Synthesis, structural topology, DFT, and photoluminescence properties of Sm(III) and octacyanomolybdate(V) building-block-based 1-D chain complex

A new one-dimensional cyanide-based coordination polymer comprising Sm(III) and octacyanomolybdate(V) building blocks was prepared and characterized through single-crystal X-ray diffraction and elemental analyses. The new compound consisted of one-dimensional chains of [Sm(terpy)(DMF) 4 ] [Mo(CN) 8...

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