1-Carbamoylhydantoins. New Aspects of Reactivity

Some derivatives of 1-carbamoylhydantoins undergo cleavage at the N 1 –C(O) bond on heating in solution. 1-Carbamoylhydantoins in aqueous and alcoholic ammonia rearrange via opening of the imidazole ring, followed by recyclization. Prolonged treatment of 1-carbamoylhydantoins with aqueous ammonia ca...

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Veröffentlicht in:	Russian journal of organic chemistry 2020-12, Vol.56 (12), p.2119-2131
Hauptverfasser:	Kavina, M. A., Sizov, V. V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Ammonia Carbonyl groups Carbonyls Chemistry Chemistry and Materials Science Imidazole Organic Chemistry
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description	Some derivatives of 1-carbamoylhydantoins undergo cleavage at the N 1 –C(O) bond on heating in solution. 1-Carbamoylhydantoins in aqueous and alcoholic ammonia rearrange via opening of the imidazole ring, followed by recyclization. Prolonged treatment of 1-carbamoylhydantoins with aqueous ammonia can lead to elimination of the C 2 =O carbonyl group.
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subjects	Ammonia Carbonyl groups Carbonyls Chemistry Chemistry and Materials Science Imidazole Organic Chemistry
title	1-Carbamoylhydantoins. New Aspects of Reactivity
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