Catalytic Photoredox Allylation of Aldehydes Promoted by a Cobalt Complex

The preparation of homoallylic alcohols by addition of organometallic allyl compounds to carbonyls is an important strategy in organic chemistry. Allylating organometallic cobalt species can be generated employing stoichiometric quantities of Zn acting as reductant. To avoid the employment of stoich...

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Veröffentlicht in:	Advanced synthesis & catalysis 2021-02, Vol.363 (4), p.1105-1111
Hauptverfasser:	Gualandi, Andrea, Rodeghiero, Giacomo, Perciaccante, Rossana, Jansen, Thomas Paul, Moreno‐Cabrerizo, Cristina, Foucher, Charles, Marchini, Marianna, Ceroni, Paola, Cozzi, Pier Giorgio
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Aldehydes Allyl compounds Allylation Carbonyls Catalysis Chemical reactions Cobalt Cobalt compounds Iridium(III) photocatalyst Metalla photoredox catalysis Organic chemistry Photoredox catalysis Reducing agents Substrates Zinc
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