Oxidative Addition of C–H Acids to bis(1,5-cyclooctadiene) Ni(0)Ni(COD)2 Complex
The paramagnetic Ni(I) complexes and the products of their reactions with ethylene in catalytic systems based on the Ni(COD) 2 , Ni(PPh 3 ) 4 complexes and C–H acids (β-diketones, 1,3-cyclopentadiene) have been identified. It is assumed that the Ni(COD) 2 and Ni(PPh 3 ) 4 reactions with these C–H ac...
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| Veröffentlicht in: | Theoretical and experimental chemistry 2021, Vol.56 (6), p.412-416 |
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| creator | Ismailov, E. H. Abbasov, Ya. A. Osmanova, S. N. Zeynalova, T. G. |
| description | The paramagnetic Ni(I) complexes and the products of their reactions with ethylene in catalytic systems based on the Ni(COD)
2
, Ni(PPh
3
)
4
complexes and C–H acids (β-diketones, 1,3-cyclopentadiene) have been identified. It is assumed that the Ni(COD)
2
and Ni(PPh
3
)
4
reactions with these C–H acids occur with the oxidation of Ni(0) to Ni(II) as a result of the oxidative addition of β-diketone (1,3-cyclopentadiene) to Ni(COD)
2
or Ni(PPh
3
)
4
in the first stage and the disproportionation of Ni(II) + Ni(0) ↔ 2Ni(I) with the formation of paramagnetic complexes of monovalent nickel at the second stage. |
| doi_str_mv | 10.1007/s11237-021-09670-w |
| format | Article |
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2
, Ni(PPh
3
)
4
complexes and C–H acids (β-diketones, 1,3-cyclopentadiene) have been identified. It is assumed that the Ni(COD)
2
and Ni(PPh
3
)
4
reactions with these C–H acids occur with the oxidation of Ni(0) to Ni(II) as a result of the oxidative addition of β-diketone (1,3-cyclopentadiene) to Ni(COD)
2
or Ni(PPh
3
)
4
in the first stage and the disproportionation of Ni(II) + Ni(0) ↔ 2Ni(I) with the formation of paramagnetic complexes of monovalent nickel at the second stage.</description><identifier>ISSN: 0040-5760</identifier><identifier>EISSN: 1573-935X</identifier><identifier>DOI: 10.1007/s11237-021-09670-w</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Cyclopentadiene ; Diketones ; Disproportionation ; Nickel ; Oxidation</subject><ispartof>Theoretical and experimental chemistry, 2021, Vol.56 (6), p.412-416</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c185w-a68674024261a8eedaf83c0e268b7ffc0d71e2882f89bc00167edba5d04e64d13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11237-021-09670-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11237-021-09670-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Ismailov, E. H.</creatorcontrib><creatorcontrib>Abbasov, Ya. A.</creatorcontrib><creatorcontrib>Osmanova, S. N.</creatorcontrib><creatorcontrib>Zeynalova, T. G.</creatorcontrib><title>Oxidative Addition of C–H Acids to bis(1,5-cyclooctadiene) Ni(0)Ni(COD)2 Complex</title><title>Theoretical and experimental chemistry</title><addtitle>Theor Exp Chem</addtitle><description>The paramagnetic Ni(I) complexes and the products of their reactions with ethylene in catalytic systems based on the Ni(COD)
2
, Ni(PPh
3
)
4
complexes and C–H acids (β-diketones, 1,3-cyclopentadiene) have been identified. It is assumed that the Ni(COD)
2
and Ni(PPh
3
)
4
reactions with these C–H acids occur with the oxidation of Ni(0) to Ni(II) as a result of the oxidative addition of β-diketone (1,3-cyclopentadiene) to Ni(COD)
2
or Ni(PPh
3
)
4
in the first stage and the disproportionation of Ni(II) + Ni(0) ↔ 2Ni(I) with the formation of paramagnetic complexes of monovalent nickel at the second stage.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Cyclopentadiene</subject><subject>Diketones</subject><subject>Disproportionation</subject><subject>Nickel</subject><subject>Oxidation</subject><issn>0040-5760</issn><issn>1573-935X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KAzEURoMoWKsv4CrgpgWjN5mZJLMs40-FYkEU3IWZJCMpbVMnU9vufAff0CcxOoI7N_duvvPdy0HolMIFBRCXgVKWCAKMEsi5ALLZQz2aiYTkSfa8j3oAKZBMcDhERyHMACImoYcepltnyta9WTwyxrXOL7GvcfH5_jHGI-1MwK3HlQsDep4RvdNz73VbGmeXdojv3QCGcRTTqyHDhV-s5nZ7jA7qch7sye_uo6eb68diTCbT27tiNCGaymxDSi65SIGljNNSWmvKWiYaLOOyEnWtwQhqmZSslnml48NcWFOVmYHU8tTQpI_Out5V41_XNrRq5tfNMp5ULM2zNM1FwmOKdSnd-BAaW6tV4xZls1MU1Lc71blT0Z36cac2EUo6KMTw8sU2f9X_UF8XcHAx</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Ismailov, E. H.</creator><creator>Abbasov, Ya. A.</creator><creator>Osmanova, S. N.</creator><creator>Zeynalova, T. G.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>Oxidative Addition of C–H Acids to bis(1,5-cyclooctadiene) Ni(0)Ni(COD)2 Complex</title><author>Ismailov, E. H. ; Abbasov, Ya. A. ; Osmanova, S. N. ; Zeynalova, T. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c185w-a68674024261a8eedaf83c0e268b7ffc0d71e2882f89bc00167edba5d04e64d13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Cyclopentadiene</topic><topic>Diketones</topic><topic>Disproportionation</topic><topic>Nickel</topic><topic>Oxidation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ismailov, E. H.</creatorcontrib><creatorcontrib>Abbasov, Ya. A.</creatorcontrib><creatorcontrib>Osmanova, S. N.</creatorcontrib><creatorcontrib>Zeynalova, T. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Theoretical and experimental chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ismailov, E. H.</au><au>Abbasov, Ya. A.</au><au>Osmanova, S. N.</au><au>Zeynalova, T. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oxidative Addition of C–H Acids to bis(1,5-cyclooctadiene) Ni(0)Ni(COD)2 Complex</atitle><jtitle>Theoretical and experimental chemistry</jtitle><stitle>Theor Exp Chem</stitle><date>2021</date><risdate>2021</risdate><volume>56</volume><issue>6</issue><spage>412</spage><epage>416</epage><pages>412-416</pages><issn>0040-5760</issn><eissn>1573-935X</eissn><abstract>The paramagnetic Ni(I) complexes and the products of their reactions with ethylene in catalytic systems based on the Ni(COD)
2
, Ni(PPh
3
)
4
complexes and C–H acids (β-diketones, 1,3-cyclopentadiene) have been identified. It is assumed that the Ni(COD)
2
and Ni(PPh
3
)
4
reactions with these C–H acids occur with the oxidation of Ni(0) to Ni(II) as a result of the oxidative addition of β-diketone (1,3-cyclopentadiene) to Ni(COD)
2
or Ni(PPh
3
)
4
in the first stage and the disproportionation of Ni(II) + Ni(0) ↔ 2Ni(I) with the formation of paramagnetic complexes of monovalent nickel at the second stage.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11237-021-09670-w</doi><tpages>5</tpages></addata></record> |
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| ispartof | Theoretical and experimental chemistry, 2021, Vol.56 (6), p.412-416 |
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| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Cyclopentadiene Diketones Disproportionation Nickel Oxidation |
| title | Oxidative Addition of C–H Acids to bis(1,5-cyclooctadiene) Ni(0)Ni(COD)2 Complex |
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