Room temperature flexible NH3 sensor based on polyaniline coated Rh-doped SnO2 hollow nanotubes

•A novel combination of polyaniline coated electrospun Rh-doped SnO2 hollow nanotubes.•Room temperature detection of NH3 with excellent selectivity, high response, favorable flexibility.•The enhanced sensing performances were due to the heterojunction between PANI and Rh- SnO2 and the catalytic effe...

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Veröffentlicht in:Sensors and actuators. B, Chemical Chemical, 2021-03, Vol.330, p.129313, Article 129313
Hauptverfasser: Liu, Ao, Lv, Siyuan, Zhao, Lianjing, Liu, Fangmeng, Wang, Jing, You, Rui, Yang, Zijie, He, Junming, Jiang, Li, Wang, Chenguang, Yan, Xu, Sun, Peng, Lu, Geyu
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container_title Sensors and actuators. B, Chemical
container_volume 330
creator Liu, Ao
Lv, Siyuan
Zhao, Lianjing
Liu, Fangmeng
Wang, Jing
You, Rui
Yang, Zijie
He, Junming
Jiang, Li
Wang, Chenguang
Yan, Xu
Sun, Peng
Lu, Geyu
description •A novel combination of polyaniline coated electrospun Rh-doped SnO2 hollow nanotubes.•Room temperature detection of NH3 with excellent selectivity, high response, favorable flexibility.•The enhanced sensing performances were due to the heterojunction between PANI and Rh- SnO2 and the catalytic effect of Rh2O3. In this work, polyaniline (PANI) coated Rh-doped SnO2 hollow nanotubes (PRS) were synthesized via electrostatic spinning and in-situ polymerization technique. The obtained samples were characterized by X-ray diffractometer, Field emission scanning electron microscopy, Transmission electron microscopy, X-ray photoelectron spectroscopy and Brunauer-Emmett-Teller. The gas sensing performances of the sensors based on PRS nanotubes were investigated systematically at room temperature. It was shown that the polyaniline coated 0.5 mol% Rh-doped SnO2 nanotube (PRS0.5) sensor exhibited the highest response value of 13.6 to 100 ppm NH3 at room temperature with excellent selectivity, acceptable repeatability and favorable flexibility. The enhanced gas sensing performances were due to the morphology structure, the heterojunction between PANI and Rh-SnO2 and the catalytic effect of Rh2O3. Thus, the PANI coated Rh-doped SnO2 hollow nanotubes could be a promising candidate for designing and fabricating flexible NH3 gas sensor at room temperature.
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In this work, polyaniline (PANI) coated Rh-doped SnO2 hollow nanotubes (PRS) were synthesized via electrostatic spinning and in-situ polymerization technique. The obtained samples were characterized by X-ray diffractometer, Field emission scanning electron microscopy, Transmission electron microscopy, X-ray photoelectron spectroscopy and Brunauer-Emmett-Teller. The gas sensing performances of the sensors based on PRS nanotubes were investigated systematically at room temperature. It was shown that the polyaniline coated 0.5 mol% Rh-doped SnO2 nanotube (PRS0.5) sensor exhibited the highest response value of 13.6 to 100 ppm NH3 at room temperature with excellent selectivity, acceptable repeatability and favorable flexibility. The enhanced gas sensing performances were due to the morphology structure, the heterojunction between PANI and Rh-SnO2 and the catalytic effect of Rh2O3. Thus, the PANI coated Rh-doped SnO2 hollow nanotubes could be a promising candidate for designing and fabricating flexible NH3 gas sensor at room temperature.</description><identifier>ISSN: 0925-4005</identifier><identifier>EISSN: 1873-3077</identifier><identifier>DOI: 10.1016/j.snb.2020.129313</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Ammonia ; Coating ; Electron microscopy ; Field emission microscopy ; Gas sensors ; Heterojunctions ; Microscopy ; Morphology ; Nanotubes ; NH3 ; Photoelectrons ; Polyaniline ; Polyanilines ; Rh-doped SnO2 hollow nanotubes ; Room temperature ; Selectivity ; Sensors ; Tin dioxide</subject><ispartof>Sensors and actuators. B, Chemical, 2021-03, Vol.330, p.129313, Article 129313</ispartof><rights>2020</rights><rights>Copyright Elsevier Science Ltd. 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B, Chemical</title><description>•A novel combination of polyaniline coated electrospun Rh-doped SnO2 hollow nanotubes.•Room temperature detection of NH3 with excellent selectivity, high response, favorable flexibility.•The enhanced sensing performances were due to the heterojunction between PANI and Rh- SnO2 and the catalytic effect of Rh2O3. In this work, polyaniline (PANI) coated Rh-doped SnO2 hollow nanotubes (PRS) were synthesized via electrostatic spinning and in-situ polymerization technique. The obtained samples were characterized by X-ray diffractometer, Field emission scanning electron microscopy, Transmission electron microscopy, X-ray photoelectron spectroscopy and Brunauer-Emmett-Teller. The gas sensing performances of the sensors based on PRS nanotubes were investigated systematically at room temperature. It was shown that the polyaniline coated 0.5 mol% Rh-doped SnO2 nanotube (PRS0.5) sensor exhibited the highest response value of 13.6 to 100 ppm NH3 at room temperature with excellent selectivity, acceptable repeatability and favorable flexibility. The enhanced gas sensing performances were due to the morphology structure, the heterojunction between PANI and Rh-SnO2 and the catalytic effect of Rh2O3. Thus, the PANI coated Rh-doped SnO2 hollow nanotubes could be a promising candidate for designing and fabricating flexible NH3 gas sensor at room temperature.</description><subject>Ammonia</subject><subject>Coating</subject><subject>Electron microscopy</subject><subject>Field emission microscopy</subject><subject>Gas sensors</subject><subject>Heterojunctions</subject><subject>Microscopy</subject><subject>Morphology</subject><subject>Nanotubes</subject><subject>NH3</subject><subject>Photoelectrons</subject><subject>Polyaniline</subject><subject>Polyanilines</subject><subject>Rh-doped SnO2 hollow nanotubes</subject><subject>Room temperature</subject><subject>Selectivity</subject><subject>Sensors</subject><subject>Tin dioxide</subject><issn>0925-4005</issn><issn>1873-3077</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kF1LwzAUhoMoOKc_wLuA150nSZuseCVDnSAOpl6HtD1lLV1Sk1bdvzejXnt1Pnjf8_EQcs1gwYDJ23YRbLHgwGPNc8HECZmxpRKJAKVOyQxyniUpQHZOLkJoASAVEmZEb53b0wH3PXozjB5p3eFPU3RIX9eCBrTBeVqYgBV1lvauOxjbdI1FWjozxO52l1Suj8mb3XC6c13nvqk11g1jgeGSnNWmC3j1F-fk4_HhfbVOXjZPz6v7l6QUPBsSzlKzVFDLoq5zJXgqlQQskBvBDee8UlCprMiMUrlhkkEqZfwhq3kpACUXc3Izze29-xwxDLp1o7dxpebpMo8UQLGoYpOq9C4Ej7XufbM3_qAZ6CNH3erIUR856olj9NxNHoznfzXodSgbtCVWjcdy0JVr_nH_AvabeWY</recordid><startdate>20210301</startdate><enddate>20210301</enddate><creator>Liu, Ao</creator><creator>Lv, Siyuan</creator><creator>Zhao, Lianjing</creator><creator>Liu, Fangmeng</creator><creator>Wang, Jing</creator><creator>You, Rui</creator><creator>Yang, Zijie</creator><creator>He, Junming</creator><creator>Jiang, Li</creator><creator>Wang, Chenguang</creator><creator>Yan, Xu</creator><creator>Sun, Peng</creator><creator>Lu, Geyu</creator><general>Elsevier B.V</general><general>Elsevier Science Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20210301</creationdate><title>Room temperature flexible NH3 sensor based on polyaniline coated Rh-doped SnO2 hollow nanotubes</title><author>Liu, Ao ; Lv, Siyuan ; Zhao, Lianjing ; Liu, Fangmeng ; Wang, Jing ; You, Rui ; Yang, Zijie ; He, Junming ; Jiang, Li ; Wang, Chenguang ; Yan, Xu ; Sun, Peng ; Lu, Geyu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c325t-214a870f6bff973246760ebe2a32a222d70d75b5a779a16104660005f2c30e623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Ammonia</topic><topic>Coating</topic><topic>Electron microscopy</topic><topic>Field emission microscopy</topic><topic>Gas sensors</topic><topic>Heterojunctions</topic><topic>Microscopy</topic><topic>Morphology</topic><topic>Nanotubes</topic><topic>NH3</topic><topic>Photoelectrons</topic><topic>Polyaniline</topic><topic>Polyanilines</topic><topic>Rh-doped SnO2 hollow nanotubes</topic><topic>Room temperature</topic><topic>Selectivity</topic><topic>Sensors</topic><topic>Tin dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Ao</creatorcontrib><creatorcontrib>Lv, Siyuan</creatorcontrib><creatorcontrib>Zhao, Lianjing</creatorcontrib><creatorcontrib>Liu, Fangmeng</creatorcontrib><creatorcontrib>Wang, Jing</creatorcontrib><creatorcontrib>You, Rui</creatorcontrib><creatorcontrib>Yang, Zijie</creatorcontrib><creatorcontrib>He, Junming</creatorcontrib><creatorcontrib>Jiang, Li</creatorcontrib><creatorcontrib>Wang, Chenguang</creatorcontrib><creatorcontrib>Yan, Xu</creatorcontrib><creatorcontrib>Sun, Peng</creatorcontrib><creatorcontrib>Lu, Geyu</creatorcontrib><collection>CrossRef</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Sensors and actuators. 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The gas sensing performances of the sensors based on PRS nanotubes were investigated systematically at room temperature. It was shown that the polyaniline coated 0.5 mol% Rh-doped SnO2 nanotube (PRS0.5) sensor exhibited the highest response value of 13.6 to 100 ppm NH3 at room temperature with excellent selectivity, acceptable repeatability and favorable flexibility. The enhanced gas sensing performances were due to the morphology structure, the heterojunction between PANI and Rh-SnO2 and the catalytic effect of Rh2O3. Thus, the PANI coated Rh-doped SnO2 hollow nanotubes could be a promising candidate for designing and fabricating flexible NH3 gas sensor at room temperature.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.snb.2020.129313</doi></addata></record>
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subjects Ammonia
Coating
Electron microscopy
Field emission microscopy
Gas sensors
Heterojunctions
Microscopy
Morphology
Nanotubes
NH3
Photoelectrons
Polyaniline
Polyanilines
Rh-doped SnO2 hollow nanotubes
Room temperature
Selectivity
Sensors
Tin dioxide
title Room temperature flexible NH3 sensor based on polyaniline coated Rh-doped SnO2 hollow nanotubes
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