Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers
In this work the thermochemistry of solution, solvation and hydrogen bond formation of chloroform in linear and cyclic ethers was studied. The infinite dilution solution enthalpies of chloroform in diethyl ether, diglyme, 1,4-dioxane, tetrahydrofuran, 12-crown-4 and 15-crown-5 were measured at 298.1...
Gespeichert in:
| Veröffentlicht in: | Journal of solution chemistry 2021-02, Vol.50 (2), p.290-298 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 298 |
|---|---|
| container_issue | 2 |
| container_start_page | 290 |
| container_title | Journal of solution chemistry |
| container_volume | 50 |
| creator | Rakipov, Ilnaz T. Semenov, Konstantin N. Petrov, Artem A. Akhmadiyarov, Aydar A. Khachatrian, Artashes A. Fakhurtdinova, Aliya R. Solomonov, Boris N. |
| description | In this work the thermochemistry of solution, solvation and hydrogen bond formation of chloroform in linear and cyclic ethers was studied. The infinite dilution solution enthalpies of chloroform in diethyl ether, diglyme, 1,4-dioxane, tetrahydrofuran, 12-crown-4 and 15-crown-5 were measured at 298.15 K. The solvation and hydrogen bonding enthalpies of chloroform in the ethers were calculated. It was found that the hydrogen bonding enthalpies of chloroform in the ethers are significantly higher for linear than for cyclic ethers. The hydrogen bonding of ethers with chloroform was discussed in cases when ethers act as a solute or solvent. |
| doi_str_mv | 10.1007/s10953-021-01059-6 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2496299089</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2496299089</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-89c512c4330ecf40959677c90e6f3fd7c9b7a176f386a166ad478f11092d92a3</originalsourceid><addsrcrecordid>eNp9kMFPwyAYxYnRxDn9BzyReBUF2kI5ajOdSRMP7k6QwtalhQmdSf976WrizRPvC7_3-HgA3BL8QDDmj5FgUWQIU4IwwYVA7AwsSMEpKgXl52CB0z0SvKSX4CrGPU5zKfIFMJudCb3XO9O3cQgj9BZ--O44tN7dT-pbTRIq18D12AS_NQ4-e9e0bjux1a7zwVsfetg6WLfOqHCCq1F3rYarIeXHa3BhVRfNze-5BJuX1aZao_r99a16qpHOiBjSrrogVOdZho22eVpZMM61wIbZzDZJfXJFeBpKpghjqsl5aUn6O20EVdkS3M2xh-C_jiYOcu-PwaUXJc0Fo0LgUiSKzpQOPsZgrDyEtldhlATLqU05tylTm_LUpmTJlM2mmGC3NeEv-h_XD2oFd5w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2496299089</pqid></control><display><type>article</type><title>Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers</title><source>SpringerLink Journals - AutoHoldings</source><creator>Rakipov, Ilnaz T. ; Semenov, Konstantin N. ; Petrov, Artem A. ; Akhmadiyarov, Aydar A. ; Khachatrian, Artashes A. ; Fakhurtdinova, Aliya R. ; Solomonov, Boris N.</creator><creatorcontrib>Rakipov, Ilnaz T. ; Semenov, Konstantin N. ; Petrov, Artem A. ; Akhmadiyarov, Aydar A. ; Khachatrian, Artashes A. ; Fakhurtdinova, Aliya R. ; Solomonov, Boris N.</creatorcontrib><description>In this work the thermochemistry of solution, solvation and hydrogen bond formation of chloroform in linear and cyclic ethers was studied. The infinite dilution solution enthalpies of chloroform in diethyl ether, diglyme, 1,4-dioxane, tetrahydrofuran, 12-crown-4 and 15-crown-5 were measured at 298.15 K. The solvation and hydrogen bonding enthalpies of chloroform in the ethers were calculated. It was found that the hydrogen bonding enthalpies of chloroform in the ethers are significantly higher for linear than for cyclic ethers. The hydrogen bonding of ethers with chloroform was discussed in cases when ethers act as a solute or solvent.</description><identifier>ISSN: 0095-9782</identifier><identifier>EISSN: 1572-8927</identifier><identifier>DOI: 10.1007/s10953-021-01059-6</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Chemical bonds ; Chemistry ; Chemistry and Materials Science ; Chloroform ; Condensed Matter Physics ; Diethyl ether ; Dilution ; Enthalpy ; Ethers ; Geochemistry ; Hydrogen ; Hydrogen bonding ; Hydrogen bonds ; Industrial Chemistry/Chemical Engineering ; Inorganic Chemistry ; Oceanography ; Physical Chemistry ; Solvation ; Tetrahydrofuran ; Thermochemistry</subject><ispartof>Journal of solution chemistry, 2021-02, Vol.50 (2), p.290-298</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-89c512c4330ecf40959677c90e6f3fd7c9b7a176f386a166ad478f11092d92a3</citedby><cites>FETCH-LOGICAL-c319t-89c512c4330ecf40959677c90e6f3fd7c9b7a176f386a166ad478f11092d92a3</cites><orcidid>0000-0001-5836-9562</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10953-021-01059-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10953-021-01059-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Rakipov, Ilnaz T.</creatorcontrib><creatorcontrib>Semenov, Konstantin N.</creatorcontrib><creatorcontrib>Petrov, Artem A.</creatorcontrib><creatorcontrib>Akhmadiyarov, Aydar A.</creatorcontrib><creatorcontrib>Khachatrian, Artashes A.</creatorcontrib><creatorcontrib>Fakhurtdinova, Aliya R.</creatorcontrib><creatorcontrib>Solomonov, Boris N.</creatorcontrib><title>Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers</title><title>Journal of solution chemistry</title><addtitle>J Solution Chem</addtitle><description>In this work the thermochemistry of solution, solvation and hydrogen bond formation of chloroform in linear and cyclic ethers was studied. The infinite dilution solution enthalpies of chloroform in diethyl ether, diglyme, 1,4-dioxane, tetrahydrofuran, 12-crown-4 and 15-crown-5 were measured at 298.15 K. The solvation and hydrogen bonding enthalpies of chloroform in the ethers were calculated. It was found that the hydrogen bonding enthalpies of chloroform in the ethers are significantly higher for linear than for cyclic ethers. The hydrogen bonding of ethers with chloroform was discussed in cases when ethers act as a solute or solvent.</description><subject>Chemical bonds</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chloroform</subject><subject>Condensed Matter Physics</subject><subject>Diethyl ether</subject><subject>Dilution</subject><subject>Enthalpy</subject><subject>Ethers</subject><subject>Geochemistry</subject><subject>Hydrogen</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Oceanography</subject><subject>Physical Chemistry</subject><subject>Solvation</subject><subject>Tetrahydrofuran</subject><subject>Thermochemistry</subject><issn>0095-9782</issn><issn>1572-8927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kMFPwyAYxYnRxDn9BzyReBUF2kI5ajOdSRMP7k6QwtalhQmdSf976WrizRPvC7_3-HgA3BL8QDDmj5FgUWQIU4IwwYVA7AwsSMEpKgXl52CB0z0SvKSX4CrGPU5zKfIFMJudCb3XO9O3cQgj9BZ--O44tN7dT-pbTRIq18D12AS_NQ4-e9e0bjux1a7zwVsfetg6WLfOqHCCq1F3rYarIeXHa3BhVRfNze-5BJuX1aZao_r99a16qpHOiBjSrrogVOdZho22eVpZMM61wIbZzDZJfXJFeBpKpghjqsl5aUn6O20EVdkS3M2xh-C_jiYOcu-PwaUXJc0Fo0LgUiSKzpQOPsZgrDyEtldhlATLqU05tylTm_LUpmTJlM2mmGC3NeEv-h_XD2oFd5w</recordid><startdate>20210201</startdate><enddate>20210201</enddate><creator>Rakipov, Ilnaz T.</creator><creator>Semenov, Konstantin N.</creator><creator>Petrov, Artem A.</creator><creator>Akhmadiyarov, Aydar A.</creator><creator>Khachatrian, Artashes A.</creator><creator>Fakhurtdinova, Aliya R.</creator><creator>Solomonov, Boris N.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-5836-9562</orcidid></search><sort><creationdate>20210201</creationdate><title>Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers</title><author>Rakipov, Ilnaz T. ; Semenov, Konstantin N. ; Petrov, Artem A. ; Akhmadiyarov, Aydar A. ; Khachatrian, Artashes A. ; Fakhurtdinova, Aliya R. ; Solomonov, Boris N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-89c512c4330ecf40959677c90e6f3fd7c9b7a176f386a166ad478f11092d92a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemical bonds</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chloroform</topic><topic>Condensed Matter Physics</topic><topic>Diethyl ether</topic><topic>Dilution</topic><topic>Enthalpy</topic><topic>Ethers</topic><topic>Geochemistry</topic><topic>Hydrogen</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Inorganic Chemistry</topic><topic>Oceanography</topic><topic>Physical Chemistry</topic><topic>Solvation</topic><topic>Tetrahydrofuran</topic><topic>Thermochemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rakipov, Ilnaz T.</creatorcontrib><creatorcontrib>Semenov, Konstantin N.</creatorcontrib><creatorcontrib>Petrov, Artem A.</creatorcontrib><creatorcontrib>Akhmadiyarov, Aydar A.</creatorcontrib><creatorcontrib>Khachatrian, Artashes A.</creatorcontrib><creatorcontrib>Fakhurtdinova, Aliya R.</creatorcontrib><creatorcontrib>Solomonov, Boris N.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solution chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rakipov, Ilnaz T.</au><au>Semenov, Konstantin N.</au><au>Petrov, Artem A.</au><au>Akhmadiyarov, Aydar A.</au><au>Khachatrian, Artashes A.</au><au>Fakhurtdinova, Aliya R.</au><au>Solomonov, Boris N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers</atitle><jtitle>Journal of solution chemistry</jtitle><stitle>J Solution Chem</stitle><date>2021-02-01</date><risdate>2021</risdate><volume>50</volume><issue>2</issue><spage>290</spage><epage>298</epage><pages>290-298</pages><issn>0095-9782</issn><eissn>1572-8927</eissn><abstract>In this work the thermochemistry of solution, solvation and hydrogen bond formation of chloroform in linear and cyclic ethers was studied. The infinite dilution solution enthalpies of chloroform in diethyl ether, diglyme, 1,4-dioxane, tetrahydrofuran, 12-crown-4 and 15-crown-5 were measured at 298.15 K. The solvation and hydrogen bonding enthalpies of chloroform in the ethers were calculated. It was found that the hydrogen bonding enthalpies of chloroform in the ethers are significantly higher for linear than for cyclic ethers. The hydrogen bonding of ethers with chloroform was discussed in cases when ethers act as a solute or solvent.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10953-021-01059-6</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-5836-9562</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0095-9782 |
| ispartof | Journal of solution chemistry, 2021-02, Vol.50 (2), p.290-298 |
| issn | 0095-9782 1572-8927 |
| language | eng |
| recordid | cdi_proquest_journals_2496299089 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemical bonds Chemistry Chemistry and Materials Science Chloroform Condensed Matter Physics Diethyl ether Dilution Enthalpy Ethers Geochemistry Hydrogen Hydrogen bonding Hydrogen bonds Industrial Chemistry/Chemical Engineering Inorganic Chemistry Oceanography Physical Chemistry Solvation Tetrahydrofuran Thermochemistry |
| title | Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T17%3A24%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Thermochemistry%20of%20Solution,%20Solvation%20and%20Hydrogen%20Bonding%20of%20Chloroform%20in%20Linear%20and%20Cyclic%20Ethers&rft.jtitle=Journal%20of%20solution%20chemistry&rft.au=Rakipov,%20Ilnaz%20T.&rft.date=2021-02-01&rft.volume=50&rft.issue=2&rft.spage=290&rft.epage=298&rft.pages=290-298&rft.issn=0095-9782&rft.eissn=1572-8927&rft_id=info:doi/10.1007/s10953-021-01059-6&rft_dat=%3Cproquest_cross%3E2496299089%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2496299089&rft_id=info:pmid/&rfr_iscdi=true |