Synthesis of Nitrile Derivatives of the closo-Decaborate and closo-Dodecaborate Anions [BnHn – 1NCR]– (n = 10, 12) by a Microwave Method
Methods for the preparation of nitrile derivatives of boron cluster anions using microwave synthesis have been proposed. The reported approaches have been used to synthesize derivatives based on high-boiling and solid organic nitriles. For the first time, derivatives of the [B 10 H 10 ] 2– anion bas...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2021-02, Vol.66 (2), p.139-145 |
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| container_title | Russian journal of inorganic chemistry |
| container_volume | 66 |
| creator | Nelyubin, A. V. Klyukin, I. N. Zhdanov, A. P. Grigor’ev, M. S. Zhizhin, K. Yu Kuznetsov, N. T. |
| description | Methods for the preparation of nitrile derivatives of boron cluster anions using microwave synthesis have been proposed. The reported approaches have been used to synthesize derivatives based on high-boiling and solid organic nitriles. For the first time, derivatives of the [B
10
H
10
]
2–
anion based on dinitriles have been prepared, and [B
12
H
11
NCCH
3
]
–
and [B
12
H
11
NCC
2
H
5
]
–
derivatives have been isolated in individual form. The prepared compounds have been studied by multinuclear NMR spectroscopy, IR spectroscopy, and elemental analysis. |
| doi_str_mv | 10.1134/S0036023621020133 |
| format | Article |
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10
H
10
]
2–
anion based on dinitriles have been prepared, and [B
12
H
11
NCCH
3
]
–
and [B
12
H
11
NCC
2
H
5
]
–
derivatives have been isolated in individual form. The prepared compounds have been studied by multinuclear NMR spectroscopy, IR spectroscopy, and elemental analysis.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023621020133</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anions ; Boron ; Chemical analysis ; Chemistry ; Chemistry and Materials Science ; Derivatives ; Infrared analysis ; Infrared spectroscopy ; Inorganic Chemistry ; Nitriles ; NMR spectroscopy ; Spectrum analysis ; Synthesis ; Synthesis and Properties of Inorganic Compounds</subject><ispartof>Russian journal of inorganic chemistry, 2021-02, Vol.66 (2), p.139-145</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2021, Vol. 66, No. 2, pp. 139–145. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Zhurnal Neorganicheskoi Khimii, 2021, Vol. 66, No. 2, pp. 134–140.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-4b63887fb553425366eecb34f9277a9906bebe88ee8831951b445c4fe652e0dc3</citedby><cites>FETCH-LOGICAL-c316t-4b63887fb553425366eecb34f9277a9906bebe88ee8831951b445c4fe652e0dc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023621020133$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023621020133$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Nelyubin, A. V.</creatorcontrib><creatorcontrib>Klyukin, I. N.</creatorcontrib><creatorcontrib>Zhdanov, A. P.</creatorcontrib><creatorcontrib>Grigor’ev, M. S.</creatorcontrib><creatorcontrib>Zhizhin, K. Yu</creatorcontrib><creatorcontrib>Kuznetsov, N. T.</creatorcontrib><title>Synthesis of Nitrile Derivatives of the closo-Decaborate and closo-Dodecaborate Anions [BnHn – 1NCR]– (n = 10, 12) by a Microwave Method</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>Methods for the preparation of nitrile derivatives of boron cluster anions using microwave synthesis have been proposed. The reported approaches have been used to synthesize derivatives based on high-boiling and solid organic nitriles. For the first time, derivatives of the [B
10
H
10
]
2–
anion based on dinitriles have been prepared, and [B
12
H
11
NCCH
3
]
–
and [B
12
H
11
NCC
2
H
5
]
–
derivatives have been isolated in individual form. The prepared compounds have been studied by multinuclear NMR spectroscopy, IR spectroscopy, and elemental analysis.</description><subject>Anions</subject><subject>Boron</subject><subject>Chemical analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Derivatives</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Nitriles</subject><subject>NMR spectroscopy</subject><subject>Spectrum analysis</subject><subject>Synthesis</subject><subject>Synthesis and Properties of Inorganic Compounds</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1UM1KAzEQDqJgrT6At4AXBVczSTa7e_CgrVqhrWD1JLJkt7N2pSY12VZ68wG8-YY-iVur9CAehhm-vxmGkF1gRwBCHg8YE4pxoTgwzkCINdKAUEAQKxDrpLGggwW_Sba8f2JMShbFDfI-mJtqhL701Ba0X1auHCNtoytnuipn-A3XApqPrbdBG3OdWacrpNoMf0E7XMGnprTG0_sz0zH08-2DQr9187AY9g09ocAOKfADms2ppr0yd_ZVz5D2sBrZ4TbZKPTY485Pb5K7i_PbVifoXl9etU67QS5AVYHMlIjjqMjCUEgeCqUQ80zIIuFRpJOEqQwzjGOsS0ASQiZlmMsCVciRDXPRJHvL3ImzL1P0Vfpkp87UK1MuE1AsklzWKliq6iO9d1ikE1c-azdPgaWLp6d_nl57-NLja615RLdK_t_0BcnhgnU</recordid><startdate>20210201</startdate><enddate>20210201</enddate><creator>Nelyubin, A. V.</creator><creator>Klyukin, I. N.</creator><creator>Zhdanov, A. P.</creator><creator>Grigor’ev, M. S.</creator><creator>Zhizhin, K. Yu</creator><creator>Kuznetsov, N. T.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210201</creationdate><title>Synthesis of Nitrile Derivatives of the closo-Decaborate and closo-Dodecaborate Anions [BnHn – 1NCR]– (n = 10, 12) by a Microwave Method</title><author>Nelyubin, A. V. ; Klyukin, I. N. ; Zhdanov, A. P. ; Grigor’ev, M. S. ; Zhizhin, K. Yu ; Kuznetsov, N. T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-4b63887fb553425366eecb34f9277a9906bebe88ee8831951b445c4fe652e0dc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Anions</topic><topic>Boron</topic><topic>Chemical analysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Derivatives</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Nitriles</topic><topic>NMR spectroscopy</topic><topic>Spectrum analysis</topic><topic>Synthesis</topic><topic>Synthesis and Properties of Inorganic Compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nelyubin, A. V.</creatorcontrib><creatorcontrib>Klyukin, I. N.</creatorcontrib><creatorcontrib>Zhdanov, A. P.</creatorcontrib><creatorcontrib>Grigor’ev, M. S.</creatorcontrib><creatorcontrib>Zhizhin, K. Yu</creatorcontrib><creatorcontrib>Kuznetsov, N. T.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nelyubin, A. V.</au><au>Klyukin, I. N.</au><au>Zhdanov, A. P.</au><au>Grigor’ev, M. S.</au><au>Zhizhin, K. Yu</au><au>Kuznetsov, N. T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Nitrile Derivatives of the closo-Decaborate and closo-Dodecaborate Anions [BnHn – 1NCR]– (n = 10, 12) by a Microwave Method</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2021-02-01</date><risdate>2021</risdate><volume>66</volume><issue>2</issue><spage>139</spage><epage>145</epage><pages>139-145</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>Methods for the preparation of nitrile derivatives of boron cluster anions using microwave synthesis have been proposed. The reported approaches have been used to synthesize derivatives based on high-boiling and solid organic nitriles. For the first time, derivatives of the [B
10
H
10
]
2–
anion based on dinitriles have been prepared, and [B
12
H
11
NCCH
3
]
–
and [B
12
H
11
NCC
2
H
5
]
–
derivatives have been isolated in individual form. The prepared compounds have been studied by multinuclear NMR spectroscopy, IR spectroscopy, and elemental analysis.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023621020133</doi><tpages>7</tpages></addata></record> |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Anions Boron Chemical analysis Chemistry Chemistry and Materials Science Derivatives Infrared analysis Infrared spectroscopy Inorganic Chemistry Nitriles NMR spectroscopy Spectrum analysis Synthesis Synthesis and Properties of Inorganic Compounds |
| title | Synthesis of Nitrile Derivatives of the closo-Decaborate and closo-Dodecaborate Anions [BnHn – 1NCR]– (n = 10, 12) by a Microwave Method |
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