Thermodynamic Aspects for the Reaction of Polychlorinated Biphenyls with Sodium Metoxide in Ethanol and Dimethyl Sulfoxide Solution

The reaction of Sovol technical-grade mixture of polychlorinated biphenyls with sodium methoxide in dimethyl sulfoxide and ethanol medium has been studied for the first time by thermodynamic modeling. The addition of ethanol co-solvent to dimethyl sulfoxide has been found to result in the emergence...

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Veröffentlicht in:	Doklady. Chemistry 2020-11, Vol.495 (1), p.186-190
Hauptverfasser:	Maiorova, A. V., Kulikova, T. V., Gorbunova, T. I., Pervova, M. G., Shunyaev, K. Yu, Leontiev, L. I.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Technology Chemistry Chemistry and Materials Science Chemistry/Food Science Chlorine Congeners Dimethyl sulfoxide Ethanol Industrial Chemistry/Chemical Engineering PCB Polychlorinated biphenyls Pretreatment Solvolysis Substitution reactions Sulfoxides Thermodynamic models
Online-Zugang:	Volltext
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