Removal of cesium ions from A-type zeolites using sodium tetrakis(4-fluorophenyl)borate and sodium tetraphenylborate

With the ultimate aim of reducing the volume of radioactive-cesium-contaminated soil generated by the nuclear power plant accident in Fukushima Prefecture in 2011, this study focuses on the desorption of Cs + ions from minerals that strongly adsorb Cs + , such as clay, using the ion-association reag...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2021, Vol.327 (1), p.337-344
Hauptverfasser: Saito, Yuko, Shimizu, Shota, Kumagai, Shogo, Kameda, Tomohito, Yoshioka, Toshiaki
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container_issue 1
container_start_page 337
container_title Journal of radioanalytical and nuclear chemistry
container_volume 327
creator Saito, Yuko
Shimizu, Shota
Kumagai, Shogo
Kameda, Tomohito
Yoshioka, Toshiaki
description With the ultimate aim of reducing the volume of radioactive-cesium-contaminated soil generated by the nuclear power plant accident in Fukushima Prefecture in 2011, this study focuses on the desorption of Cs + ions from minerals that strongly adsorb Cs + , such as clay, using the ion-association reagents sodium tetrakis(4-fluorophenyl)borate hydrate (NaTFPB) and sodium tetraphenylborate (NaTPB) under mild conditions. A-type zeolite was selected as a representative aluminosilicate mineral with a high cesium adsorption capacity. NaTFPB exhibits stronger hydrophobic interactions with Cs + and improved Cs + compared to NaTPB; a desorption efficiency of 89.4% was achieved at a 10:1 NaTFPB/cesium molar ratio. Graphic abstract
doi_str_mv 10.1007/s10967-020-07514-w
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subjects Aluminosilicates
Aluminum silicates
Cesium
Cesium ions
Chemistry
Chemistry and Materials Science
Clay minerals
Desorption
Diagnostic Radiology
Hadrons
Heavy Ions
Hydrophobicity
Inorganic Chemistry
Ion association
Nuclear accidents
Nuclear Chemistry
Nuclear Physics
Nuclear power plants
Physical Chemistry
Reagents
Sodium
Soil contamination
Zeolites
title Removal of cesium ions from A-type zeolites using sodium tetrakis(4-fluorophenyl)borate and sodium tetraphenylborate
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