Structure and tribocorrosion behavior of Ti/TiN multilayer coatings in simulated body fluid by arc ion plating
The TiN coating and Ti/TiN multilayer coatings were successfully fabricated on Ti6Al4V alloy by multi-arc ion plating. The Ti/TiN multilayer coatings with a total thickness of 4.6 μm and the TiN coating were prepared with a thickness of 5.6 μm. The XRD results indicate that the TiN phase of Ti/TiN m...
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| Veröffentlicht in: | Surface & coatings technology 2020-12, Vol.403, p.126399, Article 126399 |
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| creator | Zhao, Chunlei Zhu, Yebiao Yuan, Zhiwei Li, Jinlong |
| description | The TiN coating and Ti/TiN multilayer coatings were successfully fabricated on Ti6Al4V alloy by multi-arc ion plating. The Ti/TiN multilayer coatings with a total thickness of 4.6 μm and the TiN coating were prepared with a thickness of 5.6 μm. The XRD results indicate that the TiN phase of Ti/TiN multilayer coatings has a face-centered cubic crystal with the strong preferred orientation of (111) while the TiN coating has the face-centered cubic crystal structure with a preferred orientation of (200). For TiN coating, the hardness is (27.5 ± 1.9) GPa, the load-bearing capacity is (19.0 ± 3.6) N. For Ti/TiN multilayer coating, the hardness is (26.8 ± 1.7) GPa and the load-bearing capacity is (60.4 ± 4.0) N. The Ti/TiN multilayer coatings have excellent tribocorrosion resistance and lower coefficient of friction in simulated body fluid at 37 °C, compared with Ti6Al4V alloy and TiN coating, the tribocorrosion resistance of the multilayer coatings increased by approximately 58 and two times, respectively. The material loss which arises from tribocorrosion is not simply the summation of pure corrosion and pure wear loss, the synergism between corrosion and wear takes a large proportion of the total volume loss.
•TiN coating and Ti/TiN multilayer coatings were deposited on Ti6Al4V alloys by multi-arc ion plating.•Ti/TiN multilayer coatings exhibit excellent mechanical properties.•Ti/TiN multilayer coatings exhibit excellent tribocorrosion resistance in simulated body fluid.•The evolution of the microstructure of the multilayer coatings was studied.•The mechanisms of the multilayer coatings to improve the tribocorrosion resistance were explored. |
| doi_str_mv | 10.1016/j.surfcoat.2020.126399 |
| format | Article |
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•TiN coating and Ti/TiN multilayer coatings were deposited on Ti6Al4V alloys by multi-arc ion plating.•Ti/TiN multilayer coatings exhibit excellent mechanical properties.•Ti/TiN multilayer coatings exhibit excellent tribocorrosion resistance in simulated body fluid.•The evolution of the microstructure of the multilayer coatings was studied.•The mechanisms of the multilayer coatings to improve the tribocorrosion resistance were explored.</description><identifier>ISSN: 0257-8972</identifier><identifier>EISSN: 1879-3347</identifier><identifier>DOI: 10.1016/j.surfcoat.2020.126399</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Arc ion plating ; Bearing capacity ; Biomedical materials ; Body fluids ; Coatings ; Coefficient of friction ; Corrosion ; Corrosive wear ; Crystal structure ; Hardness ; In vitro methods and tests ; Ion plating ; Multilayers ; Preferred orientation ; Thickness ; Ti/TiN multilayer coating ; Ti6Al4V ; Tin ; TiN coating ; Titanium base alloys ; Tribocorrosion</subject><ispartof>Surface & coatings technology, 2020-12, Vol.403, p.126399, Article 126399</ispartof><rights>2020 Elsevier B.V.</rights><rights>Copyright Elsevier BV Dec 15, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c340t-5b661ccba53078e8a40687f8c655b0414b3f044954cb2c27f26acfc38c18a4553</citedby><cites>FETCH-LOGICAL-c340t-5b661ccba53078e8a40687f8c655b0414b3f044954cb2c27f26acfc38c18a4553</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0257897220310689$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Zhao, Chunlei</creatorcontrib><creatorcontrib>Zhu, Yebiao</creatorcontrib><creatorcontrib>Yuan, Zhiwei</creatorcontrib><creatorcontrib>Li, Jinlong</creatorcontrib><title>Structure and tribocorrosion behavior of Ti/TiN multilayer coatings in simulated body fluid by arc ion plating</title><title>Surface & coatings technology</title><description>The TiN coating and Ti/TiN multilayer coatings were successfully fabricated on Ti6Al4V alloy by multi-arc ion plating. The Ti/TiN multilayer coatings with a total thickness of 4.6 μm and the TiN coating were prepared with a thickness of 5.6 μm. The XRD results indicate that the TiN phase of Ti/TiN multilayer coatings has a face-centered cubic crystal with the strong preferred orientation of (111) while the TiN coating has the face-centered cubic crystal structure with a preferred orientation of (200). For TiN coating, the hardness is (27.5 ± 1.9) GPa, the load-bearing capacity is (19.0 ± 3.6) N. For Ti/TiN multilayer coating, the hardness is (26.8 ± 1.7) GPa and the load-bearing capacity is (60.4 ± 4.0) N. The Ti/TiN multilayer coatings have excellent tribocorrosion resistance and lower coefficient of friction in simulated body fluid at 37 °C, compared with Ti6Al4V alloy and TiN coating, the tribocorrosion resistance of the multilayer coatings increased by approximately 58 and two times, respectively. The material loss which arises from tribocorrosion is not simply the summation of pure corrosion and pure wear loss, the synergism between corrosion and wear takes a large proportion of the total volume loss.
•TiN coating and Ti/TiN multilayer coatings were deposited on Ti6Al4V alloys by multi-arc ion plating.•Ti/TiN multilayer coatings exhibit excellent mechanical properties.•Ti/TiN multilayer coatings exhibit excellent tribocorrosion resistance in simulated body fluid.•The evolution of the microstructure of the multilayer coatings was studied.•The mechanisms of the multilayer coatings to improve the tribocorrosion resistance were explored.</description><subject>Arc ion plating</subject><subject>Bearing capacity</subject><subject>Biomedical materials</subject><subject>Body fluids</subject><subject>Coatings</subject><subject>Coefficient of friction</subject><subject>Corrosion</subject><subject>Corrosive wear</subject><subject>Crystal structure</subject><subject>Hardness</subject><subject>In vitro methods and tests</subject><subject>Ion plating</subject><subject>Multilayers</subject><subject>Preferred orientation</subject><subject>Thickness</subject><subject>Ti/TiN multilayer coating</subject><subject>Ti6Al4V</subject><subject>Tin</subject><subject>TiN coating</subject><subject>Titanium base alloys</subject><subject>Tribocorrosion</subject><issn>0257-8972</issn><issn>1879-3347</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFUMtOwzAQtBBIlMIvIEuc09qOYyc3UMVLquBAOVvOxgZXaVxsp1L-noTCmdOuduehGYSuKVlQQsVyu4h9sOB1WjDCxiMTeVWdoBktZZXlOZenaEZYIbOykuwcXcS4JYRQWfEZ6t5S6CH1wWDdNTgFV3vwIfjofIdr86kPzgfsLd645ca94F3fJtfqwQQ8WbruI2LX4ejGh06mwbVvBmzb3o3rgHUAPCnt2x_sJTqzuo3m6nfO0fvD_Wb1lK1fH59Xd-sMck5SVtRCUIBaFzmRpSk1J6KUtgRRFDXhlNe5JZxXBYeaAZOWCQ0W8hLoiC2KfI5ujrr74L96E5Pa-j50o6VivGKSCEYmlDiiYMwbg7FqH9xOh0FRoqZu1Vb9daumbtWx25F4eySaMcPBmaAiONOBaVwwkFTj3X8S32VRhz8</recordid><startdate>20201215</startdate><enddate>20201215</enddate><creator>Zhao, Chunlei</creator><creator>Zhu, Yebiao</creator><creator>Yuan, Zhiwei</creator><creator>Li, Jinlong</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20201215</creationdate><title>Structure and tribocorrosion behavior of Ti/TiN multilayer coatings in simulated body fluid by arc ion plating</title><author>Zhao, Chunlei ; Zhu, Yebiao ; Yuan, Zhiwei ; Li, Jinlong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c340t-5b661ccba53078e8a40687f8c655b0414b3f044954cb2c27f26acfc38c18a4553</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Arc ion plating</topic><topic>Bearing capacity</topic><topic>Biomedical materials</topic><topic>Body fluids</topic><topic>Coatings</topic><topic>Coefficient of friction</topic><topic>Corrosion</topic><topic>Corrosive wear</topic><topic>Crystal structure</topic><topic>Hardness</topic><topic>In vitro methods and tests</topic><topic>Ion plating</topic><topic>Multilayers</topic><topic>Preferred orientation</topic><topic>Thickness</topic><topic>Ti/TiN multilayer coating</topic><topic>Ti6Al4V</topic><topic>Tin</topic><topic>TiN coating</topic><topic>Titanium base alloys</topic><topic>Tribocorrosion</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Chunlei</creatorcontrib><creatorcontrib>Zhu, Yebiao</creatorcontrib><creatorcontrib>Yuan, Zhiwei</creatorcontrib><creatorcontrib>Li, Jinlong</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Surface & coatings technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Chunlei</au><au>Zhu, Yebiao</au><au>Yuan, Zhiwei</au><au>Li, Jinlong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure and tribocorrosion behavior of Ti/TiN multilayer coatings in simulated body fluid by arc ion plating</atitle><jtitle>Surface & coatings technology</jtitle><date>2020-12-15</date><risdate>2020</risdate><volume>403</volume><spage>126399</spage><pages>126399-</pages><artnum>126399</artnum><issn>0257-8972</issn><eissn>1879-3347</eissn><abstract>The TiN coating and Ti/TiN multilayer coatings were successfully fabricated on Ti6Al4V alloy by multi-arc ion plating. The Ti/TiN multilayer coatings with a total thickness of 4.6 μm and the TiN coating were prepared with a thickness of 5.6 μm. The XRD results indicate that the TiN phase of Ti/TiN multilayer coatings has a face-centered cubic crystal with the strong preferred orientation of (111) while the TiN coating has the face-centered cubic crystal structure with a preferred orientation of (200). For TiN coating, the hardness is (27.5 ± 1.9) GPa, the load-bearing capacity is (19.0 ± 3.6) N. For Ti/TiN multilayer coating, the hardness is (26.8 ± 1.7) GPa and the load-bearing capacity is (60.4 ± 4.0) N. The Ti/TiN multilayer coatings have excellent tribocorrosion resistance and lower coefficient of friction in simulated body fluid at 37 °C, compared with Ti6Al4V alloy and TiN coating, the tribocorrosion resistance of the multilayer coatings increased by approximately 58 and two times, respectively. The material loss which arises from tribocorrosion is not simply the summation of pure corrosion and pure wear loss, the synergism between corrosion and wear takes a large proportion of the total volume loss.
•TiN coating and Ti/TiN multilayer coatings were deposited on Ti6Al4V alloys by multi-arc ion plating.•Ti/TiN multilayer coatings exhibit excellent mechanical properties.•Ti/TiN multilayer coatings exhibit excellent tribocorrosion resistance in simulated body fluid.•The evolution of the microstructure of the multilayer coatings was studied.•The mechanisms of the multilayer coatings to improve the tribocorrosion resistance were explored.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.surfcoat.2020.126399</doi></addata></record> |
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| subjects | Arc ion plating Bearing capacity Biomedical materials Body fluids Coatings Coefficient of friction Corrosion Corrosive wear Crystal structure Hardness In vitro methods and tests Ion plating Multilayers Preferred orientation Thickness Ti/TiN multilayer coating Ti6Al4V Tin TiN coating Titanium base alloys Tribocorrosion |
| title | Structure and tribocorrosion behavior of Ti/TiN multilayer coatings in simulated body fluid by arc ion plating |
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