Palladium Nanoparticles in Hypercrosslinked Polystyrene: Synthesis and Application in the Hydrogenation of Arenes
A novel method for incorporation of palladium nanoparticles into a porous hypercrosslinked polystyrene matrix has been developed. The composite obtained by reduction of [Pd(π-allyl)Cl] 2 with hydrogen in supercritical CO 2 shows high catalytic activity in the hydrogenation of benzene and can be used...
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| Veröffentlicht in: | Petroleum chemistry 2021, Vol.61 (1), p.76-80 |
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| container_title | Petroleum chemistry |
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| creator | Lyubimov, S. E. Zvinchuk, A. A. Korlyukov, A. A. Davankov, V. A. Parenago, O. P. |
| description | A novel method for incorporation of palladium nanoparticles into a porous hypercrosslinked polystyrene matrix has been developed. The composite obtained by reduction of [Pd(π-allyl)Cl]
2
with hydrogen in supercritical CO
2
shows high catalytic activity in the hydrogenation of benzene and can be used twelve (12) times in a row without any decrease in conversion rate. The catalyst is also suitable for quantitative hydrogenation of toluene, tetralin and phenol. The obtained catalytic system is compared with the palladium composite synthesized by a conventional method based on hypercrosslinked polystyrene. |
| doi_str_mv | 10.1134/S0965544121010084 |
| format | Article |
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2
with hydrogen in supercritical CO
2
shows high catalytic activity in the hydrogenation of benzene and can be used twelve (12) times in a row without any decrease in conversion rate. The catalyst is also suitable for quantitative hydrogenation of toluene, tetralin and phenol. The obtained catalytic system is compared with the palladium composite synthesized by a conventional method based on hypercrosslinked polystyrene.</description><identifier>ISSN: 0965-5441</identifier><identifier>EISSN: 1555-6239</identifier><identifier>DOI: 10.1134/S0965544121010084</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aromatic compounds ; Benzene ; Catalytic activity ; Chemistry ; Chemistry and Materials Science ; Cyclohexane ; Hydrogenation ; Industrial Chemistry/Chemical Engineering ; Nanoparticles ; Palladium ; Polystyrene ; Polystyrene resins ; Porous media ; Toluene</subject><ispartof>Petroleum chemistry, 2021, Vol.61 (1), p.76-80</ispartof><rights>Pleiades Publishing, Ltd. 2021. Russian Text © The Author(s), 2021, published in Neftekhimiya, 2021, Vol. 61, No. 1, pp. 87–91.</rights><rights>COPYRIGHT 2021 Springer</rights><rights>Pleiades Publishing, Ltd. 2021. Russian Text © The Author(s), 2021, published in Neftekhimiya, 2021, Vol. 61, No. 1, pp. 87–91. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c435t-2fe1bccbee430905997865cccf5c0a7dbcdeef532106bb82f27cf5246f1e219b3</citedby><cites>FETCH-LOGICAL-c435t-2fe1bccbee430905997865cccf5c0a7dbcdeef532106bb82f27cf5246f1e219b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0965544121010084$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0965544121010084$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Lyubimov, S. E.</creatorcontrib><creatorcontrib>Zvinchuk, A. A.</creatorcontrib><creatorcontrib>Korlyukov, A. A.</creatorcontrib><creatorcontrib>Davankov, V. A.</creatorcontrib><creatorcontrib>Parenago, O. P.</creatorcontrib><title>Palladium Nanoparticles in Hypercrosslinked Polystyrene: Synthesis and Application in the Hydrogenation of Arenes</title><title>Petroleum chemistry</title><addtitle>Pet. Chem</addtitle><description>A novel method for incorporation of palladium nanoparticles into a porous hypercrosslinked polystyrene matrix has been developed. The composite obtained by reduction of [Pd(π-allyl)Cl]
2
with hydrogen in supercritical CO
2
shows high catalytic activity in the hydrogenation of benzene and can be used twelve (12) times in a row without any decrease in conversion rate. The catalyst is also suitable for quantitative hydrogenation of toluene, tetralin and phenol. The obtained catalytic system is compared with the palladium composite synthesized by a conventional method based on hypercrosslinked polystyrene.</description><subject>Aromatic compounds</subject><subject>Benzene</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cyclohexane</subject><subject>Hydrogenation</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Nanoparticles</subject><subject>Palladium</subject><subject>Polystyrene</subject><subject>Polystyrene resins</subject><subject>Porous media</subject><subject>Toluene</subject><issn>0965-5441</issn><issn>1555-6239</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><recordid>eNp1kU9LxDAQxYMouK5-AG8Fz9UkTfrHW1nUFRZdWD2XNJ2sWbtJN-ke-u1NreBBJIfAvPfLzOQhdE3wLSEJu9vgIuWcMUIJJhjn7ATNCOc8TmlSnKLZKMejfo4uvN9hTDLCkhk6rEXbikYf99GLMLYTrteyBR9pEy2HDpx01vtWm09oorVtB98PDgzcR5vB9B_gtY-EaaKy61otRa-tGdGgBLxxdgtmKloVlSPoL9GZEq2Hq597jt4fH94Wy3j1-vS8KFexZAnvY6qA1FLWACzBBeZFkeUpl1IqLrHImlo2AIonYd-0rnOqaBYkylJFgJKiTuboZnq3c_ZwBN9XO3t0JrSsKMsLTFmW8uC6nVxb0UKljbK9EzKcBvZaWgNKh3qZcpLmvKAjQCbg-2McqKpzei_cUBFcjVFUf6IIDJ0YH7xmC-53lP-hL8LTjNY</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Lyubimov, S. E.</creator><creator>Zvinchuk, A. A.</creator><creator>Korlyukov, A. A.</creator><creator>Davankov, V. A.</creator><creator>Parenago, O. P.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>Palladium Nanoparticles in Hypercrosslinked Polystyrene: Synthesis and Application in the Hydrogenation of Arenes</title><author>Lyubimov, S. E. ; Zvinchuk, A. A. ; Korlyukov, A. A. ; Davankov, V. A. ; Parenago, O. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c435t-2fe1bccbee430905997865cccf5c0a7dbcdeef532106bb82f27cf5246f1e219b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aromatic compounds</topic><topic>Benzene</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cyclohexane</topic><topic>Hydrogenation</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Nanoparticles</topic><topic>Palladium</topic><topic>Polystyrene</topic><topic>Polystyrene resins</topic><topic>Porous media</topic><topic>Toluene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lyubimov, S. E.</creatorcontrib><creatorcontrib>Zvinchuk, A. A.</creatorcontrib><creatorcontrib>Korlyukov, A. A.</creatorcontrib><creatorcontrib>Davankov, V. A.</creatorcontrib><creatorcontrib>Parenago, O. P.</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><jtitle>Petroleum chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lyubimov, S. E.</au><au>Zvinchuk, A. A.</au><au>Korlyukov, A. A.</au><au>Davankov, V. A.</au><au>Parenago, O. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium Nanoparticles in Hypercrosslinked Polystyrene: Synthesis and Application in the Hydrogenation of Arenes</atitle><jtitle>Petroleum chemistry</jtitle><stitle>Pet. Chem</stitle><date>2021</date><risdate>2021</risdate><volume>61</volume><issue>1</issue><spage>76</spage><epage>80</epage><pages>76-80</pages><issn>0965-5441</issn><eissn>1555-6239</eissn><abstract>A novel method for incorporation of palladium nanoparticles into a porous hypercrosslinked polystyrene matrix has been developed. The composite obtained by reduction of [Pd(π-allyl)Cl]
2
with hydrogen in supercritical CO
2
shows high catalytic activity in the hydrogenation of benzene and can be used twelve (12) times in a row without any decrease in conversion rate. The catalyst is also suitable for quantitative hydrogenation of toluene, tetralin and phenol. The obtained catalytic system is compared with the palladium composite synthesized by a conventional method based on hypercrosslinked polystyrene.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0965544121010084</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Petroleum chemistry, 2021, Vol.61 (1), p.76-80 |
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| language | eng |
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| source | Business Source Complete; SpringerLink Journals - AutoHoldings |
| subjects | Aromatic compounds Benzene Catalytic activity Chemistry Chemistry and Materials Science Cyclohexane Hydrogenation Industrial Chemistry/Chemical Engineering Nanoparticles Palladium Polystyrene Polystyrene resins Porous media Toluene |
| title | Palladium Nanoparticles in Hypercrosslinked Polystyrene: Synthesis and Application in the Hydrogenation of Arenes |
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