Nickel(II), copper(II) and zinc(II) complexes with an N-pendent dimethyl derivative of an octamethyl macrocyclic ligand: synthesis, characterization and antimicrobial studies
Interaction of CH 3 I with L (3,10-C-meso-Me 8 [14]diene) in the ratio of 4:1 in ethanolic solution at room temperature yielded N-pendent dimethyl derivative [(L-2H)(–CH 3 ) 2 ] denoted by L Z . Interaction of nickel(II) acetate tetrahydrate with L Z and subsequent addition of NaClO 4 ·6H 2 O produc...
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| Veröffentlicht in: | Journal of chemical sciences (Bangalore, India) India), 2021, Vol.133 (1), Article 7 |
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| creator | Das Gupta, Suman Kanti Rabi, Saswata Ghosh, Deponkor Yasmin, Farhana Dey, Benu Kumar Dey, Sujan Roy, Tapashi Ghosh |
| description | Interaction of CH
3
I with L (3,10-C-meso-Me
8
[14]diene) in the ratio of 4:1 in ethanolic solution at room temperature yielded N-pendent dimethyl derivative [(L-2H)(–CH
3
)
2
] denoted by L
Z
. Interaction of nickel(II) acetate tetrahydrate with L
Z
and subsequent addition of NaClO
4
·6H
2
O produced square planar orange-yellow product, [NiL
Z
](ClO
4
)
2
. The reaction of copper(II) perchlorate hexahydrate with L
Z
afforded four coordinated square planar red [CuL
Z
](ClO
4
)
2.
However, on the reaction of zinc(II) nitrate hexahydrate with L
Z
furnished white six coordinated two distereoisomeric complexes [ZnL
Zα
(NO
3
)
2
] and [ZnL
Zβ
(NO
3
)
2
]. Axial addition reactions on four coordinated square planar [NiL
Z
](ClO
4
)
2
with KX (X= SCN, NO
3
, Cl, Br or I) and NaNO
2
resulted in six coordinated octahedral and square pyramidal axial addition products, such as [NiL
Z
(NCS)
2
], [NiL
Z
(NO
3
)(ClO
4
)], [NiL
Z
Cl(ClO
4
)], [NiL
Z
Br
2
], [NiL
Z
I
2
] and [NiL
Z
(NO
2
)](ClO
4
), respectively. However axial substitution reactions on [ZnL
Zα
(NO
3
)
2
] with KY (Y= SCN, Cl or Br) and NaNO
2
produced six coordinated octahedral axial substitution products [ZnL
Zα
(NCS)
2
], [ZnL
Zα
Cl
2
], [ZnL
Zα
Br
2
] and [ZnL
Zα
(NO
2
)
2
]. Similarly, the axial substitution reactions on [ZnL
Zβ
(NO
3
)
2
] with KI and NaClO
4
.6H
2
O resulted in six coordinated octahedral axial substitution products [ZnL
Zβ
I
2
] and [ZnL
Zβ
(H
2
O)
2
](ClO
4
)
2
, respectively. The compounds have been characterized by analytical, spectroscopic, magnetochemical and conductivity data. The antimicrobial activities of the new ligand and its complexes have been tested against different micro pathogens.
Graphic abstract
Nickel(II), copper(II) and zinc(II) complexes with an N-pendent dimethyl derivative ligand L
Z
of an octamethyl tetraazmacrocyclic ligand were prepared. The compounds were characterized by different analytical and spectroscopic methods. Antibacterial and antifungal activities of these compounds against some bacteria and fungi were also investigated. |
| doi_str_mv | 10.1007/s12039-020-01861-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2486504251</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2486504251</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-3292d66ddfdf1500244d0837a2266465b4fd7a399213f39ff9541fa4f2ff2c293</originalsourceid><addsrcrecordid>eNp9kUtLAzEUhQdR8PkHXAXcKBjNazKNOxEfBdGNrkOaRxudyYxJqtYf5W80bQV3rnLDPec7F05VHWJ0hhFqzhMmiAqICIIIjziGzUa1g0RDYYMR3VzNDFJO-Ha1m9ILQnTEGrpTfT94_Wrb4_H45BTofhhsXM5ABQO-fNCrj-67obWfNoEPn2dlBx7gYIOxIQPjO5tnixYYG_27yv7dgt4tNb3O6nfXKR17vdCt16D10wK_AGkR8swmn0ruTEWlcwF8FUAfVukqZN_54pt41YKU58bbtF9tOdUme_D77lXPN9dPV3fw_vF2fHV5DzXFIkNKBDGcG-OMwzVChDGDRrRRhHDOeD1hzjSKCkEwdVQ4J2qGnWKOOEc0EXSvOlpzh9i_zW3K8qWfx1AiJWEjXiNGalxUZK0qV6YUrZND9J2KC4mRXPYi173I0otc9SKbYqJrUyriMLXxD_2P6wfR8pJ0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2486504251</pqid></control><display><type>article</type><title>Nickel(II), copper(II) and zinc(II) complexes with an N-pendent dimethyl derivative of an octamethyl macrocyclic ligand: synthesis, characterization and antimicrobial studies</title><source>EZB-FREE-00999 freely available EZB journals</source><source>Alma/SFX Local Collection</source><source>Free Full-Text Journals in Chemistry</source><source>SpringerLink Journals - AutoHoldings</source><creator>Das Gupta, Suman Kanti ; Rabi, Saswata ; Ghosh, Deponkor ; Yasmin, Farhana ; Dey, Benu Kumar ; Dey, Sujan ; Roy, Tapashi Ghosh</creator><creatorcontrib>Das Gupta, Suman Kanti ; Rabi, Saswata ; Ghosh, Deponkor ; Yasmin, Farhana ; Dey, Benu Kumar ; Dey, Sujan ; Roy, Tapashi Ghosh</creatorcontrib><description>Interaction of CH
3
I with L (3,10-C-meso-Me
8
[14]diene) in the ratio of 4:1 in ethanolic solution at room temperature yielded N-pendent dimethyl derivative [(L-2H)(–CH
3
)
2
] denoted by L
Z
. Interaction of nickel(II) acetate tetrahydrate with L
Z
and subsequent addition of NaClO
4
·6H
2
O produced square planar orange-yellow product, [NiL
Z
](ClO
4
)
2
. The reaction of copper(II) perchlorate hexahydrate with L
Z
afforded four coordinated square planar red [CuL
Z
](ClO
4
)
2.
However, on the reaction of zinc(II) nitrate hexahydrate with L
Z
furnished white six coordinated two distereoisomeric complexes [ZnL
Zα
(NO
3
)
2
] and [ZnL
Zβ
(NO
3
)
2
]. Axial addition reactions on four coordinated square planar [NiL
Z
](ClO
4
)
2
with KX (X= SCN, NO
3
, Cl, Br or I) and NaNO
2
resulted in six coordinated octahedral and square pyramidal axial addition products, such as [NiL
Z
(NCS)
2
], [NiL
Z
(NO
3
)(ClO
4
)], [NiL
Z
Cl(ClO
4
)], [NiL
Z
Br
2
], [NiL
Z
I
2
] and [NiL
Z
(NO
2
)](ClO
4
), respectively. However axial substitution reactions on [ZnL
Zα
(NO
3
)
2
] with KY (Y= SCN, Cl or Br) and NaNO
2
produced six coordinated octahedral axial substitution products [ZnL
Zα
(NCS)
2
], [ZnL
Zα
Cl
2
], [ZnL
Zα
Br
2
] and [ZnL
Zα
(NO
2
)
2
]. Similarly, the axial substitution reactions on [ZnL
Zβ
(NO
3
)
2
] with KI and NaClO
4
.6H
2
O resulted in six coordinated octahedral axial substitution products [ZnL
Zβ
I
2
] and [ZnL
Zβ
(H
2
O)
2
](ClO
4
)
2
, respectively. The compounds have been characterized by analytical, spectroscopic, magnetochemical and conductivity data. The antimicrobial activities of the new ligand and its complexes have been tested against different micro pathogens.
Graphic abstract
Nickel(II), copper(II) and zinc(II) complexes with an N-pendent dimethyl derivative ligand L
Z
of an octamethyl tetraazmacrocyclic ligand were prepared. The compounds were characterized by different analytical and spectroscopic methods. Antibacterial and antifungal activities of these compounds against some bacteria and fungi were also investigated.</description><identifier>ISSN: 0974-3626</identifier><identifier>EISSN: 0973-7103</identifier><identifier>DOI: 10.1007/s12039-020-01861-7</identifier><language>eng</language><publisher>New Delhi: Springer India</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coordination compounds ; Copper ; Copper compounds ; Fungicides ; Ligands ; Nickel ; Nitrogen dioxide ; Regular Article ; Room temperature ; Sodium nitrite ; Sodium perchlorate ; Spectroscopic analysis ; Substitution reactions ; Zinc compounds</subject><ispartof>Journal of chemical sciences (Bangalore, India), 2021, Vol.133 (1), Article 7</ispartof><rights>Indian Academy of Sciences 2021</rights><rights>Indian Academy of Sciences 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-3292d66ddfdf1500244d0837a2266465b4fd7a399213f39ff9541fa4f2ff2c293</citedby><cites>FETCH-LOGICAL-c319t-3292d66ddfdf1500244d0837a2266465b4fd7a399213f39ff9541fa4f2ff2c293</cites><orcidid>0000-0002-2192-1584</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12039-020-01861-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12039-020-01861-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Das Gupta, Suman Kanti</creatorcontrib><creatorcontrib>Rabi, Saswata</creatorcontrib><creatorcontrib>Ghosh, Deponkor</creatorcontrib><creatorcontrib>Yasmin, Farhana</creatorcontrib><creatorcontrib>Dey, Benu Kumar</creatorcontrib><creatorcontrib>Dey, Sujan</creatorcontrib><creatorcontrib>Roy, Tapashi Ghosh</creatorcontrib><title>Nickel(II), copper(II) and zinc(II) complexes with an N-pendent dimethyl derivative of an octamethyl macrocyclic ligand: synthesis, characterization and antimicrobial studies</title><title>Journal of chemical sciences (Bangalore, India)</title><addtitle>J Chem Sci</addtitle><description>Interaction of CH
3
I with L (3,10-C-meso-Me
8
[14]diene) in the ratio of 4:1 in ethanolic solution at room temperature yielded N-pendent dimethyl derivative [(L-2H)(–CH
3
)
2
] denoted by L
Z
. Interaction of nickel(II) acetate tetrahydrate with L
Z
and subsequent addition of NaClO
4
·6H
2
O produced square planar orange-yellow product, [NiL
Z
](ClO
4
)
2
. The reaction of copper(II) perchlorate hexahydrate with L
Z
afforded four coordinated square planar red [CuL
Z
](ClO
4
)
2.
However, on the reaction of zinc(II) nitrate hexahydrate with L
Z
furnished white six coordinated two distereoisomeric complexes [ZnL
Zα
(NO
3
)
2
] and [ZnL
Zβ
(NO
3
)
2
]. Axial addition reactions on four coordinated square planar [NiL
Z
](ClO
4
)
2
with KX (X= SCN, NO
3
, Cl, Br or I) and NaNO
2
resulted in six coordinated octahedral and square pyramidal axial addition products, such as [NiL
Z
(NCS)
2
], [NiL
Z
(NO
3
)(ClO
4
)], [NiL
Z
Cl(ClO
4
)], [NiL
Z
Br
2
], [NiL
Z
I
2
] and [NiL
Z
(NO
2
)](ClO
4
), respectively. However axial substitution reactions on [ZnL
Zα
(NO
3
)
2
] with KY (Y= SCN, Cl or Br) and NaNO
2
produced six coordinated octahedral axial substitution products [ZnL
Zα
(NCS)
2
], [ZnL
Zα
Cl
2
], [ZnL
Zα
Br
2
] and [ZnL
Zα
(NO
2
)
2
]. Similarly, the axial substitution reactions on [ZnL
Zβ
(NO
3
)
2
] with KI and NaClO
4
.6H
2
O resulted in six coordinated octahedral axial substitution products [ZnL
Zβ
I
2
] and [ZnL
Zβ
(H
2
O)
2
](ClO
4
)
2
, respectively. The compounds have been characterized by analytical, spectroscopic, magnetochemical and conductivity data. The antimicrobial activities of the new ligand and its complexes have been tested against different micro pathogens.
Graphic abstract
Nickel(II), copper(II) and zinc(II) complexes with an N-pendent dimethyl derivative ligand L
Z
of an octamethyl tetraazmacrocyclic ligand were prepared. The compounds were characterized by different analytical and spectroscopic methods. Antibacterial and antifungal activities of these compounds against some bacteria and fungi were also investigated.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Fungicides</subject><subject>Ligands</subject><subject>Nickel</subject><subject>Nitrogen dioxide</subject><subject>Regular Article</subject><subject>Room temperature</subject><subject>Sodium nitrite</subject><subject>Sodium perchlorate</subject><subject>Spectroscopic analysis</subject><subject>Substitution reactions</subject><subject>Zinc compounds</subject><issn>0974-3626</issn><issn>0973-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kUtLAzEUhQdR8PkHXAXcKBjNazKNOxEfBdGNrkOaRxudyYxJqtYf5W80bQV3rnLDPec7F05VHWJ0hhFqzhMmiAqICIIIjziGzUa1g0RDYYMR3VzNDFJO-Ha1m9ILQnTEGrpTfT94_Wrb4_H45BTofhhsXM5ABQO-fNCrj-67obWfNoEPn2dlBx7gYIOxIQPjO5tnixYYG_27yv7dgt4tNb3O6nfXKR17vdCt16D10wK_AGkR8swmn0ruTEWlcwF8FUAfVukqZN_54pt41YKU58bbtF9tOdUme_D77lXPN9dPV3fw_vF2fHV5DzXFIkNKBDGcG-OMwzVChDGDRrRRhHDOeD1hzjSKCkEwdVQ4J2qGnWKOOEc0EXSvOlpzh9i_zW3K8qWfx1AiJWEjXiNGalxUZK0qV6YUrZND9J2KC4mRXPYi173I0otc9SKbYqJrUyriMLXxD_2P6wfR8pJ0</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Das Gupta, Suman Kanti</creator><creator>Rabi, Saswata</creator><creator>Ghosh, Deponkor</creator><creator>Yasmin, Farhana</creator><creator>Dey, Benu Kumar</creator><creator>Dey, Sujan</creator><creator>Roy, Tapashi Ghosh</creator><general>Springer India</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-2192-1584</orcidid></search><sort><creationdate>2021</creationdate><title>Nickel(II), copper(II) and zinc(II) complexes with an N-pendent dimethyl derivative of an octamethyl macrocyclic ligand: synthesis, characterization and antimicrobial studies</title><author>Das Gupta, Suman Kanti ; Rabi, Saswata ; Ghosh, Deponkor ; Yasmin, Farhana ; Dey, Benu Kumar ; Dey, Sujan ; Roy, Tapashi Ghosh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-3292d66ddfdf1500244d0837a2266465b4fd7a399213f39ff9541fa4f2ff2c293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Fungicides</topic><topic>Ligands</topic><topic>Nickel</topic><topic>Nitrogen dioxide</topic><topic>Regular Article</topic><topic>Room temperature</topic><topic>Sodium nitrite</topic><topic>Sodium perchlorate</topic><topic>Spectroscopic analysis</topic><topic>Substitution reactions</topic><topic>Zinc compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Das Gupta, Suman Kanti</creatorcontrib><creatorcontrib>Rabi, Saswata</creatorcontrib><creatorcontrib>Ghosh, Deponkor</creatorcontrib><creatorcontrib>Yasmin, Farhana</creatorcontrib><creatorcontrib>Dey, Benu Kumar</creatorcontrib><creatorcontrib>Dey, Sujan</creatorcontrib><creatorcontrib>Roy, Tapashi Ghosh</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Das Gupta, Suman Kanti</au><au>Rabi, Saswata</au><au>Ghosh, Deponkor</au><au>Yasmin, Farhana</au><au>Dey, Benu Kumar</au><au>Dey, Sujan</au><au>Roy, Tapashi Ghosh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel(II), copper(II) and zinc(II) complexes with an N-pendent dimethyl derivative of an octamethyl macrocyclic ligand: synthesis, characterization and antimicrobial studies</atitle><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle><stitle>J Chem Sci</stitle><date>2021</date><risdate>2021</risdate><volume>133</volume><issue>1</issue><artnum>7</artnum><issn>0974-3626</issn><eissn>0973-7103</eissn><abstract>Interaction of CH
3
I with L (3,10-C-meso-Me
8
[14]diene) in the ratio of 4:1 in ethanolic solution at room temperature yielded N-pendent dimethyl derivative [(L-2H)(–CH
3
)
2
] denoted by L
Z
. Interaction of nickel(II) acetate tetrahydrate with L
Z
and subsequent addition of NaClO
4
·6H
2
O produced square planar orange-yellow product, [NiL
Z
](ClO
4
)
2
. The reaction of copper(II) perchlorate hexahydrate with L
Z
afforded four coordinated square planar red [CuL
Z
](ClO
4
)
2.
However, on the reaction of zinc(II) nitrate hexahydrate with L
Z
furnished white six coordinated two distereoisomeric complexes [ZnL
Zα
(NO
3
)
2
] and [ZnL
Zβ
(NO
3
)
2
]. Axial addition reactions on four coordinated square planar [NiL
Z
](ClO
4
)
2
with KX (X= SCN, NO
3
, Cl, Br or I) and NaNO
2
resulted in six coordinated octahedral and square pyramidal axial addition products, such as [NiL
Z
(NCS)
2
], [NiL
Z
(NO
3
)(ClO
4
)], [NiL
Z
Cl(ClO
4
)], [NiL
Z
Br
2
], [NiL
Z
I
2
] and [NiL
Z
(NO
2
)](ClO
4
), respectively. However axial substitution reactions on [ZnL
Zα
(NO
3
)
2
] with KY (Y= SCN, Cl or Br) and NaNO
2
produced six coordinated octahedral axial substitution products [ZnL
Zα
(NCS)
2
], [ZnL
Zα
Cl
2
], [ZnL
Zα
Br
2
] and [ZnL
Zα
(NO
2
)
2
]. Similarly, the axial substitution reactions on [ZnL
Zβ
(NO
3
)
2
] with KI and NaClO
4
.6H
2
O resulted in six coordinated octahedral axial substitution products [ZnL
Zβ
I
2
] and [ZnL
Zβ
(H
2
O)
2
](ClO
4
)
2
, respectively. The compounds have been characterized by analytical, spectroscopic, magnetochemical and conductivity data. The antimicrobial activities of the new ligand and its complexes have been tested against different micro pathogens.
Graphic abstract
Nickel(II), copper(II) and zinc(II) complexes with an N-pendent dimethyl derivative ligand L
Z
of an octamethyl tetraazmacrocyclic ligand were prepared. The compounds were characterized by different analytical and spectroscopic methods. Antibacterial and antifungal activities of these compounds against some bacteria and fungi were also investigated.</abstract><cop>New Delhi</cop><pub>Springer India</pub><doi>10.1007/s12039-020-01861-7</doi><orcidid>https://orcid.org/0000-0002-2192-1584</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0974-3626 |
| ispartof | Journal of chemical sciences (Bangalore, India), 2021, Vol.133 (1), Article 7 |
| issn | 0974-3626 0973-7103 |
| language | eng |
| recordid | cdi_proquest_journals_2486504251 |
| source | EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry; SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination compounds Copper Copper compounds Fungicides Ligands Nickel Nitrogen dioxide Regular Article Room temperature Sodium nitrite Sodium perchlorate Spectroscopic analysis Substitution reactions Zinc compounds |
| title | Nickel(II), copper(II) and zinc(II) complexes with an N-pendent dimethyl derivative of an octamethyl macrocyclic ligand: synthesis, characterization and antimicrobial studies |
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