Removal of cesium ions from A-type zeolites using sodium tetrakis(4-fluorophenyl)borate and sodium tetraphenylborate
With the ultimate aim of reducing the volume of radioactive-cesium-contaminated soil generated by the nuclear power plant accident in Fukushima Prefecture in 2011, this study focuses on the desorption of Cs + ions from minerals that strongly adsorb Cs + , such as clay, using the ion-association reag...
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Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2021, Vol.327 (1), p.337-344 |
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creator | Saito, Yuko Shimizu, Shota Kumagai, Shogo Kameda, Tomohito Yoshioka, Toshiaki |
description | With the ultimate aim of reducing the volume of radioactive-cesium-contaminated soil generated by the nuclear power plant accident in Fukushima Prefecture in 2011, this study focuses on the desorption of Cs
+
ions from minerals that strongly adsorb Cs
+
, such as clay, using the ion-association reagents sodium tetrakis(4-fluorophenyl)borate hydrate (NaTFPB) and sodium tetraphenylborate (NaTPB) under mild conditions. A-type zeolite was selected as a representative aluminosilicate mineral with a high cesium adsorption capacity. NaTFPB exhibits stronger hydrophobic interactions with Cs
+
and improved Cs
+
compared to NaTPB; a desorption efficiency of 89.4% was achieved at a 10:1 NaTFPB/cesium molar ratio.
Graphic abstract |
doi_str_mv | 10.1007/s10967-020-07514-w |
format | Article |
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+
ions from minerals that strongly adsorb Cs
+
, such as clay, using the ion-association reagents sodium tetrakis(4-fluorophenyl)borate hydrate (NaTFPB) and sodium tetraphenylborate (NaTPB) under mild conditions. A-type zeolite was selected as a representative aluminosilicate mineral with a high cesium adsorption capacity. NaTFPB exhibits stronger hydrophobic interactions with Cs
+
and improved Cs
+
compared to NaTPB; a desorption efficiency of 89.4% was achieved at a 10:1 NaTFPB/cesium molar ratio.
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+
ions from minerals that strongly adsorb Cs
+
, such as clay, using the ion-association reagents sodium tetrakis(4-fluorophenyl)borate hydrate (NaTFPB) and sodium tetraphenylborate (NaTPB) under mild conditions. A-type zeolite was selected as a representative aluminosilicate mineral with a high cesium adsorption capacity. NaTFPB exhibits stronger hydrophobic interactions with Cs
+
and improved Cs
+
compared to NaTPB; a desorption efficiency of 89.4% was achieved at a 10:1 NaTFPB/cesium molar ratio.
Graphic abstract</description><subject>Aluminosilicates</subject><subject>Aluminum silicates</subject><subject>Cesium</subject><subject>Cesium ions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Clay minerals</subject><subject>Desorption</subject><subject>Diagnostic Radiology</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Hydrophobicity</subject><subject>Inorganic Chemistry</subject><subject>Ion association</subject><subject>Nuclear accidents</subject><subject>Nuclear Chemistry</subject><subject>Nuclear Physics</subject><subject>Nuclear power plants</subject><subject>Physical Chemistry</subject><subject>Reagents</subject><subject>Sodium</subject><subject>Soil contamination</subject><subject>Zeolites</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAUhYMoOI7-AVcBN7qI5tEm6XIQXzAgiK5D2iZjx7apSeow_nozVhA3ri7c-51zOQeAU4IvCcbiKhBccIEwxQiLnGRoswdmJJcSUSHxPphhyjjKBSOH4CiENca4kJLNQHwynfvQLXQWViY0Ywcb1wdovevgAsXtYOCncW0TTYBjaPoVDK7eYdFEr9-acJ4h247Ou-HV9Nv2onReRwN1X_8hp-t0PAYHVrfBnPzMOXi5vXm-vkfLx7uH68USVYwUEYmSpyyM1HXNCZeiyJixgmphZCatFoxRSXNb81Lrgle6rkXaZmWKWRrLOZuDs8l38O59NCGqtRt9n14qmskC0wxnLFF0oirvQvDGqsE3nfZbRbDataumdlVqV323qzZJxCZRSHC_Mv7X-h_VF5ZZgFY</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Saito, Yuko</creator><creator>Shimizu, Shota</creator><creator>Kumagai, Shogo</creator><creator>Kameda, Tomohito</creator><creator>Yoshioka, Toshiaki</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-4112-2584</orcidid><orcidid>https://orcid.org/0000-0002-1982-550X</orcidid><orcidid>https://orcid.org/0000-0002-5046-372X</orcidid><orcidid>https://orcid.org/0000-0002-8929-3772</orcidid></search><sort><creationdate>2021</creationdate><title>Removal of cesium ions from A-type zeolites using sodium tetrakis(4-fluorophenyl)borate and sodium tetraphenylborate</title><author>Saito, Yuko ; Shimizu, Shota ; Kumagai, Shogo ; Kameda, Tomohito ; Yoshioka, Toshiaki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-7b675131ddd61687943ef72a7e848fa7332825fd6baa96cadd7fa74b573bef663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aluminosilicates</topic><topic>Aluminum silicates</topic><topic>Cesium</topic><topic>Cesium ions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Clay minerals</topic><topic>Desorption</topic><topic>Diagnostic Radiology</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Hydrophobicity</topic><topic>Inorganic Chemistry</topic><topic>Ion association</topic><topic>Nuclear accidents</topic><topic>Nuclear Chemistry</topic><topic>Nuclear Physics</topic><topic>Nuclear power plants</topic><topic>Physical Chemistry</topic><topic>Reagents</topic><topic>Sodium</topic><topic>Soil contamination</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saito, Yuko</creatorcontrib><creatorcontrib>Shimizu, Shota</creatorcontrib><creatorcontrib>Kumagai, Shogo</creatorcontrib><creatorcontrib>Kameda, Tomohito</creatorcontrib><creatorcontrib>Yoshioka, Toshiaki</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saito, Yuko</au><au>Shimizu, Shota</au><au>Kumagai, Shogo</au><au>Kameda, Tomohito</au><au>Yoshioka, Toshiaki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Removal of cesium ions from A-type zeolites using sodium tetrakis(4-fluorophenyl)borate and sodium tetraphenylborate</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2021</date><risdate>2021</risdate><volume>327</volume><issue>1</issue><spage>337</spage><epage>344</epage><pages>337-344</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>With the ultimate aim of reducing the volume of radioactive-cesium-contaminated soil generated by the nuclear power plant accident in Fukushima Prefecture in 2011, this study focuses on the desorption of Cs
+
ions from minerals that strongly adsorb Cs
+
, such as clay, using the ion-association reagents sodium tetrakis(4-fluorophenyl)borate hydrate (NaTFPB) and sodium tetraphenylborate (NaTPB) under mild conditions. A-type zeolite was selected as a representative aluminosilicate mineral with a high cesium adsorption capacity. NaTFPB exhibits stronger hydrophobic interactions with Cs
+
and improved Cs
+
compared to NaTPB; a desorption efficiency of 89.4% was achieved at a 10:1 NaTFPB/cesium molar ratio.
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subjects | Aluminosilicates Aluminum silicates Cesium Cesium ions Chemistry Chemistry and Materials Science Clay minerals Desorption Diagnostic Radiology Hadrons Heavy Ions Hydrophobicity Inorganic Chemistry Ion association Nuclear accidents Nuclear Chemistry Nuclear Physics Nuclear power plants Physical Chemistry Reagents Sodium Soil contamination Zeolites |
title | Removal of cesium ions from A-type zeolites using sodium tetrakis(4-fluorophenyl)borate and sodium tetraphenylborate |
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