Nanocrystalline TiO2 Films: Synthesis and Low-Temperature Luminescent and Photovoltaic Properties
Nanocrystalline TiO 2 films of different morphology have been fabricated using various experimental approaches. Photoluminescent properties of films at 90 K have been studied. The effect of heat treatment on low-temperature properties caused by the anatase–rutile phase transition has been demonstrat...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2021, Vol.66 (1), p.117-123 |
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| container_title | Russian journal of inorganic chemistry |
| container_volume | 66 |
| creator | Serikov, T. M. Ibrayev, N. Kh Isaikina, O. Ya Savilov, S. V. |
| description | Nanocrystalline TiO
2
films of different morphology have been fabricated using various experimental approaches. Photoluminescent properties of films at 90 K have been studied. The effect of heat treatment on low-temperature properties caused by the anatase–rutile phase transition has been demonstrated. It has been shown that the luminescence of rutile films is longer, for both TiO
2
nanoparticles and nanotubes. Photovoltaic cells of the DSSC type have been assembled on the basis of the obtained nanostructures. Impedance spectroscopy has demonstrated that the resistance to electron transport in films of TiO
2
nanotubes is higher and the recombination rate is lower than in films of nanoparticles. |
| doi_str_mv | 10.1134/S0036023621010071 |
| format | Article |
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2
films of different morphology have been fabricated using various experimental approaches. Photoluminescent properties of films at 90 K have been studied. The effect of heat treatment on low-temperature properties caused by the anatase–rutile phase transition has been demonstrated. It has been shown that the luminescence of rutile films is longer, for both TiO
2
nanoparticles and nanotubes. Photovoltaic cells of the DSSC type have been assembled on the basis of the obtained nanostructures. Impedance spectroscopy has demonstrated that the resistance to electron transport in films of TiO
2
nanotubes is higher and the recombination rate is lower than in films of nanoparticles.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023621010071</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anatase ; Chemistry ; Chemistry and Materials Science ; Electron transport ; Heat treatment ; Inorganic Chemistry ; Inorganic Materials and Nanomaterials ; Low temperature ; Morphology ; Nanocrystals ; Nanoparticles ; Nanotubes ; Phase transitions ; Photoluminescence ; Photovoltaic cells ; Properties (attributes) ; Rutile ; Titanium dioxide</subject><ispartof>Russian journal of inorganic chemistry, 2021, Vol.66 (1), p.117-123</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2021, Vol. 66, No. 1, pp. 117–123. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Zhurnal Neorganicheskoi Khimii, 2021, Vol. 66, No. 1, pp. 107–114.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-9d4cbd27435b106f3feaddf6fa321f44858052aa0338ce552c9b364198d3a32b3</citedby><cites>FETCH-LOGICAL-c316t-9d4cbd27435b106f3feaddf6fa321f44858052aa0338ce552c9b364198d3a32b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023621010071$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023621010071$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Serikov, T. M.</creatorcontrib><creatorcontrib>Ibrayev, N. Kh</creatorcontrib><creatorcontrib>Isaikina, O. Ya</creatorcontrib><creatorcontrib>Savilov, S. V.</creatorcontrib><title>Nanocrystalline TiO2 Films: Synthesis and Low-Temperature Luminescent and Photovoltaic Properties</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>Nanocrystalline TiO
2
films of different morphology have been fabricated using various experimental approaches. Photoluminescent properties of films at 90 K have been studied. The effect of heat treatment on low-temperature properties caused by the anatase–rutile phase transition has been demonstrated. It has been shown that the luminescence of rutile films is longer, for both TiO
2
nanoparticles and nanotubes. Photovoltaic cells of the DSSC type have been assembled on the basis of the obtained nanostructures. Impedance spectroscopy has demonstrated that the resistance to electron transport in films of TiO
2
nanotubes is higher and the recombination rate is lower than in films of nanoparticles.</description><subject>Anatase</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electron transport</subject><subject>Heat treatment</subject><subject>Inorganic Chemistry</subject><subject>Inorganic Materials and Nanomaterials</subject><subject>Low temperature</subject><subject>Morphology</subject><subject>Nanocrystals</subject><subject>Nanoparticles</subject><subject>Nanotubes</subject><subject>Phase transitions</subject><subject>Photoluminescence</subject><subject>Photovoltaic cells</subject><subject>Properties (attributes)</subject><subject>Rutile</subject><subject>Titanium dioxide</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kF1LwzAUhoMoOD9-gHcFr6vnJGmbeifDqVDcYPO6pGnqOtpmJqmyf2_mBC_Eq3PxPs974CXkCuEGkfHbJQBLgbKUIiBAhkdkggnDWKTIjslkH8f7_JScObcB4BwyMSHyRQ5G2Z3zsuvaQUerdk6jWdv17i5a7ga_1q51kRzqqDCf8Ur3W22lH62OirEPglN68N_5Ym28-TCdl62KFtYE0LfaXZCTRnZOX_7cc_I6e1hNn-Ji_vg8vS9ixTD1cV5zVdU04yypENKGNVrWdZM2klFsOBeJgIRKCYwJpZOEqrxiKcdc1CwgFTsn14ferTXvo3a-3JjRDuFlSbnIqcggywOFB0pZ45zVTbm1bS_trkQo90uWf5YMDj04LrDDm7a_zf9LX-MVdWE</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Serikov, T. M.</creator><creator>Ibrayev, N. Kh</creator><creator>Isaikina, O. Ya</creator><creator>Savilov, S. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>Nanocrystalline TiO2 Films: Synthesis and Low-Temperature Luminescent and Photovoltaic Properties</title><author>Serikov, T. M. ; Ibrayev, N. Kh ; Isaikina, O. Ya ; Savilov, S. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-9d4cbd27435b106f3feaddf6fa321f44858052aa0338ce552c9b364198d3a32b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Anatase</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electron transport</topic><topic>Heat treatment</topic><topic>Inorganic Chemistry</topic><topic>Inorganic Materials and Nanomaterials</topic><topic>Low temperature</topic><topic>Morphology</topic><topic>Nanocrystals</topic><topic>Nanoparticles</topic><topic>Nanotubes</topic><topic>Phase transitions</topic><topic>Photoluminescence</topic><topic>Photovoltaic cells</topic><topic>Properties (attributes)</topic><topic>Rutile</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Serikov, T. M.</creatorcontrib><creatorcontrib>Ibrayev, N. Kh</creatorcontrib><creatorcontrib>Isaikina, O. Ya</creatorcontrib><creatorcontrib>Savilov, S. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Serikov, T. M.</au><au>Ibrayev, N. Kh</au><au>Isaikina, O. Ya</au><au>Savilov, S. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nanocrystalline TiO2 Films: Synthesis and Low-Temperature Luminescent and Photovoltaic Properties</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2021</date><risdate>2021</risdate><volume>66</volume><issue>1</issue><spage>117</spage><epage>123</epage><pages>117-123</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>Nanocrystalline TiO
2
films of different morphology have been fabricated using various experimental approaches. Photoluminescent properties of films at 90 K have been studied. The effect of heat treatment on low-temperature properties caused by the anatase–rutile phase transition has been demonstrated. It has been shown that the luminescence of rutile films is longer, for both TiO
2
nanoparticles and nanotubes. Photovoltaic cells of the DSSC type have been assembled on the basis of the obtained nanostructures. Impedance spectroscopy has demonstrated that the resistance to electron transport in films of TiO
2
nanotubes is higher and the recombination rate is lower than in films of nanoparticles.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023621010071</doi><tpages>7</tpages></addata></record> |
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| ispartof | Russian journal of inorganic chemistry, 2021, Vol.66 (1), p.117-123 |
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| language | eng |
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| subjects | Anatase Chemistry Chemistry and Materials Science Electron transport Heat treatment Inorganic Chemistry Inorganic Materials and Nanomaterials Low temperature Morphology Nanocrystals Nanoparticles Nanotubes Phase transitions Photoluminescence Photovoltaic cells Properties (attributes) Rutile Titanium dioxide |
| title | Nanocrystalline TiO2 Films: Synthesis and Low-Temperature Luminescent and Photovoltaic Properties |
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