Phenoxo-bridged dinuclear mixed valence cobalt(/) complexes with reduced Schiff base ligands: synthesis, characterization, band gap measurements and fabrication of Schottky barrier diodes

Two homometallic class-I dinuclear mixed valence cobalt complexes, [(N 3 )Co III L 1 (μ-C 6 H 4 (NO 2 )CO 2 )Co II (N 3 )] ( 1 ) and [(N 3 )Co III L 2 (μ-C 6 H 4 (NO 2 )CO 2 )Co II (N 3 )] ( 2 ), have been synthesized using multisite N 2 O 4 coordination ligands, H 2 L 1 {where H 2 L 1 = (2,2-dimeth...

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