The study of the pyrolysis products of Ni (II) and Pd (II) chelate complexes as catalysts for the oxygen electroreduction reaction
Nitrogen-doped carbon materials were prepared by the pyrolysis of carbon black Vulcan XC-72 impregnated with nitrogen-containing Pd (II) and Ni (II) complexes. The composition of materials was studied at different stages of their synthesis. It is shown that nanoparticles of metals and/or their oxide...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2021-03, Vol.25 (3), p.789-796 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Belenov, Sergey V. Guterman, Vladimir E. Popov, Leonid D. Kozakov, Alexey T. Nikolsky, Anatoly V. Danilenko, Maria V. Safronenko, Olga I. Nikulin, Alexey Yu |
| description | Nitrogen-doped carbon materials were prepared by the pyrolysis of carbon black Vulcan XC-72 impregnated with nitrogen-containing Pd (II) and Ni (II) complexes. The composition of materials was studied at different stages of their synthesis. It is shown that nanoparticles of metals and/or their oxides are not the main electroactive component of materials in the oxygen electroreduction reaction (ORR). It is established that the palladium complex provides a much more efficient doping of carbon with nitrogen compared to the nickel complex of a similar composition. This results in the high ORR electrocatalytic activity of the catalyst obtained, palladium complex being used in an alkaline medium. This material is a promising one to be used as an electrocatalyst in fuel cells with an anion-conducting membrane.
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| doi_str_mv | 10.1007/s10008-020-04854-1 |
| format | Article |
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Graphical abstract</description><subject>Analytical Chemistry</subject><subject>Carbon</subject><subject>Carbon black</subject><subject>Catalysts</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composition</subject><subject>Condensed Matter Physics</subject><subject>Coordination compounds</subject><subject>Electrocatalysts</subject><subject>Electrochemistry</subject><subject>Electrowinning</subject><subject>Energy Storage</subject><subject>Fuel cells</subject><subject>Nanoparticles</subject><subject>Nickel</subject><subject>Nitrogen</subject><subject>Original Paper</subject><subject>Palladium</subject><subject>Physical Chemistry</subject><subject>Pyrolysis</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kL1OwzAUhSMEEqXwAkyWWGAI2I6dOCOq-KlUAUOZLTu-aVOlcbATqVl5ctwEiY3FPpbPd67uiaJrgu8JxtmDDycWMaY4xkxwFpOTaEZYksQ4S8XpqGksmBDn0YX3O4xJlhI8i77XW0C-682AbIm68GgHZ-vBVx61zpq-6Pzx561Ct8vlHVKNQR9m0sUWatUBKuy-reEAHimPCtWpgAeqtG4MtIdhAw2CGorOWQfHzMo2yIEaxWV0Vqraw9XvPY8-n5_Wi9d49f6yXDyu4iLhaRcnuSKa6ixRaa6wNrTk2pRZUnKlc0y0MAxSVmpmUm54XjCaaWoAwuKap5Qm8-hmyg17ffXgO7mzvWvCSElZjlMuBOPBRSdX4az3DkrZumqv3CAJlseu5dS1DF3LsWtJApRMkA_mZgPuL_of6gfFhIKu</recordid><startdate>20210301</startdate><enddate>20210301</enddate><creator>Belenov, Sergey V.</creator><creator>Guterman, Vladimir E.</creator><creator>Popov, Leonid D.</creator><creator>Kozakov, Alexey T.</creator><creator>Nikolsky, Anatoly V.</creator><creator>Danilenko, Maria V.</creator><creator>Safronenko, Olga I.</creator><creator>Nikulin, Alexey Yu</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2980-7089</orcidid></search><sort><creationdate>20210301</creationdate><title>The study of the pyrolysis products of Ni (II) and Pd (II) chelate complexes as catalysts for the oxygen electroreduction reaction</title><author>Belenov, Sergey V. ; Guterman, Vladimir E. ; Popov, Leonid D. ; Kozakov, Alexey T. ; Nikolsky, Anatoly V. ; Danilenko, Maria V. ; Safronenko, Olga I. ; Nikulin, Alexey Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-39a1b2b73a69a0bd2f5bdf73f5ab901b8d4e64fb4d65d59c427b2dee432b56223</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analytical Chemistry</topic><topic>Carbon</topic><topic>Carbon black</topic><topic>Catalysts</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composition</topic><topic>Condensed Matter Physics</topic><topic>Coordination compounds</topic><topic>Electrocatalysts</topic><topic>Electrochemistry</topic><topic>Electrowinning</topic><topic>Energy Storage</topic><topic>Fuel cells</topic><topic>Nanoparticles</topic><topic>Nickel</topic><topic>Nitrogen</topic><topic>Original Paper</topic><topic>Palladium</topic><topic>Physical Chemistry</topic><topic>Pyrolysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Belenov, Sergey V.</creatorcontrib><creatorcontrib>Guterman, Vladimir E.</creatorcontrib><creatorcontrib>Popov, Leonid D.</creatorcontrib><creatorcontrib>Kozakov, Alexey T.</creatorcontrib><creatorcontrib>Nikolsky, Anatoly V.</creatorcontrib><creatorcontrib>Danilenko, Maria V.</creatorcontrib><creatorcontrib>Safronenko, Olga I.</creatorcontrib><creatorcontrib>Nikulin, Alexey Yu</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Belenov, Sergey V.</au><au>Guterman, Vladimir E.</au><au>Popov, Leonid D.</au><au>Kozakov, Alexey T.</au><au>Nikolsky, Anatoly V.</au><au>Danilenko, Maria V.</au><au>Safronenko, Olga I.</au><au>Nikulin, Alexey Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The study of the pyrolysis products of Ni (II) and Pd (II) chelate complexes as catalysts for the oxygen electroreduction reaction</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2021-03-01</date><risdate>2021</risdate><volume>25</volume><issue>3</issue><spage>789</spage><epage>796</epage><pages>789-796</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>Nitrogen-doped carbon materials were prepared by the pyrolysis of carbon black Vulcan XC-72 impregnated with nitrogen-containing Pd (II) and Ni (II) complexes. The composition of materials was studied at different stages of their synthesis. It is shown that nanoparticles of metals and/or their oxides are not the main electroactive component of materials in the oxygen electroreduction reaction (ORR). It is established that the palladium complex provides a much more efficient doping of carbon with nitrogen compared to the nickel complex of a similar composition. This results in the high ORR electrocatalytic activity of the catalyst obtained, palladium complex being used in an alkaline medium. This material is a promising one to be used as an electrocatalyst in fuel cells with an anion-conducting membrane.
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| subjects | Analytical Chemistry Carbon Carbon black Catalysts Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Composition Condensed Matter Physics Coordination compounds Electrocatalysts Electrochemistry Electrowinning Energy Storage Fuel cells Nanoparticles Nickel Nitrogen Original Paper Palladium Physical Chemistry Pyrolysis |
| title | The study of the pyrolysis products of Ni (II) and Pd (II) chelate complexes as catalysts for the oxygen electroreduction reaction |
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