yxWeWv1prD7HFjeXT3_c_Xg8IPjAtss0f4m_y99AZkFhHM</recordid><startdate>20210201</startdate><enddate>20210201</enddate><creator>Tukumova, N. V.</creator><creator>Belova, N. V.</creator><creator>Usacheva, T. R.</creator><creator>Thuan, Tran Thi Dieu</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210201</creationdate><title>Effect of the Composition of Mixed Aqueous Organic Solvents on the Stability of Copper(II) Complexes with Anions of Succinic and Maleic Acids</title><author>Tukumova, N. V. ; Belova, N. V. ; Usacheva, T. R. ; Thuan, Tran Thi Dieu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-61eb1fb0c92d4d8260259e1a41ce7d59ed5d53a3ec4bd11fed00db601d53c5b13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Anions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composition effects</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Ethanol</topic><topic>Logarithms</topic><topic>Physical Chemistry</topic><topic>Physical Chemistry of Solutions</topic><topic>Quantum chemistry</topic><topic>Solvents</topic><topic>Spectrophotometry</topic><topic>Stability</topic><topic>Stability constants</topic><topic>Titration</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tukumova, N. V.</creatorcontrib><creatorcontrib>Belova, N. V.</creatorcontrib><creatorcontrib>Usacheva, T. R.</creatorcontrib><creatorcontrib>Thuan, Tran Thi Dieu</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tukumova, N. V.</au><au>Belova, N. V.</au><au>Usacheva, T. R.</au><au>Thuan, Tran Thi Dieu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of the Composition of Mixed Aqueous Organic Solvents on the Stability of Copper(II) Complexes with Anions of Succinic and Maleic Acids</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2021-02-01</date><risdate>2021</risdate><volume>95</volume><issue>2</issue><spage>292</spage><epage>297</epage><pages>292-297</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>The effect aqueous ethanol solvents have on the stability of coordination compounds between Cu(II) ions and anions of succinic (Y
2–
) and maleic (L
2–
) acids is studied via UV–Vis spectrophotometry. Logarithms of stability constants for succinate and maleate complexes are compared to ones obtained via potentiometric titration. Quantum chemistry calculations are performed for the structures of maleic and succinic acids and complexes of them with Cu(II) ions to explain the difference between the stabilities of succinate and maleate complexes.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036024421020278</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0244 |
| ispartof | Russian Journal of Physical Chemistry A, 2021-02, Vol.95 (2), p.292-297 |
| issn | 0036-0244 1531-863X |
| language | eng |
| recordid | cdi_proquest_journals_2499404845 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Anions Chemistry Chemistry and Materials Science Composition effects Coordination compounds Copper Copper compounds Ethanol Logarithms Physical Chemistry Physical Chemistry of Solutions Quantum chemistry Solvents Spectrophotometry Stability Stability constants Titration |
| title | Effect of the Composition of Mixed Aqueous Organic Solvents on the Stability of Copper(II) Complexes with Anions of Succinic and Maleic Acids |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-18T05%3A02%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Effect%20of%20the%20Composition%20of%20Mixed%20Aqueous%20Organic%20Solvents%20on%20the%20Stability%20of%20Copper(II)%20Complexes%20with%20Anions%20of%20Succinic%20and%20Maleic%20Acids&rft.jtitle=Russian%20Journal%20of%20Physical%20Chemistry%20A&rft.au=Tukumova,%20N.%20V.&rft.date=2021-02-01&rft.volume=95&rft.issue=2&rft.spage=292&rft.epage=297&rft.pages=292-297&rft.issn=0036-0244&rft.eissn=1531-863X&rft_id=info:doi/10.1134/S0036024421020278&rft_dat=%3Cproquest_cross%3E2499404845%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2499404845&rft_id=info:pmid/&rfr_iscdi=true |